IAOe?IIAEUeIA AEAAeAI?ss IAOE OE?A?IE
O?CEEI-O?I?*IEE ?INOEOOO ?I. I.A. AIAAONUeEIAI
OAO?AI EE?EEI EAII?AeIAE*
OAeE 541.183.1:543.3
EIIIEAENIOOAI?THTH*? NI?AAIOE IA INIIA? AII?OIEO E?AIIACAI?A ?
i-Ae?IENEO?IIAIIE?A OA ?O AIAE?OE*IA
CANOINOAAIIss
02.00.02 – aiae?oe/ia o?i?y
A A O I ? A O A ? A O
aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy
eaiaeeaeaoa o?i?/ieo iaoe
Iaeana-1998
Aeena?oaoe??th ? ?oeiien
?iaioa aeeiiaia ia eaoaae?? aiae?oe/ii? o?i?? Iaeanueeiai aea?aeaaiiai
oi?aa?neoaoo ?i. ?.?. Ia/ieeiaa
Iaoeiaee ea??aiee: eaiaeeaeao o?i?/ieo iaoe, aeioeaio
*aaioa?ueia Ieaenaiae? Ieeieaeiae/,
caa. eaoaae?ith aiae?oe/ii? o?i??
Io?oe?ei? iiiiaioe: aeieoi? o?i?/ieo iaoe,
O?ioei/oe Aiaoie?e Einoyioeiiae/,
Ee?anueeee aea?aeaaiee oi?aa?neoao ?i. Oa?ana Oaa/aiea,
noa?oee iaoeiaee ni?a?ia?oiee
eaiaeeaeao o?i?/ieo iaoe,
AEaeoaae ?aai ?aaiiae/,
O?ceei-o?i?/iee ?inoeooo ?i. I.A. Aiaaonueeiai IAI
Oe?a?ie, noa?oee iaoeiaee ni?a?ia?oiee
I?ia?aeia onoaiiaa: ?inoeooo o?i?? iiaa?oi? IAI Oe?a?ie
Caoeno a?aeaoaeaoueny “19” eenoiiaaea 1998 ?. ia 11 aiaeei? ia
can?aeaii? niaoe?ae?ciaaii? a/aii? ?aaee Ae 41.219.01 o O?ceei-o?i?/iiio
?inoeooo?
?i. I.A. Aiaaonueeiai IAI Oe?a?ie ca aae?anith 270080, i. Iaeana,
Ethnoaei?onueea
aei?iaa, 86
C aeena?oaoe??th iiaeia iciaeiieoenue o a?ae?ioaoe? O?ceei-o?i?/iiai
?inoeoooo
?i. I.A. Aiaaonueeiai IAI Oe?a?ie
Aaoi?aoa?ao ?ic?neaiee “_____” aeiaoiy 1998 ?.
A/aiee nae?aoa? niaoe?ae?ciaaii?
a/aii? ?aaee, eaiaeeaeao o?i?/ieo iaoe Iaca?aiei I.I.CAAAEUeIA
OA?AEOA?ENOEEA ?IAIOE
Aeooaeuei?noue oaie. ?iiia?e?caoe?y i?aai?/ieo ?aaaaio?a ia iiaa?oi?
oaa?-aeeo iin??a a?aee?eea iia? iiaeeeaino? aeey noai?aiiy
eiei?eiao?e/ieo oano-iaoi-ae?a aeieia?/iiai iii?oi?eiao, /ooeeaeo
aeaiaio?a iioe/ieo naini??a, ?yaeo ?i-oeo ia?niaeoeaieo iai?yie?a
aiae?oe/ii? o?i??. Ni?aaioe, ui i?noyoue cae??iea-i? aiae?oe/i?
?aaaaioe, ana oe?oa aeei?enoiaothoueny a iia?e a?oi?
niaeo?ioioi-iao?e/ieo iaoiae?a aiae?co – oaa?aeioaci?e
niaeo?ioioiiao???, o oiio /ene?, a aeaeo?iii?e niaeo?ineii??
aeeooc?eiiai a?aeaeooy. Aeaia a?oia aiae?oe/ieo ia-oiae?a, caa??aath/e
a?aeii? iiceoeai? yeino? o?aaeeoe?eii? niaeo?ioioiiao???,
a?ae-??ciy?oueny a?eueo aenieith /ooeea?noth ? naeaeoeai?noth ca ?aooiie
ni?aoe?eiiai eiioeaio?oaaiiy ? i?yiiai aecia/aiiy ?a/iaeie a oac?
ni?aaioo.
Iaeiei ?c iaoiae?a iaea?aeaiiy ni?aaio?a, ye? canoiniaothoueny a
oaa?aeioaci?e niaeo?ioioiiao???, ? niaoeeo?/ia aaeni?aoe?y i?aai?/ieo
?aaaaio?a ia iiaa?oi? ca ?aooiie ?iiii-anioe?aoeaii? aca?iiae?? c
ooieoe?iiaeueieie a?oiaie iiniy. Iacaaaeath/e ia cia/i? oni?oe a aaeoc?
noai?aiiy oaeiai ?iaeo ni?aaio?a, ?yae ieoaiue, iia’ycaieo ?c aieeaii
iaoeaii? iao?eoe?, oiia ? iaoai?ci?a ?iiia?e?caoe?? i?aai?/iiai ?aaaaioo
ia oaa?ae?e iiaa?oi?, a oaeiae aeayeeo ?ioeo oaeoi??a ia
o?i?-ei-aiae?oe/i? oa?aeoa?enoeee iaea?aeaieo ni?aaio?a, i?aeoe/ii ia
?ic?iaeai?. E??i oiai, a e?oa?aoo?? iaaaaeaii ae?ae ??aee? i?eeeaaee
aeei?enoaiiy oaa?aei-oacii? niaeo?ioioiiao??? aeey aecia/aiiy
i?e?ie?eueeinoae oaeeo aeaiaio?a, ye iie?aaeai, oeoai, aae?e, ieiai oa
?io?, ui eaaei a?ae?ie?cothoueny. I?aai?/i? ?aaaaioe eeano
i-ae?ieneo?iiaiie?a, yei ? ia?niaeoeaieie aeey niaeo?ioioi-iao?e/iiai
aecia/aiiy ?yaeo aaaaoica?yaeieo ?ii?a, a yeinoi iiaeeo?eaoi?ia oaa?aei?
iiaa?oi?, aeioaia? ia canoiniaoaaeeny.
Aeena?oaoeieia ?iaioa aeeiiaia o aiaeiiaiaeiinoi c eii?aeeiaoeieiei
ieaiii IAe? eaoaae?e aiaeioe/ii? o?i?? o?i?/iiai oaeoeueoaoo Iaeanueeiai
aea?aeaaiiai oi?aa?neoaoo ?i. ?.?. Ia/ieeiaa ? 0194U044430.
Iaoa ?iaioe: onoaiiaeoe o?i?ei-aiae?oe/i? aeanoeaino?
eiiieaeniooai-?thth/eo ni?aaio?a ia iniia? aii?oieo e?aiiacai?a ?
i-ae?ieneo?iiaiie?a, a oa-eiae caeiiii??iino? ?o aaeni?aoe?eii?
aca?iiae?? c aaaaoica?yaeieie ?iiaie iaoae?a.
Aeey aeinyaiaiiy oe??? iaoe iaiao?aeii aoei ae??oeoe oae? caaea/?:
– aeine?aeeoe caeiiii??iino? aaeni?aoe?eii? aca?iiae??
i-ae?ieneo?iiaiie?a c ii-aa?oiath ??cieo ca ooieoe?iiaeueiei neeaaeii
aii?oieo e?aiiacai?a ? iioei?co-aaoe oiiae iaea?aeaiiy
eiiieaeniooai?thth/eo ni?aaio?a;
– i?iaanoe ii??aiyeueia aeine?aeaeaiiy iaea?eueo aaaeeeaeo
o?i?ei-aiae?oe/ieo oa?aeoa?enoee eiiieaeniooai?thth/eo ni?aaio?a ia
iniia? e?aiiacai?a ? i-ae?-ieneo?iiaiie?a, io?eiaieo iaoiaeaie
aaeni?aoe?eiiai ? o?i?/iiai iiaeeo?eoaaiiy;
– aea/eoe e iioei?coaaoe oiiae ni?aoe?eii? aca?iiae?? ?yaeo
aaaaoica?yaeieo ?ii?a iaoae?a c eiiieaeniooai?thth/ei ni?aaioii ia
iniia? 3-ai?iii?ii?eaa?i-neeo (3-AIA) ? ea?aieneeae?ieneo?iiaiieo
(EAeO);
– ?ic?iaeoe ni?aoe?eii-niaeo?ioioiiao?e/i? iaoiaeeee aecia/aiiy
i?e?ie?eue-einoae Ii (VI), Ti (IV) ? Ga (III) o i?e?iaeieo ia’?eoao c
aeei?enoaiiyi eii-ieaeniooai?thth/iai ni?aaioo 3-AIA-EAeO.
Iaoeiaa iiaecia. Aia?oa aeine?aeaeaii e?iaoeeo, ni?yiiaai?noue,
iaoai?c-ie ? nooo?ai oaeoi?e aaeni?aoe?? i-ae?ieneo?iiaiie?a aii?oieie
e?aiiacaiaie c ??ciei ooieoe?iiaeueiei neeaaeii iiaa?oiaaiai iie?eao.
