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Кінетика розкладу вищих аліфатичних одноосновних пероксикислот у водних лужних розчинах та їх реакції з люмінолом: Автореф. дис… канд. хім. наук / І

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EUeA?ANUeEEE AeA?AEAAIEE OI?AA?NEOAO

?iai? ?aaia O?aiea

CA??*IEE ?AI? IE?IIIAE*

OAeE 541.535

E?iaoeea ?iceeaaeo aeueo ae?oaoe/ieo iaeiiiniiaieo ia?ieneeeneio o
aiaeieo eoaeieo ?ic/eiao

oa ?o ?aaeoe?? c ethi?iieii

02.00.04- o?ce/ia o?i?y

AAOI?AOA?AO

aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy

eaiaeeaeaoa o?i?/ieo iaoe

EUeA?A – 1999

Aeena?oaoe?y ? ?oeiien.

?iaioa aeeiiaia ia eaoaae?? o?i?? oa o?ceee Euea?anueei? eiia?oe?eii?
aeaaeai??, Oeiiini?eea.

Iaoeiaee ea??aiee eaiaeeaeao o?i?/ieo iaoe, i?ioani?

Nei?iaiaaoee ss?ineaa Iao?iae/,

Euea?anueea eiia?oe?eia aeaaeai?y,

caa?aeoaa/ eaoaae?e o?i?? oa o?ceee

Io?oe?ei? iiiiaioe: aeieoi? o?i?/ieo iaoe, i?ioani?

Oo?ianueeee Aiaoie?e Aioiiiae/,

A?aeae?eaiiy o?ceei-o?i?? ? oaoiieia?? ai?th/eo

eiiaeei ?inoeoooo o?ce/ii? o?i??

?i. E. A. Iena?aeaanueeiai, caa?aeoaa/ a?aeae?eo

eaiaeeaeao o?i?/ieo iaoe, aeioeaio

Ae?a??aiee Aieiaeeie? Ieeieaeiae/,

Aea?aeaaiee oi?aa?neoao “Euea?anueea iie?oaoi?ea”,

aeioeaio eaoaae?e o?ce/ii? ? eiei?aeii? o?i??

I?ia?aeia onoaiiaa ?inoeooo o?ceei-i?aai?/ii? o?i?? ?
aoaeao?i??

?i. E. I. Eeoaeiaiea IAI Oe?a?ie, i. Aeiiaoeuee

Caoeno a?aeaoaeaoueny “ 16 ” aa?aniy 1999 ?ieo i 16 aiaeei? ia
can?aeaii? niaoe?ae?ciaaii? a/aii? ?aaee Ae 35.051.10 o Euea?anueeiio
aea?aeaaiiio oi?aa?neoao? ?iai? ?aaia O?aiea

( 290005, i. Euea?a, aoe. Ee?eea ? Iaoiae?y 6, o?i?/iee oaeoeueoao,
aoaeeoi??y N 2.)

C aeena?oaoe??th iiaeia iciaeiieoenue o iaoeia?e a?ae?ioaoe?
Euea?anueeiai aea?aeaaiiai oi?aa?neoaoo ?iai? ?aaia O?aiea ca aae?anith:
i. Euea?a, aoe. Ae?aaiiaiiaa, 5

Aaoi?aoa?ao ?ic?neaiee “ 12” na?iiy 1999 ?ieo

A/aiee nae?aoa?

niaoe?ae?ciaaii? a/aii? ?aaee
ss?aiei C. I.

CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE

Aeooaeueiith i?iaeaiith no/aniiai i?aai?/iiai neioaco, iniaeeai c oi/ee
ci?o c?inoath/eo aeiiii?/ieo ? aeieia?/ieo aeiia, ? i?aeaeuaiiy
oaeaeeino? ? naeaeoeaiino? i?ioean?a ??aeeiii-oaciiai ieeneaiiy
i?aai?/ieo ?a/iaei. Ia oeyoo ?? ae??oaiiy ia?niaeoeaiei ? aeei?enoaiiy
ae?oaoe/ieo ia?ieneeeneio, ye ieenethaa/?a. Niaoeeo?/i?noue aoaeiae
iiiiia?ieneeeneio aeicaiey? i?iaiaeeoe ?aaeoe?? ca ?o o/anoth a ??cieo
?ic/eiieeao, a aeniea ieenethth/a caeaoi?noue ? naeaeoeai?noue c?iaeea
?o oi?aa?naeueieie ieenieeaie aoaeaaiaei?a, oaiie?a, ai?i?a oa ?o
iio?aeieo, a?ae?ieneethth/eie aaaioaie oa niaoeeo?/ieie oeo?aioaie aeey
e?euee?niiai aecia/aiiy iaiane/aieo, acio- ? n??eiai?nieo niieoe.

Aaaeeeaei iai?yieii ? aeei?enoaiiy ia?ieneeeneio ye ?i?oe?thth/eo
aaaio?a aeey ?aaeeeaeueieo i?ioean?a, ye ioaa?aeaeoth/eo aaaio?a oa
a?aea?ethaa/?a. E??i oeueiai, ui?ac a?eueoa aeooaeueiei noa? ieoaiiy i?i
?o a?ieia?/io ?ieue o aiaeieo ?icaaaeaieo ?ic/eiao ? ia iiaa?oi?
iaia?ai. Iaeiae, ia aeaiee /an, naia aiaei? ?ic/eie ia?ieneeeneio ?
iaeiaioa aea/aieie. Iecueea ?o no?ee?noue iaiaaeo? aeei?enoaiiy ia
i?aeoeoe?. Ciaiiy iaoai?cio ? e?iaoe/ieo caeiiii??iinoae ?iceeaaeo
ia?ieneeeneio a oeeo oiiaao aeicaieeei a ?aaoethaaoe oeae i?ioean. A
naith /a?ao, aeine?aeaeaiiy ye?niiai oa e?euee?niiai neeaaeo i?iaeoeo?a,
ui ooai?ththoueny i?e ?iceeaae? ia?ieneeeneioe, cia/ii ?icoe?eei a
iiiyooy i?i ieenethth/o caeaoi?noue ia?ieneeeneio, ca?eueoeei a
iiaeeeaino? aeei?enoaiiy ia?ieneeeneio, iineeeei a ?o aoaeoeai?noue a
oaea ?nioth/eo oaoiieia?/ieo i?ioeanao, oiiaeeeaeei a eiio?ieue ca
ieenethaaeueieie i?ioeanaie, ye? a?aeaoaathoueny i?e caa??aaii? oa?/iaeo
i?iaeoeo?a /e iaoieia?/ieo ci?iao a aeeaeo i?aai?ciao.

Ca’ycie ?iaioe c iaoeiaeie i?ia?aiaie, ieaiaie, oaiaie. Aeaia ?iaioa ?
neeaaeiaith /anoeiith iaoeiaiai iai?yieo eaoaae?e o?i?? oa o?ceee
Euea?anueei? eiia?oe?eii? aeaaeai??. Aeeiiaiiy oe??? ?iaioe aoei
/anoeiai i?aeo?eiaia I?aeia?iaeiith Ni?in?anueeith i?ia?aiith i?aeo?eiee
ina?oe a aaeoc? oi/ieo iaoe (ISSEP).