Aeieacaii ?iiii-anioe?a-oeaiee oa?aeoa? aca?iiae?? i-ae?ieneo?iiaiie?a,
ui i?noyoue ooieoe?iiaeuei? a?oie ??cii? eeneioiino?, c iiaa?oiath
3-ai?iii?ii?eaa?ineeo.
C aeei?enoaiiyi ea?aiae??i?aeiiai iaoiaeo cae?eniaii eiaaeaioia
ca’ycoaai-iy ea?aieneeae?ieneo?iiaiieo c iiaa?oiath
3-ai?iii?ii?eaa?ineeo. Iieacaii, ui ii noeoiiino? iaea?eueo aaaeeeaeo
o?i?ei-aiae?oe/ieo oa?aeoa?enoee, c o?a-ooaaiiyi i?inoioe ? c?o/iino?
iaea?aeaiiy, ni?aaio, iiaeeo?eiaaiee aaeni?aoe??th i?aai?/iiai ?aaaaioo,
ia?aaa?oo? aiaeia, neioaciaaiee o?i?/iith ?iiia?e?-caoe??th.
Ia i?eeeaae? ni?aoe?? iieiaaeaio (VI) ? oeoaio (IV) i?iaaaeaii
ii??aiyeueiee aiae?c eiiaoeee, iaea?eueo aaaeeeaeo oaeoi?ia ? iaoai?ci?a
aca?iiae?? aaaaoica-?yaeieo ?ii?a ?c iiaa?oiath 3-AIA-EAeO ? aa?ineeo
A-380. Ciaeaeaii iioeiaeuei? oiiae ni?aoe?eii-niaeo?ioioiiao?e/iiai
aecia/aiiy cacia/aieo iaoae?a ic aeei?enoaiiyi ni?aaioo 3-AIA-EAeO.
I?aeoe/ia cia/aiiy aeine?aeaeaiue. Io?eiai? aenia?eiaioaeuei? ?
?ic-?aooieia? aeai? aeicaieythoue i?iaiicoaaoe iaea?eueo aoaeoeai?
nenoaie “iin?e-iiaeeo?eaoi?” i?e noai?aii? ia?niaeoeaieo
eiiieaeniooai?thth/eo ni?aaio?a iaoiaeii aaeni?aoe?eiiai iiaeeo?eoaaiiy
c iaoith naeaeoeaiiai eiioeaio?oaaiiy ?
oaa?aeioacii-niaeo?ioioiiao?e/iiai aecia/aiiy i?e?ie?eueeinoae iaoae?a.
?ic?iaeaii /ooeea? ? naeaeoeai? iaoiaeeee aecia/aiiy Ii (VI), Ti (IV) ?
Ga (III). Ieaeiy iaaea aecia/aiiy neeaaea?: 1,5*10-7 % ian.(Mo),
2,5*10-7 % ian. (Ti), 2*10-7 % ian. (Ga). Cai?iiiiiaai? iaoiaeeee
ai?iaiaaii i?e aiae?c? ian?iiy aiaiaeo ?ineei ia ai?no Ii (VI) ?
e?eoaaeueieo ioeiaeo a?aeeeaaeaiue (iaei?ae?a) ia ai?no Ti (IV) ? Ga.
A?aeiinia iioeaea aecia/aiiy iaoae?a ia ia?aaeuo? 3-5 %.
Iniaenoee aianie aaoi?a: iinoaiiaea caaea/ aeine?aeaeaiiy aeeiioaaeany
ca o/anoth aeena?oaioa. Aiae?c e?oa?aoo?ieo aeaieo ? aenia?eiaioaeuei?
aeine?ae-aeaiiy i?iaaaeai? aaoi?ii naiino?eii. Iaaiai?aiiy ?acoeueoao?a
aeine?aeaeaiue ? ?o iiyniaiiy cae?enithaaeiny ca aeoeaiith o/anoth
aeena?oaioa.
Ai?iaaoe?y ?acoeueoao?a aeena?oaoe??. Iniiai? ?acoeueoaoe aeena?oaoe??
aeiiia?-aeaeeny e iaaiai?thaaeeny ia: I?aeia?iaeiiio Eiia?an? c
aiae?oe/ii? o?i?? (Iineaa, 1997); I?aeia?iaei?e eiioa?aioe?? “Silica:
From Synthesis to Application” (Mulhouse, France, 1998); Anaoe?a?inueeeo
eiioa?aioe?yo c aiae?oe/ii? o?i??, i?enay/aieo 90-??//th c aeiy
ia?iaeaeaiiy aeaaeai?ea A.E. Aaaea (Ee?a, 1995) ? /eaia-ei?aniiiaeaioa
A.A. Iaca?aiea (Oaeai?iae, 1998); XIV Oe?a?inuee?e eiioa-?aioe?? c
iai?aai?/ii? o?i?? (Ee?a, 1996); Iaoeiai-ae?iaie/?e eiioa?aioe?? c
nai?oa?ii? o?i?? ? oieneeieia?? (?ee?/?anuee, 1994); iaoeia?e
eiioa?aioe?? i?ioa-ni?nueei-aeeeaaeaoeueeiai neeaaeo ? iaoeiaeo
i?aoe?aiee?a Iaeanueeiai aea?aeaaiiai oi?aa?neoaoo ?i. I.I. Ia/ieeiaa
(1995).
Ioae?eaoe??: ca oaiith aeena?oaoe?? iioae?eiaaii 4 noaoo? ? 5 oac
aeiiia?aeae.
No?oeoo?a ? ?ici?? aeena?oaoe??. Aeena?oaoe?eia ?iaioa aeeeaaeaia ia 120
noi??ieao iaoeiiieniiai oaenoo, aeeth/a? 17 oaaeeoeue, 28 ?enoie?a,
neeaaea?oueny c? anooio, oanoe ?icae?e?a, caeeth/aiiy oa caaaeueieo
aeniiae?a. Nienie oeeoiaaii? e?oa?aoo?e aeeth/a? 190 aeaea?ae.
CI?NO ?IAIOE
O anooi? iaa?oioiaaii aea?? oaie i aecia/aia iaoa aeena?oaoe?eii?
?iaioe, iaaaaeaii iaoeiao iiaecio ? i?aeoe/io cia/ei?noue io?eiaieo
?acoeueoao?a.
O ia?oiio ?icae?e? ?icaeyiooi iniiai? iaoiaee iiaa?oiaaiai
iiaeeo?eo-aaiiy aii?oieo e?aiiacai?a ii oeio aca?iiae?? iiaeeo?eaoi?a ?
iao?eoei. Iieaca-ii, ui ia?niaeoeaiei iai?yieii aiae?oe/ii? o?i?? ?
canoinoaaiiy iiaeeo?eiaa-ieo oaa?aeeo iin??a o “a?a?eaeieo” iaoiaeao
aiae?co, a oiio /ene?, ni?aoe?eii-niaeo?ioioiiao?e/ieo.
I?aee?aneth?oueny, ui iacaaaeath/e ia oni?oe, aeinyaioo? a ?ic?iaoe? ?
canoinoaaii? ni?aoe?eii-niaeo?ioioiiao?e/ieo iaoiae?a, caeeoathoueny
iaae??oaieie i?iaeaie oe?eani?yiiaaiiai aeai?o niiniao cae??ieaiiy
i?aai?/ieo ?aaaaio?a ia oaa?ae?e iiaa?oi?, i?iaiicoaaiiy aieeao oeio
?iiia?e?-caoe?? ia ni?aoe?ei? oa?aeoa?enoeee oa ?io? o?i?ei-aiae?oe/i?
aeanoeaino? iiaeeo?eiaaieo ni?aaio?a.
O ae?oaiio ?icae?e? iaaiaeeoueny oa?aeoa?enoeea iaoa??ae?a ? iaoiae?a,
ye? aeei?enoai? a aeai?e ?iaio?. A yeino? iiaeeo?eaoi??a aeey
iaea?aeaiiy eiiieaeni-ooai?thth/eo ni?aaio?a canoiniaoaaee ?yae
i?aaenoaaiee?a i?aai?/ieo ?aaaaio?a eeano i-ae?ieneo?iiaiie?a (AeIO)
6,7-ae?iene-2-oai?e-4-ea?aieneaaicii??ee?e oei?eae (EAeO),
a,7-ae?iene-2-oai?e-4-iaoeeaaicii??ee?e oei?eae (IOAeO) ?
6,7-ae?iene-2-(3′-noeueoioai?e)-4-iaoeeaaicii??ee?e oei?eae (NAeO).
EAeO NAeO IOAeO
sse iin?? aeey cae??ieaiiy AeIO aeei?enoiaoaaee aenieiaeenia?ni?
aii?oi? e?aiiacaie – ay?ineee A-380 ? 3-AIA, ui a?ae??ciythoueny
eeneioii-iniiaieie aeanoeainoyie iiaa?oiaaeo ooieoe?iiaeueieo a?oi.
Cacia/ai? oaa?ae? iin??, caaaey-ee aenieiio nooiaith iiiiaeenia?niino?,
a?aenooiino? ii?, ? c?o/ieie iiaeaeyie aeey aea/aiiy i?ioean?a
?iiia?e?caoe?? i?aai?/ieo ?aaaaio?a, a oaeiae ia?niaeoeaii aeey
aeei?enoaiiy o oaa?aeioaci?e niaeo?ioioiiao??? aiane?aeie a?aenooiino?
aeaniiai na?oeiiiaeeiaiiy ? iaeiai ?ici??o /anoeiie.
O?i?/ia i?euaieaiiy EAeO aei iiaa?oi? 3-AIA c ooai?aiiyi ai?aeiiai
ca’y-ceo cae?enithaaee ea?aiae??iiaeiei iaoiaeii. Aeey aeieaco
?aae?caoe?? o?enoth/iai ca’yceo aeei?enoiaoaaee ?*-niaeo?ineii?/iee
aiae?c neioaciaaiiai ni?aaioo. A ?*-niaeo?ao c?ace?a 3-AIA, o?i?/ii
iiaeeo?eiaaieo EAeO, e??i iayaiino? nioa, oa?aeoa?ieo aeey
aaiciii?aiieueiiai oeeeeo cae??ieaiiai ?aaaaioo (1052, 1021 i 900 ni-1)
niinoa??aa?oueny cia/ia ciaioaiiy ?ioaineaiino? nioa a?eueieo ai?iia?oi
3-AIA (((NH2) ? ((NH2) i?e 3380, 3308 ni-1 ? 1600 ni-1 a?aeiia?aeii), a
oaeiae a?aenooi? eieeaaiiy ea?aieneeueieo a?oi EAeO aianiaeie ooai?aiiy
aiiaeiiai ca’yceo.
Eiioeaio?aoe?th iiaa?oiaaeo a?oi iiaeeo?eiaaieo ni?aaio?a
anoaiiaethaaee iaoiaeii aaoa?iaaiiiai iioaioe?iiao?e/iiai oeo?oaaiiy
ie?aieo iaaaaeie.
O?iiioi?i? oa?aeoa?enoeee cae??ieaieo i?aai?/ieo ?aaaaio?a ? ?o
eiiieaen?a c iaoaeaie aeine?aeaeoaaee iaoiaeii aeaeo?iiii? niaeo?ineii??
aeeooc?eiiai a?aeaeooy (ANAeA).
O o?aoueiio ?icae?e? iiaeaii ?acoeueoaoe aea/aiiy iniiaieo oaeoi??a, ui
aieeaathoue ia aaeni?aoe?th AeIO ia?aieie e?aiiacaiieie iin?yie –
eeneioiino? ? ?iiii? neee na?aaeiaeua, i?e?iaee ? neeaaeo ?ic/eiiee?a.
Aeii?ioth/a ae?y eeneio-iino? na?aaeiaeua iaea?eueo ae?aaeaia a
?ioa?aae? pI 3-5 aeey nenoai “eeneioiee AeIO – 3-AIA” ? iiaea aooe
iiyniaia ia?aaaaeii ?iiii-anioe?aoeaiei oa?aeoa?ii aca?iiae?? aaeni?aaoo
? aaeni?aaioo. I?e aaeni?aoe?? AeIO o aiaeii-aoaiieueieo na?aaeiaeuao
aeiy eiioeaio?aoe?? aoaiieo aeyaey?oueny a iaeano? eiai iaeiai ai?noo ?
iaea?eueo ae?aaeaia a aaoa?iaaiieo nenoaiao “AeIO – ay?inee A-380” ?
“IOAeO – 3-AIA”. Aieea aeaiiai oaeoi?o ?ioa?i?aoo?oueny c iiceoe?e
eiieo?aioe?? iieaeoe aoaiieo ca aeoeai? oeaio?e o?ce/ii? aaeni?aoe??
(neeaiieuei? oa ai?iia?oie iin??a). Cai?ia aiaeii-aoaiieueiiai
na?aaeiaeua ia AeIOA ia i?ecaiaeeoue aei ?noioii? ci?ie iaoai?ci?a
aaeni?aoe??, iaeiae eiieo?aioe?y c aieo oeueiai ?ic/eiieea ca aeoeai?
oeaio?e iiaa?oi? ae?aaeaia cia/ii neaae?oa. I?aeaeuaiiy ?iiii? neee
?ic/eio iaaaoeaii a?aeaeaa?oueny ia eieueeinieo ia?aiao?ao
aenieiniaoeeo?/ii? aaeni?aoe?? ?iiii-anioe?aoeaiiai oeio (nenoaie
“NAeO-3-AIA” ? “EAeO-3-AIA”). Aeiy aeaiiai oaeoi?o iaea?eueo ae?aaeaia
i?e iaeeo eiioeaio?aoe?yo nieueiaiai oiio (( ( 0,1). C iiaeaeueoei
c?inoaiiyi eiioeaio?aoe?? nieae iao??th aei 1 iieue/e, aieea ?iiii? neee
caeeoa?oueny i?aeoe/ii iaci?iiei.
?en. 1. ?cioa?ie aaeni?aoe?? AeIO ia aii?oieo e?aiiacaiao i?e ?I 1 (A),
3 (A),
5 (A). t=20±1°N; mni?aaioo=0,1 a; V=25 ie; (=0,1; Naoaiieo=2 %;
(ni?aoe?? =30 oa.
E?iaoeea ? iaoai?ci aaeni?aoe?? AeIO ia?aieie e?aiiacaiieie iin?yie a
?ioa?aae? pI 0-7, aieiaiei /eiii, caeaaeaoue a?ae ooieoe?iiaeueiiai
neeaaeo eiiii-iaio?a aaoa?iaaiii? nenoaie. Aca?iiae?y eeneioieo AeIO c
3-AIA oa?aeoa?eco-?oueny aenieith oaeaee?noth anoaiiaeaiiy
aaeni?aoe?eii? ??aiiaaae (5-10 oa) a ?i-oa?aae? pI 3-5. A ?aoo?
aaoa?iaaiieo nenoai /an anoaiiaeaiiy ??aiiaaae ?noioii aeua (aei 25-30
oa).
?cioa?ie aaeni?aoe?? EAeO ? NAeO ia 3-AIA a ?ioa?aae? pI 1-5 (?en. 1)
a?aeiinyoueny aei ae?aaeaiiai I-oeio (iaioeueiaee ii/aoie ?cioa?ie,
aaeeeee eoo iaoeeo a iaeano? Aai??, i?ioyaiooa ? i?aeoe/ii
ai?eciioaeueia ieaoi iiiiiiea-eoey?ii? aaeni?aoe??), ui na?ae/eoue i?i
ia?aaaaeii oaiini?aoe?eiee oa?aeoa? aca?-iiae?? ca ?aooiie ooai?aiiy
iiiii-anioeiaoeaiiai ca’yceo c aiiiia?oiaie ni?aaioo. I?ioyaooee
a?ae??cie iiiiiieaeoey?iiai caiiaiaiiy iiaa?oi? aaeni?aaoii aeicaiey?
ia?aoe oiiae iiiioa?iaiai iiaeeo?eoaaiiy 3-AIA eeneioieie AeIO. A ?ioeo
aeiaaeeao (aaeni?aoe?y AeIO ia aa?ineei A-380 ? IOAeO – ia 3-AIA)
iaea?aeaii L- ? S-oi?ie ?cioa?i. L-oei icioa?i niinoa?iaa?oueny a
iioa?aaei ?I iica iciaeaeo?e/ii? oi/ee iaiiaeeoieiaaiiai e?aiiacaio
(iai?e-eeaae ?I 1 ? 5) i naiae/eoue i?i neaaeo aca?iiaeith aaeni?aaoo c
iini?i aiane?aeie ooaiaiiy aiaeiaaiai ca’yceo, a oaeiae ieaia?ia
?iciiuaiiy iieaeoe AeIO aiaeiinii iiaa?oii. Iaeiae, i?e ?I 1 aeey
L-oi?ie ?cioa?i aaeni?aoe?? EAeO ? NAeO i?inoei aa?ineeii oa?aeoa?i?
aeayei ?ene I-oeio, ui aeaco? ia ai?iaiaeiee aeeaae oaiini?aoe?eii?
aca?iiae?? cacia/aieo aa?aiee?a ii i?ioiiiaaieo neeaiieueieo a?oiao
iin?y. I?e ?I 3 i aeua, ii?ooaiiy eeane/ii? eaiaith??anueei? oi?ie
?cioa?i i?e ia?aoiae? a?ae iaeano? Aai?? aei ieaoi, yea a?aeiia?aea?
caiiaiaiith iiiiiieaeoey?iiai oa?o, iiaea aooe iia’ycaii c
iaiaeii??aei?noth iiaa?oiaaiai iie?eao e?aiiacaiii? iao?eoe?, a oaeiae c
iie?ooieoe?iiaeuei?noth naieo AeIO. S-oei ?cioa?i a oi/oe?
aeaeo?iiaeo?aeueiino? (?I 2-3) na?ae/eoue i?i neeueio eiieo?aioe?th c
aieo ?ic/eiieea ca aeoeai? oeaio?e aaeni?aoe??. I?e oeueiio iieaeoee
aeine?aeaeo?ieo aa?aiee?a aaeni?aothoueny aa?oeeaeueii, o aeaeyae? oae
caaieo «J-aa?aaao?a» u?eueiiai oiaeoaaiiy.