Iaoa ? caaea/? ?iaioe. Ioe?ieoe noaa?euei?noue oa ieenethth/o
caeaoi?noue aeueo ae?oaoe/ieo iaeiiiniiaieo ia?ieneeeneio ?yaeo N8-N13 o
aiaeieo eoaeieo ?ic/eiao. Aeey oeueiai:

· aea/eoe e?iaoeeo ?iceeaaeo ia?ieneeeneio, caeaaei?noue ?? a?ae ??cieo
oaeoi??a ? nai?eoe ia oe?e iniia? e?iaoe/io iiaeaeue ?iceeaaeo
ia?ieneeeneio a neaaeieoaeiiio na?aaeiaeu?.

· ?aeaioeo?eoaaoe i?iaeoeoe ?iceeaaeo ia?ieneeeneio, anoaiiaeoe
iiaeeea?noue ?o e?euee?nii? ioe?iee ca ia?aiao?aie oai?ethi?ianoeaioe??
a ?aaeoe?? c ethi?iieii.

· aeine?aeeoe ?aaeoe?? aeueo iiiiia?ieneeeneio a i?oeaey?iiio
na?aaeiaeu?.

Iaoeiaa iiaecia iaea?aeaieo ?acoeueoao?a. Aeyaeaii o?niee ca’ycie
ia?aiao??a oai?ethi?ianoeaioe?? a nenoai? ethi?iie – ia?ieneeeneioa c
e?iaoeeith ?iceeaaeo ia?ieneeeneio.

A ?acoeueoao? aeeiiaii? ?iaioe:

· Aia?oa aea/aia e?iaoeea ?iceeaaeo aeueo ae?oaoe/ieo iaeiiiniiaieo
ia?iene-eeneio ?yaeo N8-N13 i?e ??cieo oaiia?aoo?ao. Ca?aeii
cai?iiiiiaaii? e?iaoe/ii? noaie ciaeaeaii eiinoaioe oaeaeeino? ?aaeoe?e,
ye? i?ecaiaeyoue aei ?iceeaaeo ia?ieneeeneioe oa aeoeaaoe?ei? ia?aiao?e
?iceeaaeo.

· Aia?oa ciyoi niaeo?e ethi?ianoeaioe??, ui aeieea? i?e ieeneaii?
ethi?iieo aeueie iiiiia?ieneeeneioaie. Anoaiiaeaii iniiai? i?ii?aei?
i?iaeoeoe ?iceeaaeo ia?ieneeeneio. Aeine?aeaeaii aieea oaiia?aoo?e ia
ia?aiao?e oai?ethi?ianoeaioe??.

· Aia?oa aea/aii i?oeaey?i? aeanoeaino? aiaeieo ?ic/ei?a aeueo
ae?oaoe/ieo iiiiia?ieneeeneio.

Ia iniia? aeine?aeaeaiue aieeao i?oeaeiooai?aiiy ia e?iaoeeo ?iceeaaeo
iiiiia?ieneeeneio oa ?aaeoe?th c ethi?iieii ?ic?iaeaii
oai?ethi?ianoeaioio iaoiaeeeo aecia/aiiy ?o e?eoe/ii? eiioeaio?aoe??
i?oeaeiooai?aiiy.

I?aeoe/ia cia/aiiy iaea?aeaieo ?acoeueoao?a. Iaaaaeai? a ?iaio?
?acoeueoaoe aeine?aeaeaiiy e?iaoeee ? oa?iiaeeiai?ee aeoeaaoe??
?iceeaaeo aeueo ae?oaoe/ieo iiiiia?ieneeeneio o aiaeieo eoaeieo ?ic/eiao
iiaeooue iaoe i?aeoe/iee ?ioa?an aeey o?i?? i?aai?/ieo ia?ieneaeieo
niieoe. Ciaiiy e?iaoeee ?iceeaaeo aeicaieeoue, aei aeayei? i??e,
ea?oaaoe i?ioeanii o aaaeaiiio iai?yieo. Aeyaeaii o?niee ca’ycie
ia?aiao??a oai?ethi?ianoeaioe?? a ?aaeoe?yo ieeneaiiy ethi?iieo
ia?ieneeeneioaie c e?iaoeeith ?o ?iceeaaeo, ui aea? ciiao ioe?ieoe ai?no
ei?ioeiaeeao/iai noia?ieneae ?ii-?aaeeeaeo a i?iaeoeoao ?iceeaaeo
ia?ieneeeneio. ?aeaioeo?eiaaii ai?oa? oai?ethi?ianoeaioe??. Ia iniia?
oai?ethi?ianoeaioe?? cai?iiiiiaaii oi?aa?naeueiee niin?a aecia/aiiy
e?eoe/ii? eiioeaio?aoe?? i?oeaeiooai?aiiy aeueo ae?oaoe/ieo
iaeiiiniiaieo ia?ieneeeneio, ui aeicaiey? aeine?aeeoe ?o
eiei?aeii-o?i?/i? aeanoeaino? o aiaeieo ?ic/eiao.

Iniaenoee aianie aaoi?a. Iinoaiiaea caaaeaiiy aeine?aeaeaiue
a?aeaoaaeanue ca aaciina?aaeiueith o/anoth aaoi?a. Iiooe ? ii?aoethaaiiy
e?oa?aoo?ieo aeaea?ae c aeine?aeaeoaaii? i?iaeaie, aenia?eiaioaeueia
?iaioa oa ?ioa?i?aoaoe?y io?eiaieo ?acoeueoao?a aeeiiai? aaoi?ii
iniaenoi.

Ai?iaaoe?y ?iaioe. Iaoa??aee aeena?oaoe?eii? ?iaioe aeiiia?aeaeeny oa
aoee iaaiai?ai? ia ?-iio neiiic?oi? o?i?/ii? eii?n?? iaoeiaiai
oiaa?enoaa ?i. O. Oaa/aiea, i?enay/aiiio iai’yo? aeaae. ?. Eo/a?a
(Euea?a, 18-20 aa?aciy 1993 ?.), iaoeia?e eiioa?aioe?? aei 150-??//y
“Euea?anueei? iie?oaoi?ee” (Euea?a, 17-19 o?aaiy 1994 ?.),
iaoeiai-i?aeoe/i?e eiioa?aioe?? “Euea?anuee? o?i?/i? /eoaiiy“,
i?enay/ai?e 50-??//th o?i?/iiai oaeoeueoaoo EAeO (Euea?a, 26 o?aaiy
1995 ?.).

Ioae?eaoe??. Iniiaiee ci?no aeena?oaoe?eii? ?iaioe aeeeaaeaii a 16
ae?oeiaaieo i?aoeyo, a oiio /ene? a naie iaoeiaeo noaooyo.