C ?acoeueoaoaie i?iaaaeaieo aaeni?aoe?eieo aenia?eiaio?a aeia?a
ei?aeththoue aeai? ANAeA, a oaeiae ?ic?aoiaai? eiinoaioe Aai?? ?
cia/aiiy noaoe/ii? ni?aoe?e-ii? ?iiino? aea/aieo e?aiiacai?a a?aeiinii
ia?aieo AeIO. Ii?ooaiiy ei?aey-oe?? ?ic?aooieiaeo ? aenia?eiaioaeueieo
ia?aiao??a niinoa??aa?oueny i?e pI ( 5, ui iiaea iiynithaaoeny ci?iith
?ic/eiiino? AeIO ic c?inoaiiyi pI.
I?iaaaeai? aaeni?aoe?ei? ? niaeo?ineii?/i? aeine?aeaeaiiy aeicaieeee
iioei?co-aaoe oiiae aaeni?aoe?eii? ?iiia?e?caoe?? cacia/aieo ?aaaaio?a.
E?auith nenoaiith aeey oaeiai iiaeeo?eoaaiiy ? niieo/aiiy eeneioiiai
o?iiaiieo c ai?iie?aiia-caiiith iao?eoeath.
I II
Ii?yae c aaeni?aoe?eiei
iiaeeo?eoaaiiyi, aoei cae?eniaii eiaaeaioia ca’ycoaaiiy EAeO c
3-AIA ca ?aooiie ooai?aiiy ai?aeiiai ca’yceo. Cai?iiiiiaaii iiaeeea?
no?oeoo?e iiaa?oiaaeo niieoe, iaea?aeaieo aaeni?aoe?eiei iaoiaeii (I) ?
o?i?/iith ?iiia?e?-caoe??th (II). Aeey io?eiaieo iiaee-o?eiaaieo
ni?aaio?a oa?aeoa?i? aenie? eiioeaio?aoe?? i?euaieaii-ai ?aaaaioo (1,7 –
2*10-4 iieue/a i 1,1 – 1,4*10-4 iieue/a aeey aaeni?a-oe?eiiai ?
eiaaeaioiiai ca’ycoaai-iy a?aeiia?aeii).
*aoaa?oee ?icae?e i?enay-/aii aeine?aeaeaiith iaea?eueo aaae-eeaeo a
aiae?oe/iiio ieai? o?ce-ei-o?i?/ieo aeanoeainoae ni?aai-o?a ia iniia?
EAeO ? aii?oieo e?aiiacai?a – a?ae?ie?oe/ii? no?e-eino? ?
niaeo?ioioiiao?e/ieo oa-?aeoa?enoee iiaa?oiaaiai ooie-oe?iiaeueiiai
iie?eao.
Ae?aiacii pI a?ae?ie?oe/ii? noaa?eueiino? ni?aaioo 3-AIA-EAeO (?en. 2),
io?eiaiiai aaeni?a-oe??th (pI 1 – 8), ia aeoaea cia/ii iinooia?oueny
oae?e aeey aiaeiao, neioaciaaiiai eiaaeaioiei ca’y-coaaiiyi (pI 0-9).
I?e oeueiio i?aeaeuaia no?ee?noue oa?o aaeni?-aiaaiiai ?aaaaioo a eene?e
iaea-no? aeinyaa?oueny i?e cieaeaii? eii-oeaio?aoe?? aoaiieo a
aeenia?n?eii-io na?aaeiaeu? (e?ea? 2-4). A eoae-i?e iaeano? (?I 12)
niinoa??aa?oue-ny cai?ioi?e aoaeo – iaioa eii-oeaio?aoe?y aoaiieo
i?ecaiaeeoue aei cieaeaiiy no?eeino? cae??ieaiiai oa?o.
?en. 3. Ae?aa?aia ?iciiae?eo eeneioii-iniia-ieo oi?i EAeO a ??cieo
nenoaiao. 1 – EAeO a ?ic/ei?; 2 – EAeO-EIA? (OeOIA); 3 – EAeO-
A-380; 4 – 3-AIA-EAeO (eiaaeaioia ca’ycoaai-iy); 5 – 3-AIA-EAeO
(aaeni?aoe?y, aieia? c?acee).
?en. 2. A?ae?ie?oe/ia no?eeinoue ni?aaio?a ia iniia? 3-AIA ? EAeO,
io?eiaieo ??cieie iaoiaeaie: 1 – 3-AIA-EAeO (eiaaeaioia ca’yco-aaiiy);
2-4 – 3-AIA-EAeO (aaeni?aoe?eia iiaee-o?eoaaiiy). Ni?aa?aeiioaiiy
I2I:C2H5OH (%):
2 – 98:2; 1, 3 – 50:50; 4 – 4:96.*an eiioaeoo oac – 1 aeiaa;
mni?aaioo=0,1 a;V=25 ie.
Ii??aiyeueiee aiae?c o?iii-oi?ieo aeanoeainoae EAeO a ??c-ieo
aiiiaaiieo ? aaoa?iaaiieo nenoaiao a oe?ieiio ?ioa?aae? ?I (?en. 3;
ioieoe?ieie e?i?yie iicia/aii iaae? ?ioa?aae?a pI ?n-ioaaiiy
eeneioii-iniiaieo oi?i EAeO) aeicaieea aeyaeoe aeecueeee oa?aeoa?
?iciiae?eo ?iiii-iieaeo-ey?ieo oi?i EAeO a /enoiio ?ic-/ei? ? ia
iiaa?oii aa?ineeo A-380 (e?ea? 1, 3), ui aeaco? ia neaaeee aieea
iao?eoe? iaiiaeeo?eiaaiiai e?aiiacaio ia niaeo?aeuei? aeanoeaino?
aaoa?iaaiici-aaiiai ?aaaaioo. I?inoaaeo?oueny oaeiae aiaeia?y a
nenoaiao EAeO – 3-AIA ?
EAeO – EIA? (e?ea? 2, 5). Aeey iaio nenoai oa?aeoa?ia a?aenooi?noue
ia?aoiaeo aei inaaaeiiieaeoey?ii? oi?ie EAeO (a), ui na?ae/eoue i?i
o?enaoe?th ?aaaaioo a aeaeyae? ea?aieneeao-ai?iio. O?iiioi?i?
oa?aeoa?enoeee EAeO, o?i?/ii ?iiia?e?ciaaiiai ia 3-AIA, ?noioii
a?ae??ciythoueny a?ae on?o ?ioeo aeine?aeaeoaaieo nenoai (e?eaa 4). Aeey
aeaii? nenoaie oa?aeoa?ia iayai?noue o?ueio ?iiii-iieaeo-ey?ieo noai?a,
ui, ai?ia?aeii, a?aeiia?aeathoue eao?iii?e (a) ? aeaii ai?iiiei (a, a)
oi?iai. Iaeiae oe? oi?ie ?niothoue a ?ioeo ?ioa?aaeao pI c a?ii- ?
a?inio?iiii cnoiooeie iaeneioiaie a niaeo?ao a ii??aiyii? c 3-AIA-EAeO,
io?eiaiei aaeni?aoe?eiei iaoiaeii.
Ia i?aenoaa? ii??aiyeueiiai aeine?aeaeaiiy o?ceei-o?i?/ieo aeanoeainoae
3-AIA-EAeO, iaea?aeaiiai ??cieie iaoiaeaie, iieacaii, ui iiaeeoieiaaiee
ni?aaio, io?eiaiee aaeni?aoe??th, ca a?ae?ie?oe/iith no?eeinoth
i?aeoe/ii ia iinooia-?oueny, a ca o?iiioi?ieie oa?aeoa?enoeeaie cia/ii
ia?aaa?oo? aiaeia, neioa-ciaaiee eiaaeaioiei ca’ycoaaiiyi.
Oaaeeoey 1
Ciaeo?ioioiiao?e/i? oa?aeoa?enoeee aeineiaeaeaiieo aaoa?iaaiieo nenoai
ca o/anoth EAeO
Nenoaia (max, ii ((max, ii
aiaeiinii EAeO
a ?ic/eii ((max, ii
aiaeiinii nenoaie
A-380-EAeO
Iiaio?yii-nooi c?acee (ANAeA)
A-380-EAeO 501 (1,21)* 61 –
3-AIA-EAeO (aaeni?aoeiy) 530 (2,48) 90 29
3-AIA-EAeO (oii. ca’ycoaaiiy) 509 (1,84) 69 7
Aieiai c?acee, ?I 3 (ANAeA)
A-380-EAeO 465 (1,71) 25 –
3-AIA-EAeO (aaeni?aoeiy) 495 (2,74) 55 30
3-AIA-EAeO (oii. ca’ycoaaiiy) 484 (1,91) 44 19
Noniaici? a ae?oea?eii (niaeo?e iiaeeiaiiy)
A-380-EAeO 465 (0,62) 25 –
3-AIA-EAeO (aaeni?aoeiy) 495 (0,98) 55 30
3-AIA-EAeO (oii. ca’ycoaaiiy) 482 (0,79) 42 17
EAeO a ?ic/eii, ?I 3 (niaeo?e iiaeeiaiiy)
EAeO 440 (0,74) – –
EAeO-OeOIA 455 (0,81) 15 –
* – a aeoaeeao iaaaaeaii cia/aiiy iioe/ii? aonoieie oa ooieoei?