No?oeoo?a ? ia’?i ?iaioe. Aeena?oaoe?eia ?iaioa neeaaea?oueny ?c anooio,
i’yoe ?icae?e?a, aeniiae?a oa nieneo aeei?enoaieo e?oa?aoo?ieo aeaea?ae
(173 aeaea?aea). ?iaioa aeeeaaeaia ia 153 noi??ieao iaoeiiieniiai
oaenoo, i?noeoue 47 ?enoie?a oa 34 oaaeeoe?.

INIIAIEE CI?NO ?IAIOE

?ICAe?E 1. E?OA?AOO?IEE IAEssAe

Ocaaaeueiaii e?oa?aoo?i? aeai? i?i aeanoeaino? i?aai?/ieo ia?ieneeeneio
oa ?o iiaaae?ieo a ?ic/eiao, iaaaaeaii oa?aeoa?enoeeo caoaeaeaieo noai?a
iieaeoee eenith: neiaeaoiiai eenith ? noia?ieneae ?ii-?aaeeeaeo – ye
iiaeeeaeo aeoeaieo i?iaeoeo?a ?iceeaaeo aeueo ae?oaoe/ieo
iiiiia?ieneeeneio o aiaeiiio na?aaei-aeu?, iaaiai?aii o?i?ci aeieeiaiiy
oai?ethi?ianoeaioe?? i?e ieeneaii? ethi?iieo.

?ICAe?E 2. I*EUAIIss ?AAAAIO?A ? OAOI?EA AENIA?EIAIOO

Ia’?eoaie aeine?aeaeaiiy aoee aeu? ae?oaoe/i? iiiiia?ieneeeneioe ?yaeo
N8-N13. ?o neioacoaaee c a?aeiia?aeieo ea?aiiiaeo eeneio ? 30%
ia?ieneaeo aiaeith a n??/aiieeneiio na?aaeiaeu?. Ai?no iniiaii? ?a/iaeie
neeaaeaa ia iaioa 97%. Iaaaaeaii oa?aeoa?enoeeo ?ioeo aeo?aeieo ?a/iaei,
iaoiaeeee ?o iaea?aeaiiy /e iiia?aaeiuei? i/enoee.

I?e aea/aii? e?iaoeee ?iceeaaeo ia?ieneeeneio aeei?enoiaoaaee ia’?iiee
eiaeiiao?e/iee iaoiae. Aeey aecia/aiiy ia?ieneaeo aiaeith a ?aaeoe?ei?e
noi?o?, ui ooai?eany i?e a?ae?ie?c? ia?ieneeeneioe, aeei?enoiaoaaee
oeoaiiiao?e/iee iaoiae. Iioe/io aonoeio ?ic/ei?a aei??thaaee ia
oioieiei?eiao?? EOE-3, a niaeo?ioioiiao?e/i? aeine?aeaeaiiy i?iaiaeeee
ia niaeo?ioioiiao?ao Specord M40 ? NO-46. Cia/aiiy ?I ?ic/ei?a
aei??thaaee ia i?eeaae? ?I-150. Aeey oai?ethi?ian-oeaioieo
aeine?aeaeaiue canoiniaoaaee onoaiiaeo, ui neeaaeaeanue c
oioiaeaeo?e/iiai iiiiiaeoaa/a OYO-79 c iiae?ethaa/ai iai?oae, yeee
aeeaeoueny a?ae aenieiaieueoiiai noaa?e?caoi?a AN-22, aeaeo?iiiiai
i?aeneethaa/a iaeeo no?oi?a EIO-05, ?ioaa?aoi-?a E-02 ? naiiieoo/iai
iioaioe?iiao?a TZ 4620. Onoaiiaea aeicaiey? iaeii/anii iaea?aeaoe
e?iaoe/io e?eao oai?ethi?ianoeaioe?? ? noio na?oea ca iaaiee /an
aeniice-oe??. I?e aeine?aeaeaii? niaeo??a oai?ethi?ianoeaioe?? ?iceeaae
aei?ii?ithaaiiy cae?enithaaany ia iiiio?iiaoi?? IAe?-12 ? ?a?no?oaaany
oioiaeaeo?iiiei iiiiiaeoaa/ai OYO-100. Iooi?noue ?ic/ei?a ia?ieneeeneio
aecia/aee ia iaoaei-iao?? IOI c eooii ?icn?thaaiiy 1350, a iieaciee
caeiieaiiy – ia ?ao?aeoiiao?? E?O-23. An? ?ic/eie ?aaaaio?a
oa?iinoaooaaee c oi/i?noth wmetafile8? ??‰????????????
???????????yyy????.????1?????????????
?????&??yyyy?????Ayyy????A?????????&??MathType??
????u@y???????ICAe?E 3. CAEIIII??IINO? ?ICEEAAeO IIIIIA?IENEEENEIO
?ssAeO N8 – N13 O AIAeIEO EOAEIEO ?IC*EIAO

Ae?oaoe/i? iiiiia?ieneea?aiiia? eeneioe (IE) o aiaeieo ?ic/eiao
naii/eiii iaiai?ioiuei ?iceeaaeathoueny. Iaie anoaiiaeaii, ui
oaeaee?noue ?o ?iceeaaeo caeaaeeoue a?ae i?e?iaee ia?ieneeeneioe,
eeneioiino? ? oaiia?aoo?e ?aaeoe?eiiai na?aaeiaeua. No?ee?noue
aeine?aeaeoaaieo IE o aiaeieo ?ic/eiao a ?yaeo N8-N13 ciaioo?oueny.
Caeaaei?noue oaeaeeino? ?iceeaaeo IE a?ae ?I na?aaeiaeua ia?
aeno?aiaeueiee oa?aeoa?. Aaee/eia ?I, i?e ye?e a ?cioa?i?/ieo oiiaao
aeinyaa?oueny iaea?eueoa oaeaee?noue, aeey an?o ia?ieneeeneio
iaaeeaea?oueny aei cia/aiiy ?o ?Ea, ui ocaiaeaeo?oueny c oyaeaiiyie i?i
?iciaae ia?ieneeeneio /a?ac i?ii?aeiee eiiieaen, yeee ooai?th?oueny i?e
aca?iiae?? iieaeoee IE c ?? ia?ieneai?iiii. Oey noaae?y ? e?i?ooth/ith,
oiio i?ioean ?iceeaaeo iiaeiai iienoaaoeny e?iaoe/iei ??aiyiiyi ae?oaiai
ii?yaeeo. Aeyaeaii, ui caaaeueiee ii?yaeie ?iceeaaeo ca IE
iaaeeaea?oueny aei aeaio o?eueee i?e ?I??Ea ia?ieneeeneioe, a i?e aeueo
cia/aiiyo ?I a?i ciaioo?oueny. Oea aeaco? ia ia?aeaeueia i?io?eaiiy a
?aaeoe?ei?e nenoai? ?ioeo i?ioean?a, ye? ni?eythoue ?iceeaaeo IE ?
iineeththoueny o eoaeiiio na?aaeiaeu?, cie?aia – ?aaeoe?? a?ae?ie?co
ia?ieneeeneio, a ?acoeueoao? yei? ooai?th?oueny ia?ieneae aiaeith. C
e?oa?aoo?iiai iaeyaeo a?aeiii, ui a neaaeieoaeiiio na?aaeiaeu? ?aaeoe?y
a?ae?ie?co IE iieno?oueny e?iaoe/iei ??aiyiiyi ia?oiai ii?yaeeo.
Aeine?aeaeaiiy e?iaoeee iaeiie/aiiy ia?ieneaeo aiaeith a ?aaeoe?ei?e
noi?o? i?e ?iceeaae? ia?ieneeeneio iieacaei, ui ?o caeaoi?noue aei
a?ae?ie?co a ?yae? N8-N13 c?inoa?. Iaie anoaiiaeaii oaeiae, ui iaa?oue
iacia/i? aeiaaaee ia?ieneaeo aiaeith (10-4-10-3 I) a ?aaeoe?eio noi?o
iii?oii ca?eueoothoue oaeaee?noue ?iceeaaeo ia?ieneeeneio. I/aaeaeii,
ia?ieneae aiaeith i?eeia? o/anoue a i?ioean? ?iceeaaeo, aca?iiae?th/e c
ai?iiii IE. Aeeaae oe??? ?aaeoe?? a caaaeueiee i?ioean ?iceeaaeo
ia?ieneeeneioe ca?eueoo?oueny c ?inoii cia/aiiy ?I. Anoaiiaeaii ia?oee
ii?yaeie ?aaeoe?? ca ia?ieneeeneioith.

Oaeei /eiii, i?ioean ?iceeaaeo aeine?aeaeoaaieo ia?ieneeeneio o eoaeiiio
na?aaeiaeu? ? aaaaoinoaae?eiee ? i?io?ea? ca o?ueiia iniiaieie
iai?yieaie iaeii/anii. Ca iniiao aeey e?iaoe/ieo ?ic?aooie?a acyee
ianooiio noaio i?ioeano.

O aiaeiiio eoaeiiio ?ic/ei? ia?ieneeeneioa aeenioe?th?:

? aeae? i?ioiaeeoue ?? ?iciaae c ooai?aiiyi i?ii?aeieo eiiieaen?a ca
??aiyiiyie:

wmetafile8? ??e???I???????nG???
h?I??&?‘MDLSK?????a??X????Y????
?Arialx????8?9?a?K?”?0????„?
??8?9?a?K?”?0??yy?d*?*? ?0????OAI¤
Q?M?ei/?2i/?”

? ??a oaeaee?noue iaeiie/aiiy ia?ieneaeo aiaeith: wmetafile8? ????????????? ???????????yyy????.????1????????????? ????&??yyyy?????Ayyy?yyyA??O?????&??MathType??°? ???u?????????"????-?????H@????H‡???u?th??????aea k1, k2, k3 - a?aeiia?aeii eiinoaioe oaeaeeino? ?aaeoe?e a?ae?ie?co ia?ieneeeneioe (n-1) ? a?iieaeoey?ii? aca?iiae?? ia?ieneai?iio c IE ( I-1n-1) oa ia?ieneaeii aiaeith ( I-1n-1). wmetafile8? ??¬??? ???????? ?????????????yyy????.??????1????????????? ?`???&??yyyy?????Ayyy·yyy ??7?????&??MathType??p? ???u?th???????ic?aooiie a?aeiia?aeieo eiinoaio oaeaeeino? ?iceeaaeo aeine?aeaeoaaieo ia?ieneeeneio o aiaeieo eoaeieo ?ic/eiao iieacaa, ui aeeaae ie?aieo noaae?e a i?ioean ?iceeaaeo iaiaeiaeiaee ? caeaaeeoue ye a?ae i?e?iaee iiiiia?ieneeeneioe, oae ? a?ae ?I oa oaiia?aoo?e ?aaeoe?eiiai na?aaeiaeua. E?iaoe/ii aecia/ath/ith noaae??th ?iceeaaeo ? a?iieaeoey?ia aca?iiae?y ??cieo oi?i ia?ieneeeneioe (?aaeoe?y (3)). C ?inoii ?I iiaeeaeth?oueny eoaeiee a?ae?ie?c IE, yeee coiiaeth? c?inoaiiy ??aiiaaaeii? eiioeaio?aoe?? ia?ieneaeo aiaeith o ?ic/ei?, ui a naith /a?ao i?ecaiaeeoue aei ca?eueoaiiy aeeaaeo ?aaeoe?? ia?ieneai?iio c I2I2 a caaaeueiee i?ioean ?iceeaaeo. Oaeei /eiii, caaaeueia oaeaee?noue ? iioeiaeueia ?I ?iceeaaeo ia?ieneeeneioe ? ?acoeueooth/eie aaee/eiaie aeeaae?a aeae?eaieo ?aaeoe?e. Oaaeeoey 1. E?iaoe/i? oa aeoeaaoe?ei? ia?aiao?e ?aaeoe?? (2) a?ae?ie?co ae?oaoe/ieo iiiiia?ieneeeneio o aiaeieo eoaeieo ?ic/eiao i?e 298 E Oaaeeoey 2. E?iaoe/i? oa aeoeaaoe?ei? ia?aiao?e ?aaeoe?? (3) a?iieaeoey?ii? aca?iiae?? ae?oaoe/ieo iiiiia?ieneeeneio o aiaeieo eoaeieo ?ic/eiao i?e 298 E Oaaeeoey 3. E?iaoe/i? oa aeoeaaoe?ei? ia?aiao?e ?aaeoe?? (4) aca?iiae?? aeine?aeaeoaaieo iiiiia?ieneeeneio c ia?ieneaeii aiaeith i?e 298 E E?iaoe/i? oa aeoeaaoe?ei? ia?aiao?e ?aaeoe?e ?iceeaaeo iiiiia?ieneeeneio o aiaeieo eoaeieo ?ic/eiao iaaaaeai? a oaaeeoeyo 1-3. Ca?aeii oaaeeoeue, “a?eueia aia?a?y“ ia?ao?aeieo noai?a a ?yae? eeneio ci?ith?oueny iacia/ii, ui na?ae/eoue i?i ?aeeiee iaoai?ci ?o ?iceeaaeo. Aeineoue aaeee? iaaaoeai? cia/aiiy aio?ii?? aeey on?o o?ueio ?aaeoe?e ((2)-(4)) aeacothoue ia eieaeueia oii?yaeeoaaiiy no?oeoo?e IE o ?ic/eiao, yea a?aeaoaa?oueny ca ?aooiie ooai?aiiy aei?noeeo iiey?ieo aeoeaiaaieo eiiieaen?a ia?ieneai?iio c iieaeoeaie ia?ieneeeneioe, ia?ieneaeo aiaeith /e ?ic/eiieea, a oaeiae aeeia?ecaoe?? IE, ia ui aeacothoue iecuee? cia/aiiy i?aaeaeniiiaioe. Iaeiae, ?c ca?eueoaiiyi aioaeuei?? aeoeaaoe?? a ?yae? ia?ieneeeneio aaee/eie aio?ii?? aeoeaaoe?? c?inoathoue, ui coiiaeaii ciaioaiiyi nooiaiy aii?yaeeiaaiino? na?aaeiaeua, yea ioi/o? aeoeaiaaiee eiiieaen. Ooai?aiiy aeoeaiaaieo eiiieaen?a a ?ic/ei? i?e ?iceeaae? ia?ieneeeneioe ca ?aaeoe?yie (2)-(4) noi?iaiaeaeo?oueny ?ic?eaii iaaaeeei? e?eueeino? iayaieo aiaeiaaeo ca’yce?a i?ae iieaeoeaie ?ic/eiieea. A oiiaao aenia?eiaioo niinoa??aathoueny e?i?ei? caeaaeiino? i?ae aaee/eiaie wmetafile8? ??‰???????????? ???????????yyy????.????1????????????? ????&??yyyy?????AyyyayyyA?????????