Eoaaeee-Ioiea
I?ioyaii niaeo?ioioiiao?e/ieo aeine?aeaeaiue aeyaeaia oaeiae
caeaaeiinoue niaeo?aeueieo aeanoeainoae io?eiaieo iiaeeoieiaaieo
ni?aaioia aiae ?o aieiai-noi. sse aeaeii c iaaaaeaieo a oaae. 1 aeaieo,
iacaeaaeii a?ae iaoai?cio aca?iiae?? EAeO c aeine?aeaeo?ieie iao?eoeyie,
i?e ci?i? aieiaino? c?aceo a aeaeo?iiieo niaeo?ao niinoa??aa?oueny
a?ae?aco aeaa aoaeoe: ciaioaiiy aaoio?iiiiai cnoao a?aeiinii EAeO a
?ic/ei? oa i?aeaeuaiiy ?ioaineaiino? a iaeneioiao niaeo?aeueieo nioa.
Iayai?noue aeacaieo aoaeo?a iaoiiaeaia cia/iei aieeaii a?ae?aoiaaiino?
ni?aaioo ia o?iiioi?i? oa?aoa?enoeee ?iiia?e?ciaaiiai EAeO. Iaaaaeai?
caeiiii??iino? i?inoaaeothoueny ye a ANAeA iaea?aeaieo c?ace?a
ni?aaioia, oae i a ?o aeaeo?iieo niaeo?ao o aeaeyae? noniaic?e a
aeioea?ei?. Iaeiae, aieia?noue c?ace?a oa niinia aei??thaaiiy niaeo??a
ia aieeaathoue ia aaoio?iiiee cnoa niaeo?aeueieo iaeneioiia aeey
ni?aaioo 3-AIA-EAeO (aaeni?aoe?y), a?aeiinii nenoaie A-380 – EAeO,
iaea?aeaii? a ?aeaioe/ieo oiiaao (((max ( 30 ii). Oeae cnoa oeieeii
iia’yca-iee ?c aieeaii ?iiii-annioe?aoeaiiai iaoai?cio aca?iiae??
aa?aieea c ai?iie?ai-iacaiiith iiaa?oiath.
?en. 4. Caeaaei?noue nooiaiy aeeo/aiiy Ii (VI) ? Ti (IV) ?c aiaeieo
?ic/ei?a a?ae pI na?a-aeiaeua. NMe=4*10-5 iieue/e; (ni?aoe?? = 30 oa;
t = 20±1°N; mni?aaioo = 0,1 a. Ni?aoe?y Ii (VI): 1 – ia aa?inee? A-380;
2 – ia 3-AIA-EAeO; Ni?aoe?y Ti (IV): 3 – ia aa?inee? A-380;
4 – ia 3-AIA-EAeO.
O i’yoiio ?icae?e? iaaaaeaii ?acoeueoaoe aea/aiiy ni?aoe?eii? aca?iiae??
?ii?a Ii (VI) ? Ti (IV) c iiaa?oiath 3-AIA-EAeO ? aa?ineeo A-380.
Ni?aoe?y ca-cia/aieo iaoae?a ia 3-AIA-EAeO oa?aeoa?eco?oueny cia/ii
a?eueoith oaeaee?noth anoaiiaeaiiy aaoa?iaaiii? ??aiiaaae, i?ae o
aeiaaeeo aa?ineeo A-380. Iaea?eueoa oaeaee?noue aca?iiae?? c
iiaeeo?ei-aaiei ni?aaioii aeinyaa?oueny i?e pI 1 ? 2 aeey ?ii?a Ii (VI)
? Ti (IV) a?aeiia?aeii. I?e oaeiio ?I na-?aaeiaeua /an aeinyaiaiiy
aaoa-?iaaiii? ??aiiaaae a nenoai?
«3-AIA-EAeO – iaoae» noaiiaeoue 5 – 10 oa, ia a?aei?io a?ae aa?ineeo
A-380, aeey yeiai oeae ia?aiao? cia/ii aeua (45-60 oa).
C iaoith aea/aiiy iniaee-ainoae aieeao ?I ?ic/eio ia ni?aoe?th Ii (VI) ?
Ti (IV) e?aiia-caiieie ni?aaioaie, aoee aei-ne?aeaeai? a?aeiia?aei?
caeaaeiino? S=f(pH). Iaaaaeai? ia ?en. 4 e?eai na?ae/aoue i?i ??ciee
oa?aeoa? ae?? eeneioiino? na?aaeiaeua ia aca?-iiae?th ?ii?a Ii (VI) c
iiaa?oiath 3-AIA-EAeO ? ay?ineeo A-380. E?euee?nia aeeo/aiy Ii (VI) ia
ni?aaio? 3-AIA-EAeO (S=98 %) aeinyaa?oueny i?e ?I 1, oiae? ye aeey
aa?ineeo A-380 – i?e ?I 3. Aeey ?ii?a Ti (IV) caeaaeiino? S=f(pH)
iathoue ?ioo oi?io (e?ea? 2, 4), ine?eueee aeey iaio aeine?aeaeaieo
iini?a ni?aoe?eiee i?ioean oneeaaeiaiee oae caaiith “a?ae?ie?oe/iith”
ni?aoe??th oeoaio a aeaeyaei Ti(OH)4. Iaeiae ia io?eiaieo e?eaeo iiaeia
aeae?eeoe a?ae??cie a ?ioa?aae? ?I 1,5-2,5, aea aeeo/aiiy aeaiiai iaoaeo
ia 3-AIA-EAeO ia 40-60% a?eueoa, i?ae ia aa?inee? A-380, ui na?ae/eoue
i?i ia?aaaaeii oaiini?aoe?eiee oa?aeoa? eiai aca?iiae?? c iiaa?oiath
iiaeeoieiaaiiai e?aiiacaio. Aaaeeeai, ui cia/aiiy pI e?euee?niiai
aeeo/aiiy ?ii?a Ii (VI) ? Ti (IV) ia ni?aaioi 3-AIA-EAeO ca?aathoueny c
iioeioiii eiiieaeniooai?aiiy oeeo iaoae?a c EAeO a ?ic/ei?.
Aeieacii oaiini?aoe?eiiai oa?aeoa?o aca?iiae?? aeine?aeaeo?ieo iaoae?a
c
3-AIA-EAeO ca ?aooiie ooai?aiiy iiaa?oiaaeo oaeao?a ? ?cioa?ie ni?aoe??
a eeneiio na?aaeiaeu? (?en. 5). Oae, ?cioa?ie ni?aoe?? Ii (VI) ? Ti (IV)
aeey iiaeeo?eiaaiiai ni?aaioo, ia a?aei?io a?ae aa?ineeo A-380, iathoue
I-oi?io (e?ea? 3, 4, 7, 8). O aeiaaeeo i?inoiai aa?ineeo oi?ia
iaaaaeaieo ?cioa?i aeey Ii (VI) (e?ea? 1, 2) iaeaaeeoue aei L-oeio.
Iaeiae, i?e ?I 3 oi?ia e?eai? icioa?ie ciiith?-oueny, ui iiynith?oueny
?noioiei aianeii oaiini?aoe?? ca ?aooiie eiiieaeniooai-?aiiy Ii (VI) ic
neeaiieueieie a?oiaie iiaa?oi? aa?ineeo A-380. Aeaiee oaeo
i?aeoaa?aeaeo?oueny aaeeeei eooii iaoeeo ii/aoeiaiai aiae??ceo
a?aeiia?aeii? e?eai?
?en. 5. ?cioa?ie ni?aoe?? iieiaaeaio (VI) (?en. A) ? oeoaio (IV) (?en.
A) ia aa?inee? A-380 ? 3-AIA-EAeO i?e ??cieo pI na?aaeiaeua. 1 –
Ii-A-380 (?I=3), 2 – Ii-A-380 (?I=1), 3 – Ii-3-AIA-EAeO (?I=1), 4 – Ii –
3-AIA-EAeO (?I=3); 5 – Ti – A-380 (?I=1), 6 – Ti – A-380 (?I=3), 7 – Ti
– 3-AIA-EAeO (?I=1), 8 – Ti – 3-AIA-EAeO (?I=2).
i?e ?I 3 ? cia/iith ni?aoe?eiith ?ii?noth aa?ineeo ii iie?aaeaio.
?cioa?ie ni?aoe?? ?ii?a Ti (IV) aa?ineeii A-380 o neeueiieeneioiiio
na?aaeiaeu? oaeiae iathoue L-oi?io, iaeiae i?e pI ( 3 niinoa??aa?oueny
ia?ao?ae aei N-oeio ?cioa?i (e?eaa 6), ui aeaco? ia ia?aaaaeii
“a?ae?ie?oe/io” ni?aoeith oeoaio.