&??MathType?? ????u@y???????ICAe?E 4. OAI?ETHI?IANOeAIOI? ?AAEOe?? ETHI?IIEO C AE?OAOE*IEIE IIIIIA?IENEEENEIOAIE O EOAEIIIO NA?AAeIAEU? Aca?iiae?y 3-ai?iiooaeaaiai a?ae?aceaeo (ethi?iieo) c ae?oaoe/ieie ia?ie-neeeneioaie o eoaeiiio na?aaeiaeu? noi?iaiaeaeo?oueny aei?ii?ithaaiiyi na?oea. Ia ?enoieo 1 iaaaaeaii niaeo? oai?ethi?ianoeaioe?? i?e ieeneaii? ethi?iieo ia?ieneeai?eiiaith eeneioith. Anoaiiaeaii, ui eiai oa?aeoa? ia caeaaeeoue a?ae ?I na?aaeiaeua. Iaeneioi niaeo?o i?eiaaea? ia 445 ii. I?e ?iceeaae? niaeo?o aeyaeaii aea? ?iaeea?aeoaeuei? nioae c iaeneioiaie i?e 1 max= 433 ii, 2 max= 475 ii, ye? i?eienothoue ??ciei caoaeaeaiei noaiai 3-ai?iiooaeaoo, ui a?ae??ciythoueny ca nooeoo?ith. Aeine?aeaeaii niaeo?e oeoi?anoeaioe?? i?iaeoeo?a ieeneaiiy ethi?iieo, ye? aeia?a ocaiaeaeothoueny c niaeo?aie OE. Anoaiiaeaii oaeiae, ui oa?aeoa? niaeo?o caoaeaeaiiy OE ia caeaaeeoue a?ae i?e?iaee IE. Iaea?aeaiee niaeo? caaeia?eueii ni?aiaaea? c? niaeo?ii iiaeeiaiiy i?iaeoeo?a ieeneaiiy I2L. C i?iaaaeaieo aeine?aeaeaiue ne?aeo?, ui ai?oa?ii OE a ?aaeoe?yo ieeneaiiy ethi?iieo ae?oaoe/ieie iiiiia?ieneeeneioaie ? 3-ai?iiooaeao o caoaeaeaiiio noai?. Iaie anoaiiaeaii, ui ia?aiao?e oai?ethi?ianoeaioe?? caeaaeaoue a?ae i?e?iaee ia?ieneeeneioe, eiioeaio?aoe?? ?aaaoth/eo eiiiiiaio?a, ?I ? oaiia?aoo?e ?ic/eio. Caeaaei?noue iaeneiaeueii? ?ioaineaiino? na?/aiiy a?ae eeneioiino? na?aaeiaeua (?en.2) i?ioiaeeoue /a?ac ?en. 1. Niaeo? oai?ethi?ianoeaioe?? ethi?iieo i?e ieeneaii? eiai ia?ieneeai?eiiaith eeneioith (1) oa ?iaeea?aeoaeuei? nioae aei?ii?ithaaiiy (2,3). NIE =110-3 I, wmetafile8? ??TH???? ???????? ?????????????yyy????.??????1????????????? AA???&??yyyy?????Ayyy·yyy???w?????&? ?MathType???en.2.Caeaaei?noue iaeneiaeueii? ?ioaineaiino? aei?ii?ithaaiiy a?ae ?I aeey ia?ieneeeneio: 1 - N8, 2 - N9, 3 - N10, 4 - N12, 5 - N13. NIE = 1.010-3 I, wmetafile8? ??TH???? ???????? ?????????????yyy????.??????1?????? ???????AA???&??yyyy?????Ayyy·yyy???w?????&? ?MathType??aeno?aioi, ui niinoa??aa?oueny i?e ?I, aeecueeiio aei cia/aiiy ?Ea a?aeiia?aeii? ia?ieneeeneioe. Naia oe? oiiae ? iaeni?eyoeea?oeie aeey a?iieaeoey?iiai ?iceeaaeo IE ca ?aaeoe??th (3). Ia?aiao?e oai?ethi?ianoeaioe?? a aeine?aeaeoaai?e nenoai? caeaaeaoue a?ae oaeaeeino? ?iceeaaeo ia?ieneeeneioe. I?e oeueiio aei?ii?ithaa/ na?oea ooai?th?oueny a ?aaeoe?? aca?iiae?? ?aaeeeaeueii? oi?ie ethi?iieo c noia?ieneae ?ii-?aaeeeaeii, yeee aaia?o?oueny i?e ?iceeaae? IE. Ine?eueee cia/aiiy eiinoaioe oaeaeeino? ieeneaiiy ai?i?a oa ?o iio?aeieo noia?ieneaeii ? aeineoue aaeeea, iiaeia aaaaeaoe, ui e?i?ooth/ith noaae??th a i?ioean? oai?ethi?ianoeaioiiai ia?aoai?aiiy ethi?iieo ? ooai?aiiy ?ii-?aaeeeaeo wmetafile8? ????? ???????? ?????????????yyy????.??????1????????????? ?????&??yyyy?????Ayyy®yyy@??.?????&??MathType??P? ???u`y??????Iioeiaeuei? cia/aiiy ?I aeey noie na?/aiiy a ?aaeoe?yo a?aeiia?aeieo ia?ieneeeneio ci?uai? a?aeiinii ?o ?Ea (?en. 4) o eoaeio iaeanoue. Ia iao iiaeyae, oea coiiaeaia ianooiieie i?e/eiaie: - ca?eueoaiiyi eiioeaio?aoe?? ai?iiii? oi?ie ethi?iieo, yea i?e ieeneaii? ooai?th? ai?oa? oai?ethi?ianoeaioe??; - ca?eueoaiiyi a eoaeiiio na?aaeiaeu? /ano aeeooy noia?ieneaeo wmetafile8? ??TH???????????? ???????????yyy????.????1????????????? ?A???&??yyyy?????Ayyy?yyy?????????&? ?MathType??@????u?y??????- aeiaeaoeiaei aaia?oaaiiyi ?ii-?aaeeeaeo a ?aaeoe?? (4), yea ca?eueoo? na?e aianie a caaaeueiee i?ioean ?iceeaaeo IE i?e i?aeaeuaii? ?I. Uiaei inoaiiueiai aeniiaeo, iaie iieacaii, ui aeiaaaee ia?ieneaeo aiaeith a ?aaeoe?eio nenoaio e?i?eii ca?eueoothoue ?ioaineai?noue ? cia/ii i?iaeiaaeothoue o?eaa-e?noue oai?ethi?ianoeaioe??. Ia?aiao?e oai?ethi?ianoeaioe??, a aeaiiio aeiaaeeo aeia?a ocaiaeaeothoueny c caeiiii??iinoyie ?iceeaaeo IE (eiao?oe??ioe ia?ii? ei?aeyoe?? wmetafile8? ????????????? ???????????yyy????.????1????????????? A????&??yyyy?????AyyyAyyy@????????&? ?MathType??`????u?y?????? ?en.3. Caeaaei?noue iaeneiaeueii? ?ioaineaiino? na?/aiiy a?ae aoaeoeaii? eiinoaioe ?iceeaaeo ae?oaoe/ieo ia?ieneeeneio ?yaeo N8-N13 i?e 298 E ca ?aaeoe??th (3.3) i?e iioeiaeueieo cia/aiiyo ?I. NIE = 1.010-3 I, wmetafile8? ??TH???? ???????? ?????????????yyy????.??????1????????????? AA???&??yyyy?????Ayyy·yyy???w?????&??MathType???en. 4. Caeaaei?noue noia?iiai na?/aiiy a?ae ?I aeey ia?ieneeeneio: 1 - N8, 2 - N9, 3 - N10, 4-N12, 5 - N13. NIE = 1.010-3 I, wmetafile8? ??TH???? ???????? ?????????????yyy????.??????1?????? ???????AA???&??yyyy?????Ayyy·yyy???w?????&? ?MathType???iceeaaeo ia?ieneeeneio i?e aeiaeaaaii? a ?aaeoe?eio nenoaio ia?ieneaeo aiaeith a ?icae?e? 3 iiyniaii ca?eueoaiiyi aeeaaeo ?aaeoe?? I2I2 c ai?iiii IE (?aaeoe?y (4)) a caaaeueiee i?ioean ?iceeaaeo IE. C aeeeaaeaieo ?acoeueoao?a aeine?aeaeaiue i/aaeaeii, ui aeoeaiei i?iaeoeoii oe??? ?aaeoe?? ? noia?ieneae ?ii-?aaeeeae. Ca?eueoaiiy eiai eiioeaio?aoe?? a ?aaeoe?ei?e nenoai? i?e i?eoaeaeoaii? ?aaeoe?? (4) a eoaeiiio na?aaeiaeu? i?ecaiaeeoue aei c?inoaiiy ?ioaineaiino? ? noie na?/aiiy. Aea/aii aieea oaiia?aoo?e ia oai?ethi?ianoeaioio aeoeai?noue iiiiia?ieneeeneio a ?aaeoe?? c ethi?iieii. I?aeaeuaiiy oaiia?aoo?e ?aaeoeeeiiai na?aaeiaeua ca?eueoo? ?ioaineai?noue aei?ii?ithaaiiy i?e ieeneaii? ethi?iieo ia?ieneeao?eiiaith ? ia?ieneo?eaeaeaiiaith eeneioaie. Oaiia?aoo?ia aeoeaoaaiiy OE o oeueiio aeiaaeeo iia’ycaia ?c ca?eueoaiiyi oaeaeeino? ?o ?iceeaaeo, aiane?aeie /iai a ?aaeoe?ei?e noi?o? c?inoa? eiioeaio?aoe?y aeoeaieo i?iaeoeo?a, caeaoieo ieenethaaoe ethi?iie. Oiio iiaeia noaa?aeaeoaaoe, ui c?inoaiiy ?ioaineaiino? aei?ii?ithaaiiy i?e i?aeaeuaii? oaiia?aoo?e ?aaeoe?eiiai na?aaeiaeua coiiaeaia i?enei?aiiyi i?ioean?a oai?ethi?ianoeaioiiai ia?aoai?aiiy ethi?iieo. I?i oea na?ae/eoue oaeiae iaeaea iaci?iia cia/aiiy noie na?/aiiy i?e ??cieo oaiia?aoo?ao. Oaiia?aoo?ia caeaaei?noue iaeneiaeueii? ?ioaineaiino? aei?ii?ithaaiiy i?e iioeiaeueieo cia/aiiyo ?I a a??ai?on?anueeeo eii?aeeiaoao aeyaeeanue e?i?eiith. Ciaeaeai? aia?a?? aeoeaaoe?? oai?ethi?ianoeaioieo ?aaeoe?e aeey ia?ieneeao?eiiai? ? ia?ieneo?eaeaeaiiai? eeneio noaiiaeyoue, a?aeiia?aeii, 29,5 eAeae/iieue ? 23,8 eAeae/iieue ? ? cia/ii iaio? a?ae oaeeo aeey ?aaeoe?e ?iceeaaeo ia?ieneeeneio. Oea aea? i?aenoaao aaaaeaoe, ui ?aaeoe?? ?iceeaaeo IE ? e?i?ooth/eie a i?ioean? oai?ethi?-ianoeaioiiai ia?aoai?aiiy ethi?iieo ca o/anoth aeoeaieo i?iaeoeo?a ?iceeaaeo. Anoaiiaeaii, ui i?aeaeuaiiy oaiia?aoo?e ?aaeoe?eiiai na?aaeiaeua i?ecaiaeeoue aei cieaeaiiy aeoiaeo na?oea a ?aaeoe?? ethi?iieo c ieae/eie ia?ieneeen-eioaie aeine?aeaeoaaiiai ?yaeo. Aiae?c e?iaoeee ?o ?iceeaaeo a oiiaao oai?ethi?ianoeaioe?? iieacaa, ui oaeaee?noue ?o ?iceeaaeo ?c ca?eueoaiiyi oaiia?aoo?e c?inoa?, a oea ia ocaiaeaeo?oueny c ?acoeueoaoaie oai?ethi?ianoeaioe??. Ine?eueee a?aeiia?aeaeueiei ca oai?ethi?ianoeaioe?th ethi?iieo ? noia?ieneae wmetafile8? ????? ???????? ?????????????yyy????.??????1????????????? ?????&??yyyy?????Ayyy®yyy@??.?????&??MathType??P? ???u`y??????Iaaaaeaieie aeua aeine?aeaeaiiyie i?aeoaa?aeaeaii ooai?aiiy i?e ?iceeaae? aeueo ae?oaoe/ieo iiiiia?ieneeeneio noia?ieneae ?ii-?aaeeeaeo. I?i iayai?noue wmetafile8? ????? ???????? ?????????????yyy????.??????1????????????? ?????&??yyyy?????Ayyy®yyy@??.?????&??MathType??P? ???u`y??????wmetafile8? ??i???Ae???????;3/4??? ‰2Ae??&?MDLSK?????a??X????Y?????Arialx??? ?0?yyyy?2ecwQ?M?ei/?2i/??FYI/aaeaeii, ui wmetafile8? ??Oe???? ???????? ?????????????yyy????.??????1????????????? @ ???