Aeai? ANAeA i?aeoaa?aeaeothoue anoaiiaeai? caeiiii??iino? ni?aoei?
aeine?ae-aeoaaieo iiiia iaoae?a c 3-AIA-EAeO, ui i?iyaey?oueny a
cia/iiio aaoio?ii-iiio cnoa? iaeneioi?a niaeo??a cae??ieaieo eiiieaen?a
(((max = 70 – 80 ii) a?aeiinii aeo?aeiiai ni?aaioo. E??i oiai,
iayai?noue e?i?eii? ei?aeyoe?? cia/aiue ooieoe?? Eoaaeee-Ioiea (F(R)) c
eiioeaio?aoe??th cae??ieaiiai eiiieaeno aiaee?eaa? iiaeeeainoue
canoinoaaiiy ni?aaioo 3-AIA-EAeO o i?yiiio
oaa?aei-oacii-niaeo?ioioiiao?e/iiio aecia/aii? iieiaaeaio ? oeoaio.
Aeoiaey/e ?c ni?aoe?eieo ? niaeo?ineii?/ieo aeine?aeaeaiue, anoaiiaeaii
neeaae iiaa?oiaaeo eiiieaen?a ia?aieo iaoaeia, yeee aei??aith? EAeO:Ia =
2:1. Iiaeoaa?aeaeaiiyi oaeiai neeaaeo ? eiai caia c ni?aa?aeiioaiiyi
eiioeaio?aoei? EAeO ia iiaa?oii 3-AIA (1,8*10-4 iieue/a) oa na?aaeiuei?
ni?aoe?eii? ?iiino? 3-AIA-EAeO a?aeiinii Ii (VI) i Ti (IV) a
iioeiiciaaieo oiiaao (0,9*10-4 iieue/a).
O oinoiio ?icae?e? iiaeai? iaoiaeeee ni?aoe?eii-niaeo?ioioiiao?e/iiai
aecia/aiiy i?e?ie?eueeinoae Ii (VI), Ti (IV) ? Ga a i?e?iaei?o ia’?eoao
c aeei?enoaiiyi ni?aaioo 3-AIA-EAeO. Oiiae aecia/aiiy iioei?ciaai? ia
iiaeaeueieo nenoaiao, ui i?noyoue ?iie Nr (III), Nr (VI), Cu (II), Ni
(II), Ni (II), Zn (II), Mn (II), Pb (II), Cd (II), Fe (III), V (V), Sn
(IV). Aea?? iiaeaeueieo nenoai cae?enithaaee c o?aooaaiiyi neeaaeo
?aaeueieo c?ace?a.
Aeine?aeaeaiee ni?aaio 3-AIA-EAeO, caaaeyee caa??aaiith
eiiieaeniooai-?thth/i? ni?iiiaeiino? cae??ieaiiai ?aaaaioo aei ?yaeo
aaaaoica?yaeieo ?ii?a iaoae?a, iiaea c oni?oii canoiniaoaaoenue aeey ?o
ni?aoe?eii-niaeo?ioioi-iao?e/iiai aecia/aiiy. I?e oeueiio ni?aoe?eia
aeeo/aiiy oa?aeoa?eco?oueny aenieeie eiao?oe??ioaie eiioeaio?oaaiiy (aei
1*103). Aca?iiee caaaaeath/ee aieea ?ii?a, ui aca?iiae?thoue c EAeO ia
iiaa?oi? iiaeeo?eiaaiiai ni?aaioo, onoaaee ca aeiiiiiaith niaoe?aeueii
i?ae?a?aieo nenoai ianeoth/eo aaaio?a, ui i?noyoue ooi?eae-?iie,
anei?a?iiao ? o?iae?eieaao eeneioe.
Aoaeoeai?noue ?ic?iaeaieo iaoiaeee ni?aoe?eii-niaeo?ioioiiao?e/iiai
aecia/aiiy Ii (VI), Ti (IV) ? Ga aoei ia?aa??aii iaoiaeii
«aaaaeaii-ciaeaeaii» a iiaeaeueieo ?ic/eiao a i?enooiino? ?yaeo noiooi?o
(Nr (III), Nr (VI), Cu (II), Ni (II), Ni (II), Zn (II), Mn (II), Pb
(II), Cd (II)) oa caaaaeath/eo (Fe (III), V (V), Sn (IV)) ?ii?a iaoae?a
(oaae. 2). Aecia/aiiy cae?enithaaee ca aeiiiiiaith a?aaeoeiaaiiai
a?aoieo a oaeeo oiiaao: ?I 1 (Ii), ?I 2 (Ti, Ga); aeiaaeeia oaeei i?e
aeii?thaaii? cia/aiiy F(R) – (=610 ii (Ii) oa (=600 ii (Ti, Ga).
Oaaeeoey 2
?acoeueoaoe aecia/aiiy iie?aaeaio, oeoaio ? aae?th (Ia) a iiaeaeueieo
?ic-/eiao a i?enooiinoi iaaeeeoe?a noie noiooiio oa caaaaeath/eo ?ii?a
iaoaeia ((Ia), (?=0,95; n=5; Naeo?ae.(Ii, Ti, Ga) = 5*10-6 iieue/e;
mc=0,2 a; (n=15 oa.; V=200 ie)
Oe?eueiaee
?ii Ni?aa?aeiioaiiy Ia:(Ia* Ciaeaeaii
N ( (p, iieue/e
*105 Sr
Ii (VI) 1:1 1.00 ( 0.02 0.025
Ti (IV) – « – 0.99 ( 0.02 0.023
Ga – « – 1.01 ( 0.03 0.034
Ii (VI) 1:50 1.01 ( 0.02 0.024
Ti (IV) – « – 0.99 ( 0.03 0.028
Ga – « – 0.98 ( 0.03 0.028
Ii (VI) 1:100 1.02 ( 0.04 0.038
Ti (IV) – « – 0.99 ( 0.05 0.048
Ga – « – 1.02 ( 0.04 0.045
* – cacia/aii niiaaiaeiioaiiy noinothoueny eiaeiiai c i?enooiio ?ii?a
iaoaeia
sse aeaeii c oaae. 2, io?eiai? ?acoeueoaoe iathoue aeia?o
a?aeoai?thaaii?noue
(Sr ia ia?aaeuo? 0,048), a cai?iiiiiaaii ianeoth/? nenoaie aeicaieythoue
cia/ii i?aeaeueoe naeaeoeai?noue aecia/aiiy Ii (VI), Ti (IV) ? Ga
?ic?iaeaiei iaoiaeii ? aoaeoeai? aei 100-e?aoieo iaaeeeoe?a noiooiio oa
caaaaeath/eo ?ii?a iaoaeia.
Iaoiaeeee ni?aoe?eii-niaeo?ioioiiao?e/iiai aecia/aiiy Ii (VI), Ti (IV) ?
Ga aoee ai?iaiaai? ia c?aceao i?e?iaeiueiai iioiaeaeaiiy: ian?iii
aiaiaeo ?in-eei (Ii (VI)) ? iaei?aeao (Ti (IV), Ga). ?acoeueoaoe
aecia/aiiy a iioeiiciaaieo oiiaao iaaaaeai? a oaae. 3, 4.
Aeaii oaae. 3, 4 naiae/aoue i?i oa, ui iacaeaaeii a?ae iae?iiniiae
i?e-?iaeiueiai c?acea, eiai i?e?iaeaiaioiiai neeaaeo ? eiioeaio?aoe??
oe?eueiaiai eii-iiiaioo, ?acoeueoaoe aiae?co cai?iiiiiaaiei iaoiaeii
oa?aeoa?ecothoueny aeineoue aenieith a?aeoai?thaaii?noth (0,022 ( Sr (
0,062). E?ii oiai, e?aui iao?ieiai/ii oa?aeoa?enoeee niinoa?iaathoueny
i?e canoinoaaiii iaoiaeo noaiaea?ieo aeiaeaoeia. I?aaeeuei?noue
io?eiaieo ?acoeueoao?a eiio?iethaaee ?ioeie niaeo?ineii?/ieie
Oaaeeoey 3
?acoeueoaoe ni?aoe?eii-niaeo?ioioiiao?e/iiai aecia/aiiy Mo (VI) a
ia-n?ii? aiaiaeo ?ineei ?c canoinoaaiiyi 3-AIA-EAeO. (n=5; ?=0,95)
IAN?IIss NI?
Iaoiae a?aaeoeiaaiiai a?ao?ea Iaoiae noaiaea?oieo aeiaeaoe?a AAN***
? N(Ii) ± (P, ia/ea Sr N(Ii) ± (P, ia/ea Sr N(Ii) ± (P, ia/ea
Sr
I* 2.74 ± 0.14 0.057 2.77 ± 0.07 0.030 2.79 ± 0.18 0.074
2 4.72 ± 0.19 0.046 4.79 ± 0.14 0.025 4.69 ± 0.27 0.066
3 3.20 ± 0.14 0.051 3.22 ± 0.1 0.036 3.33 ± 0.18 0.062
4 3.16 +0.15 0.054 3.11 ±0. 08 0.027 3.05 ± 0.16 0.060
5 2.22 ± 0.10 0.044 2.20 ± 0.06 0.029 2.22 ± 0.12 0.056
IAN?IIss IOOA
1** 1.35 ± 0.07 0.055 1.37 ± 0.05 0.042 1,34 ± 0.08 0.071
2 0.88 ± 0.05 0.062 0.87 ± 0.04 0.047 0.87 ± 0.05 0.068
3 0.98 ± 0.05 0.057 1.02 ± 0.04 0.041 1.01 ± 0.06 0.066
*- iiia?aie iicia/ai? oae? ni?oe ni?: 1 – “THa-30”; 2 – “A?eaaeey
Iaeanneay”; 3 – “Iaeanneay-124”; 4 – “Iaeueie?a”; 5 – “Aeoycue-50”.