&??yyyy?????uyyy·yyy???/?????&??MathType??P? ???u y???????ICAe?E 5. EIEI?AeII-O?I?*I? AEANOEAINO? AIAeIEO ?IC*EI?A AEUEO AE?OAOE*IEO IIIIIA?IENEEENEIO ?ssAeO N8 - N13 Anoaiiaeaii, ui aeine?aeaeoaai? iiiiia?ieneeeneioe aieiae?thoue caeaoi?noth aei ooai?aiiy eiei?aeieo ?ic/ei?a, i?i ui na?ae/aoue iecuee? cia/aiiy e?eoe/ieo eiioeaio?aoe?e i?oeaeiooai?aiiy (EEI), iaaaaeai? a oaae. 4. I?e noaeiio cia/aii? ?I oa ?iiii? neee ?ic/eio caeaaei?noue ln EEI a?ae /enea a?oi (-NI2-) o aoaeaaiaeiaaiio ?aaeeeae? IE e?i?eia. Ciaeaeaia c oe??? caeaaeiino? aia?a?y ?ic/eiaiiy, ui i?eiaaea? ia iaeio (-NI2-) - a?oio (1,64 eAeae/iieue), aeia?a ni?aiaaea? c e?oa?aoo?ieie aeaieie, a cia/aiiy aia?a?? ?ic/eiaiiy ia?ieneea?aieneeueii? a?oie (2,19 eAeae/iieue) a ii??aiyii? c ea?aieneeueiith ? ieae/ei aiane?aeie iaioi? ?? iiey?iino? /a?ac ia?a?iciiae?e aeaeo?iiii? aonoeie ia aoiiao eenith. Oiio cia/aiiy EEI aeine?aeaeoaaiiai ?yaeo ia?ieneeeneio ? ia ii?yaeie ieae/eie ca a?aeiia?aei? aaee/eie aeey aeo?aeieo ea?aiiiaeo eeneio (oaae. 4.). Oaaeeoey 4. Cia/aiiy e?eoe/ii? eiioeaio?aoe?? i?oeaeiooai?aiiy ia?ieneeeneio Iieacaii, ui ca?eueoaiiy nooiaiy ?ii?caoe?? ia?ieneeeneioe, yea a?aeaoaa?oue-ny i?e i?aeaeuaii? oaiia?aoo?e /e ?I na?aaeiaeua, i?ecaiaeeoue aei c?inoaiiy aaee-/eie ?? EEI. Ca ni?aa?aeiioaiiyi Aeaaay aecia/aii i?oeaey?i? iane ? /enea aa?aaa-oe?? aeey ia?ieneo?eaeaeaiiai? eeneioe. A oaaeeoe? 5 iaaaaeaii cia/aiiy oeeo aaee/ei i?e ??cieo ?I na?aaeiaeua. sse aeaeii, ia?ao?ae aei aeueo cia/aiue ?I ni?ey? oe?oiiaiith aa?aaao?a. I?ney aeinyaiaiiy ?I=?Ea ia?ieneo?eaeaeaiiai? eeneioe ??no i?oeaey?ii? iane oiia?eueith?oueny, ui, i/aaeaeii, iiaycaii ?c ca?eueoaiiyi /anoee ?ii?ciaaieo iieaeoe IE a i?oeae? ? ?o aca?iiei aeaeo?inoaoe/iei a?aeooia- Oaaeeoey 5. Cia/aiiy i?oeaey?ieo ian oa /enae aa?aaaoe?? aeey ia?ieneo?eaeaeaiiai? eeneioe i?e *enei aa?aaaoe?? 209181183305390ooaaiiyi. I?e ?ic?aooieo /enae aa?aaaoe?? ia a?aoiaaii e?euee?noue iieaeoe nie?oo ? aiaee, ye? iiaeooue aoiaeeoe aei neeaaeo i?oeaee ? aeeaiei i?iieeaoe a na?aaeeio ?? yae?a. Oiio, ?aaeueii, oe? aaee/eie ? aeaui ieae/eie a?ae iaaaaeaieo a oaaeeoe? 5. Iieacaii, ui ooai?aiiy i?oeae ia?ieneeeneioe o aiaeiiio ?ic/ei? nooo?ai aieeaa? ia ?? no?ee?noue. I?e aeine?aeaeaii? caeaaeiino? oaeaeeino? ?iceeaaeo ia?ieneo?eaeaeaiiai? eeneioe a?ae ?? eiioeaio?aoe?? o ?ic/ei? iaie aeyaeaii, ui a iaeano? EEI a?aeaoaa?oueny ci?ia caaaeueiiai ii?yaeeo i?ioeano ?iceeaaeo ca IE, i?e/iio, eeneioi?noue na?aaeiaeua ii-??ciiio ci?ith? iaoee eiioeaio?aoe?eii? e?eai?. Ca?eueoaiiy caaaeueiiai ii?yaeeo ?iceeaaeo a?aeaoaa?oueny a neaaeieoaeiiio na?aaeiaeu? c ?I? ??a???????????? ???????????yyy????.????1????????????? ?A???&??yyyy?????Ayyy°yyy???°?????&? ?MathType??`????uAth??????O iaoiio aeiaaeeo oea iiaeia iia’ycaoe c iaeiie/aiiyi a nenoai? i?iaeoeo?a “oaiiiaiai” ieeneaiiy ethi?iieo, ye?, ye aeiaaaeaii a ?icae?e? 4, ? aan?yie oai?ethi?ianoeaioe??. ? ae?enii,i?e aeueo eiioeaio?aoe?yo ethi?iieo aeo?ae na?oea a oe?eiio ciaioo?oueny (?en. 6.), aea oa?aeoa? eiioeaio?aoe?eii? caeaaeiino? caeeoa?oueny iaeiaeiaei. sse iieaco? aeeoa?aioe?eia caeaaei?noue ia ?en. 7, ciaioaiiy na?oeiaiai aeoiaeo iacaeaaeii a?ae ai?noo ethi?iieo a ?aaeoe?ei?e nenoai? a?aeaoaa?oueny i?e eiioeaio?aoe?yo ia?ieneeeneioe, ui ni?aiaaeathoue c ?? EEI. Ia iniia? aeyaeaiiai aieeao i?oeaeiooai?aiiy IE ia ia?aiao?e oai?ethi?ianoeaioe?? a ?aaeoe?? c ethi?iieii, iaie cai?iiiiiaaii i?inoee ? c?o/iee iaoiae aecia/aiiy e?eoe/ii? eiioeaio?aoe?? i?oeaeiooai?aiiy aeueo iiiiia?ieneeeneio o aiaeieo eoaeieo ?ic/eiao. Nooue iaoiaeo iieyaa? o aei??thaaii? noia?iiai na?