** – iicia/aiiy ni?o?a iooo: 1 – «Aieaia?aaeneee»; 2 –
“E?aniieooneee-123”; 3 – «Nia-oiciue-14»
*** – AAN – aoiiii-aani?aoe?eia niaeo?ineii?y c aoiiecaoe??th a iieoi’?
(aeai? iaaeai? Iaeanueeei aiioaoiieia?/iei ?inoeoooii)
iaoiaeaie – aoiiii-aani?aoe?eiei ? aoiiii-ai?n?eiei. Ieaeiy iaaea
aecia/aiiy aeine?aeaeoaaieo iaoae?a cai?iiiiiaaiei iaoiaeii neeaaea?
(C(-e?eoa??e): 1,5*10-7 % ian. (Ii), 2,5*10-7 % ian. (Ti), 2*10-7 % ian.
(Ga). Ii?yae c aenieith /ooee-a?noth, cai?iiiiiaai? iaoiaeeee
ni?aoe?eii-niaeo?ioioiiao?e/iiai aecia/aiiy i?e?ie?eueeinoae Ii (VI), Ti
(IV) ? Ga a i?e?iaei?o ia’?eoao c aeei?enoaiiyi ii-aiai
eiiieaeniooai?thth/iai ni?aaioo ia iniia? 3-ai?iii?ii?eaa?ineeo ?
ea?-aieneeae?ieneo?iiaiieo a?aecia/athoueny i?inoioith aeeiiaiiy ?
aeni?ani?noth.
Oaaeeoey 4
?acoeueoaoe ni?aoe?eii-niaeo?ioioiiao?e/iiai aecia/aiiy Ti (IV) ? Ga a
iaei?aeao c canoinoaaiiyi ni?aaioo 3-AIA-EAeO. (n=5, ?=0,95)
Oeoai (IV)
Iaoiae a?aaeoeiaaiiai a?ao?ea Iaoiae noaiaea?oieo aeiaeaoe?a AAN**
? C(Ti) ± (p, a/ea Sr C(Ti) ± (p, a/ea Sr C(Ti) ± (p, a/ea Sr
I* 3.84 ± 0,14 0.038 3.80±0.07 0.022 3.79 ± 0.25 0.075
2 3.72 ± 0,15 0.049 3.73 ± 0.08 0.025 3.69 ± 0.27 0.084
3 3.1 ± 0,10 0.042 3.15 ± 0.07 0.025 3.03 ± 0.18 0.068
4 3.36 ± 0,11 0.041 3.39 ±0.09 0.029 3.37 ± 0.28 0.094
5 3.76 ± 0,12 0.038 3.75 ± 0.09 0.028 3.70 ± 0.24 0.073
Aae?e
? C(Ga) ± (p, ia/ea Sr C(Ga) ± (p, ia/ea Sr C(Ga) ± (p, ia/ea Sr
1 1.97 ± 0.070 0.041 1.94 ± 0.06 0.034 2.03 ± 0.14 0.079
2 2.02 ± 0.09 0.053 1.98 ± 0.07 0.039 2.05 ± 0.15 0.082
3 2.89 ± 0.14 0.055 0.85 ± 0.10 0.039 2.87 ± 0.23 0.093
4 2.05 ± 0.08 0.042 2.08 ± 0.07 0.038 1.99 ± 0.21 0.120
5 1.59 ± 0.07 0.053 1.08 ± 0.06 0.041 1.60 ± 0.14 0.098
* – iiia?aie iicia/ai? aeoyaeee, io?eiai? c iaei?aeia, a?ae?a?aieo a
??cieo oi/eao Eoyeueieoeueeiai eeiaio (Iaeanueea iaeanoue);
** – AAN – aoiiii-ai?n?eia niaeo?ineii?y (aeai? iaaeai? Oe?IAe?
eo?i?oieia?? ? iaaee/-ii? ?aaa?e?oaoe??, i. Iaeana).
A caeeth/aiii, ia iiaenoaai ii?iaiyeueiiai aiaeico aenia?eiaioaeueieo oa
eioa?aoo?ieo aeaieo iieacaii aeaoa?iiioth/o ?ieue eeneioiinoi
na?aaeiaeua o aea-/aieo aaoa?iaaieo nenoaiao. Ae?y aeaiiai oaeoi?o
iieyaa? o aieea? ia noai ii-aa?oiaaeo ooieoe?iiaeueieo a?oi ni?aaioo oa
?iiii-iieaeoey?i? oi?ie aaeni?-aaoo. Aecia/ath/e a priori noai iiaa?oii
oa oi?ie aaeni?aaoo a caeaaeiino? a?ae ?I na?aaeiaeua, iiaeia
i?iaiicoaaoe iaoai?ci, ni?yiiaai?noue aaoa?iaaiii? aca?ii-aei? oa
o?i?ei-aiae?oe/i? aeanoeaino? ni?aaio?a, iaea?aeo?ieo ic canoinoaaiiyi
aaeni?aoeieiiai iaoiaeo iiaeeoieoaaiiy.
AENIIAEE
1. Aeine?aeaeaii e?iaoeeo, iaoai?cie ? nooo?ai oaeoi?e aaeni?aoe??
iio?aeieo
i-ae?ieneo?iiaiie?a c ??ciei ooieoe?iiaeueiei neeaaeii ia iiaa?oi?
aa?ineeo
A-380 ? 3-ai?iii?ii?eaa?ineeo. Iieacaii ?noioiee aieea eeneioiinoi
na?aaei-aeua (?I 0-7), a oaeiae aeith i?e?iaee, neeaaeo ?ic/eiieea oa
iiiii? neee ia aea/aii aaeni?aoeieii i?ioeane. Ia iiaenoaai ?ic?aoiaaieo
eiinoaio Aai?? anoaiiaeaii iiiioiee aianie ?ic/eiiinoi aaeni?aaoia o
aaee/eio ?o aaeni?aoei?, ii/eiath/e c ?I 5 i aeua. C aiaeico oi?i
icioa?i aeieacaii iiiii-anioeiaoeaiee iaoaiici aca?iiaei? eeneioieo
i-ae?ieneo?iiaiieia c iiaa?oiath 3-aiiiii?ii?eaa?ineeo.
2. Aia?oa, c aeei?enoaiiyi ?iiii-anioe?aoeaiiai iaoai?cio ?iiia?e?caoe??
i?aai?/iiai ?aaaaioo ia oaa?ae?e iiaa?oi? oa eiaaeaioiiai ca’ycoaaiiy
ea?aiae??i?aeiei iaoiaeii io?eiaii iiaee eiiieaeniooai?thth/ee ni?aaio
ia iniia? 3-ai?iii?ii?eaa?ineeo ? ea?aieneeae?ieneo?iiaiieo
(3-AIA-EAeO).
3. Aea/aii o?i?ei-aiae?oe/ii aeanoeainoi ni?aaioo 3-AIA-EAeO,
iaea?aeaiiai ??cieie iaoiaeaie. Onoaiiaeaii, ui aaeni?aoeieii
iiaeeoieiaaiee ni?aaio ca a?ae?ie?oe/iith no?eeinoth i?aeoe/ii ia
iinooia?oueny, a ca o?iiioi?ieie oa?aeoa?enoeeaie ia?aaa?oo? aiaeia,
neioaciaaiee eiaaeaioiei ca’ycoaaiiyi. Aeineiaeaeaii aieea
aiae?aoiaaiinoi e?aiiacaiii? iao?eoei i niiniao iiiiaieicaoei? ia
niaeo?ioioiiao?e/ii aeanoeainoi cae?iieaiiai ea?aieneeaeeieneo?iiaiieo.
4. Onoaiiaeaii caeiiii??iino? ni?aoe?eii? aca?iiae?? ?ii?a iie?aaeaio
(VI) ? oeoaio (IV) c 3-AIA-EAeO. Iieacaii, ui aeniea oaeaee?noue
aeinyaiaiiy aaoa?iaaiii? ??aiiaaae, ca?a iioeiaeueiiai cia/aiiy pI
ni?aoe?? c oiiaaie eiiieaeniooai?aiiy c EAeO a ?ic/ei?, ae?aaeaiee I-oei
?cioa?i, cia/iee ?ici?? aaoio?iiieo cnoa?a a niaeo?ao aeeooc?eiiai
a?aeaeooy (((max = 70-80 ii) iaeiicia/ii na?ae/aoue i?i oaiini?aoe?th
cacia/aieo iaoae?a ii cae??ieaiiio i?aai?/iiio ?aaaaioo Iioei?ciaai?
oiiae ni?aoe?eiiai aeeo/aiiy ?ii?a iieiaaeaio (VI) ? oeoaio (IV)
eiiieaeniooai?thth/ei ni?aaioii 3-AIA-EAeO.
5. ?ic?iaeaii iaoiaeeee naeaeoeaiiai ? /ooeeaiai
ni?aoe?eii-niaeo?ioioi-iao?e/iiai aecia/aiiy iieiaaeaio, oeoaio ? aae?th
c aeei?enoaiiyi ni?aaioo
3-AIA-EAeO a ia’?eoao i?e?iaeiueiai iioiaeaeaiiy – ian?iii aiaiaeo
?ineei ? e?eoaaeueieo ioeiaeo a?aeeeaaeaiiyo. Cai?iiiiiaai? iaoiaeeee
a?ae??ciythoueny iecueeith iaaeath aecia/aiiy 1,5*10-7 % ian. (Ii),
2,5*10-7 % ian. (Ti), 2*10-7 % ian. (Ga), aeia?ith a?aeoai?thaaii?noth
?acoeueoao?a aiae?co (0,022 ( Sr ( 0,062), i?inoioith aeeiiaiiy oa
aeni?ani?noth.
Iniiaiee ci?no aeena?oaoe?? aeeeaaeaii a oaeeo ioae?eaoe?yo:
*aaioa?aa A.I., Oao?ai E. E., Ai?enthe I. A., Oaioeth?a A. O.
Aaeni?aoeeiiiia acaeiiaeaenoaea ea?aieneeaeeieneo?iiaiiea n
iiaa?oiinoueth e?aiiacaiiuo ni?aaioia // Oe?. oei. aeo?i., 1995.- o.61,
? 12.-N.102-107.
*aaioa?aa A. I., Oao?ai E. E., Ai?enthe I. A. Oeceei-oeie/aneea
oa?aeoa?enoeee eiiieaeniia?acothuaai ni?aaioa ia iniiaa
3-aieiii?iieeay?ineea e ea?aieneeaeeieneo?iiaiiea // Oe?. oei.
aeo?i.,1996.- o. 62, ? 1.- N. 12 – 18.
*aaioa?aa A. I., Oao?ai E. E., Caeaiay A. A. Ni?aoeey iieeaaeaia (VI) e
oeoaia (IV) ia 3-aieiii?iieeay?ineea, iiaeeoeoee?iaaiiii
ea?aieneeaeeieneo?iiaiieii. // Oe?. oei. aeo?i., 1997, ? 10.-C. 132-137.
Shafran K. L., Chebotaryov A. N. Specificity of receiving,
physico-chemical and analytical properties of dispersed pyrogenic
silicas modified with o-dihydroxy-chromenols.//Proceedings of the
International Conference “Silica: from Sythesis to Application”, 1998,
Mulhouse, France.-P. 577-579.
Chebotaryov A.N., Shafran K.L. Physico-chemical properties and
analytical abilities of silica immobilized analytical organic reagents
of a o-dioxychromenols class.// International Congress on Analytical
Chemistry, Moscow, June 15-21, 1997.- V.1, P. D-25.
Oao?ai E. E. Eiiieaeniooai?thth/i ni?aaioe ia iniiai aii?oieo
e?aiiacaiia i i-ae?ieneo?iiaiieia oa ?o aiaeioe/ia canoinoaaiiy. –
?oeiien.
Aeena?oaoeiy ia caeiaoooy iaoeiaiai nooiaiy eaiaeeaeaoa oiii/ieo iaoe
ca niaoeiaeueiinoth 02.00.02 – aiaeioe/ia oiiiy. – Oiceei-oiii/iee
iinoeooo ii.
I.A. Aiaaonueeiai IAI Oe?a?ie, Iaeana, 1998.
Aeena?oaoeith i?enay/aii aeineiaeaeaiith eiiieaeniooai?thth/eo
ni?aaioia ia iniiai aii?oieo e?aiiacaiia i i-ae?ieneo?iiaiieia.
Onoaiiaeaii oiiiei-aiaeioe/ii oa?aeoa?enoeee ni?aaioia, iiaeeoieiaaieo
aaeni?aoeieiith i oiii/iith iiiiaieicaoei?th i-ae?ieneo?iiaiieia.
Aea/aii caeiiiii?iinoi ni?aoei? i iioeiiciaaii oiiae ni?aoeieiiai
aeeo/aiiy aaaaoica?yaeieo iiiia iaoaeia 3-aiiii-i?ii?eaa?ineeii,
iiaeeoieiaaiei ea?aieneeae?ieneo?iiaiieii. Cai?iiiiiaaii iaoiaeeee
ni?aoeieii-niaeo?ioioiiao?e/iiai aecia/aiiy iie?ieieueeinoae Ii (VI), Ti
(IV) oa Ga a i?e?iaeiio ia’?eoao aaaaoieiiiiiaioiiai neeaaeo.
Eeth/iai neiaa: aiaeic; iiie iaoaeia; ni?aoeiy; iiaeeoieiaaii
e?aiiacaie; oaa?aeioacia niaeo?ioioiiao?iy.
Oao?ai E.E. Eiiieaeniia?acothuea ni?aaiou ia iniiaa aii?oiuo e?aiiacaiia
e i-aeeieneo?iiaiieia, eo aiaeeoe/aneia eniieueciaaiea. – ?oeiienue.
Aeenna?oaoeey ia nieneaiea o/aiie noaiaie eaiaeeaeaoa oeie/aneeo iaoe ii
niaoeeaeueiinoe 02.00.02 – aiaeeoe/aneay oeiey. – Oeceei-oeie/aneee
einoeooo ei. A.A. Aiaaoneiai IAI Oe?aeiu, Iaeanna, 1998.
Aeenna?oaoeey iinayuaia enneaaeiaaieth eiiieaeniia?acothueo ni?aaioia ia
iniiaa aii?oiuo e?aiiacaiia e i-aeeieneo?iiaiieia. Onoaiiaeaiu
oeieei-aiaeeoe/aneea oa?aeoa?enoeee ni?aaioia, iiaeeoeoee?iaaiiuo
aaeni?aoeeiiiie e oeie/aneie eiiiaeeecaoeeae i-aeeieneo?iiaiieia.
Eco/aiu caeiiiia?iinoe ni?aoeee e iioeiece?iaaiu oneiaey ni?aoeeiiiiai
ecaea/aiey iiiaica?yaeiuo eiiia iaoaeeia 3-aieiii?iieeay?ineeii,
iiaeeoeoee?iaaiiiai ea?aieneeaeeieneo?iiaiieii I?aaeeiaeaiu iaoiaeeee
ni?aoeeiiii-niaeo?ioioiiao?e/aneiai ii?aaeaeaiey iee?ieiee/anoa Ii (VI),
Ti (IV) e Ga a i?e?iaeiuo iauaeoao neiaeiiai ninoaaa.
Eeth/aaua neiaa: aiaeec; eiiu iaoaeeia; ni?aoeey; iiaeeoeoee?iaaiiua
e?aiiacaiu; oaa?aeioaciay niaeo?ioioiiao?ey.
Shafran K.L. Chelating sorbents based on amorphous silicas and
o-dihydroxy-chromenols. – The manuscript.
The dissertation is for a scientific degree of the candidate of
chemical sciences in a specialty 02.00.02 – analytical chemistry. – A.V.
Bogatsky Physico-Chemical Institute, National Academy of Sciences of
Ukraine, Odessa, 1998.
The dissertation is devoted to the investigation of chelating sorbents
based on amorphous silicas and o-dihydroxychromenols. Physico-chemical
conditions of the receiving of sorbents, which are modified with
adsrotpion and chemical immobilization of o-dihydroxychromenols, have
been found. Conditions of the easily hydrolising
metals adsorption on 3-aminopropylaerosil modified with
o-dihydroxychromenol were determined. New methods of the
sorption-spectrophotometric determination of the Mo (VI), Ti (IV) and Ga
microamounts in environmental samples of a complex composition have been
suggested.
Key words: analysis; metal ions; adsorption; modified silicas; solid
phase spectrophotometry.
PAGE
PAGE 18
a*105,
iieue/a
a*105,
iieue/a
a*105,
iieue/a
A)
A)
A)
N?*105
iieue/e
N?*105
iieue/e
N?*105
iieue/e
a
a
a
a
S, %
a*105,
iieue/a
N?.105,iieue/e
N?.105,iieue/e
1
5
7
8
2
4
3
A)
A)
6
a*105,
iieue/a
0,0
4,0
8,0
12,0
16,0
0,0
4,0
8,0
12,0
16,0
0,0
4,0
8,0
12,0
0,0
4,0
8,0
12,0
?I
4
2
1
0
1
2
3
4
3
0,0
20,0
40,0
60,0
80,0
100,0
0
2
4
6
8
10
12
Naeani?a*105,
1
2
3
4
5
6
1
3
4
2
?I
iieue/e
420
460
500
540
580
4
2
3
5
0
2
4
6
8
10
l
, ii
?I
1
3
H
O
N
O
+
O
C
O
H
O
H
O
N
S i O 2
S i O 2
H
+
H
H
N
O
O
O
+
A-380-EAeO
A-380-IOAeO
A-380-NAeO
3-AIA-EAeO
3-AIA-IOAeO
3-AIA-NAeO
0,0
3,0
6,0
9,0
12,0
15,0
0,0
3,0
6,0
9,0
12,0
15,0
0,0
3,0
6,0
9,0
12,0
15,0
0,0
4,0
8,0
12,0
16,0
20,0
0,0
4,0
8,0
12,0
16,0
20,0
0,0
4,0
8,0
12,0
16,0
20,0
l
C
l
l
3
3
O
O
O
H
3
C
C
H
C
H
O
H
O
H
O
O
H
O
O
C
H
O
S
H
C
H
O
H
O
+
+
+
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