/aiiy i?e ieeneaii? ethi?iieo a aiaeiiio eoaeiiio na?aaeiaeu? ?ic/eiaie ia?ieneeeneioe ??cii? eiioeaio?aoe??. I?e oeueiio caeaaei?noue noia?iiai na?/aiiy a?ae eiioeaio?aoe?? IE e?i?eii c?inoa? ? aeinyaa? iane/aiiy. Eiioeaio?aoe?y ia?ieneeeneioe, ?en. 6. Caeaaei?noue noie na?/aiiy a?ae eiioeaio?aoe?? ia?ieneo?eaeaeaiiai? eeneioe i?e ??cieo eiioeaio?aoe?yo ethi?iieo: 1 - 410-4 I, 2 - 210-4 I, 3 - 110-5 I, 4 - 110-4 I, 5 -510-5 I. O = 298 E. ?en. 7. Aeeoa?aioe?eia caeaaei?noue noie na?/aiiy ia?ieneeao?eiiai? eeneioe a?ae ?? eiioeaio?aoe?? i?e: 1 - ?I = 8.5, 2 - ?I = 9.1, 3 - ?I = 9.5, 4 - ?I = 9.8, 5 - ?I = 10.4, 6 - ?I = 10.0, wmetafile8? ????? ???????? ?????????????yyy????.??????1?????? ???????``???&??yyyy?????Ayyy?yyy ???????&? ?MathType??p? ???u y?????? i?e ye?e niinoa??aa?oueny ceai eiioeaio?aoe?eii? e?eai?, a?aeiia?aea? EEI. Iienaiee oai?ethi?ianoeaioiee iaoiae aecia/aiiy EEI aeueo ae?oaoe/ieo iaeiiiniiaieo ia?ieneeeneio aea? caaeia?euei? ?acoeueoaoe (oaae. 6.) ? i?eaeaoiee aeey aeine?aeaeaiue a eoaeiiio na?aaeiaeu? c ?I = 8.5 - 11.0. AENIIAEE 1. Anoaiiaeaii, ui i?ioean ?iceeaaeo aeueo ae?oaoe/ieo iaeiiiniiaieo ia?ieneeeneio ?yaeo N8-N13 o aiaeieo neaaeieoaeieo ?ic/eiao cae?enith?oueny ia?aaaaeii ca ?iiiei iaoai?ciii. ?iceeaae aaaaoinoaae?eiee ? aeeth/a? o?e iniiai? iai?yiee: a?ae?ie?c ia?ieneeeneioe, aca?iiae?th ?ii?ciaaii? oa iieaeoey?ii? oi?ie IE i?ae niaith ? aca?iiae?th ia?ieneai?iio c ia?ieneaeii aiaeith, yeee ooai?eany i?e a?ae?ie?c? IE. Eiaeia ?aaeoe?y oa?aeoa?eco?oueny nai?ie e?iaoe/ieie oa aeoeaaoe?eieie ia?aiao?aie. Iaea?eueoa eiinoaioa oaeaeeino? niinoa??aa?oueny aeey ae?oai? ?aaeoe??, oiaoi a?iieaeoey?ia aca?iiae?y ??cieo oi?i ia?ieneeeneioe ? e?iaoe/ii aecia/aeueiith noaae??th ?iceeaaeo. 2. Ni?aa?aeiioaiiy aaaiiino? aeeaaeo aeae?eaieo ?aaeoe?e a noia?io oaeaee?noue ?iceeaaeo caeaaeeoue a?ae ?I na?aaeiaeua; iaeneiaeueia oaeaee?noue i?ioeano niinoa??aa?oueny i?e cia/aii? ?I, aeecueeiio aei ?Ea ia?ieneeeneioe, ine?eueee oe? oiiae ? iaeni?eyoeea?oeie aeey i?io?eaiiy a?iieaeoey?iiai ?iceeaaeo IE. 3. sse noia?ia oaeaee?noue ?iceeaaeo ia?ieneeeneioe, oae ? eiinoaioe oaeaeeino? iiiaeeiieeo ?aaeoe?e c?inoaee ?c ca?eueoaiiyi iieaeoey?ii? iane IE. 4. Aeey on?o o?ueio ?aaeoe?e ?iceeaaeo ia?ieneeeneioe aeyaeaii ?cie?iaoe/io caeaaei?noue i?ae aaee/eiaie S ? H. I?eiouaii, ui aeoeaaoe?y i?ioean?a ?iceeaaeo ia?ieneeeneioe cae?enith?oueny ca ?aooiie o?i?/ii? aca?iiae?? o ?ic/ei?. Ooai?aiiy iano?eeeo ia?ao?aeieo eiiieaen?a ia?ieneai?ii-aiaea, ia?ieneai?ii-iieaeoea IE, ia?ieneai?ii-ia?ieneae aiaeith i?e i?io?eaii? a?aeiia?aeieo ?aaeoe?e noi?iaiaeaeo?oueny ?ic?eaii iaaaeeei? e?eueeino? aiaeiaaeo ca’yce?a i?ae iieaeoeaie ?ic/eiieea. ?iciaae oaeiai eiiieaeno ia ea?aiiiao eeneioo ? eenaiue ? e?i?ooth/ei a i?ioean? ?iceeaaeo ia?ieneeeneioe. 5. A ?acoeueoao? aea/aiiy oai?ethi?ianoeaioii? ?aaeoe?? ethi?iieo c aeueie ae?oaoe/ieie iiiiia?ieneeeneioaie iieacaii, ui ai?oa?ii OE ? 3-ai?ii-ooaeao o caoaeaeaiiio noai?, yeee ooai?th?oueny i?e ieeneaii? ethi?iieo IE. 6. C’yniaaii, ui ieeneaiiy ethi?iieo aeueie iiiiia?ieneeeneioaie i?io?ea? ca aeaiia oeyoaie iaeii/anii: ia?oee - c aei?ii?ithaaiiyi na?oea, a ae?oaee - aacaei?ii?ithaaeueiee, noi?iaiaeaeo?oueny iaeiie/aiiyi a nenoai? i?iaeoeoo “oaiiiaiai” ieeneaiiy I2L, yeee aaneoue caoaeaeai? noaie ye naiiai ethi?iieo, oae ? eiai ieenieea - noia?ieneae ?ii-?aaeeeaeo. Iieacaii, ui i?aeaeuaiiy oaiia?aoo?e ?aaeoe?eiiai na?aaeiaeua i?ecaiaeeoue aei ca?eueoaiiy ?ioaineaiino? oai?ethi?ianoeaioe?? ethi?iieo c ia?ieneeao?eiiaith oa ia?ieneo?eaeaeaiiaith eeneioaie. Ciaioaiiy ?ioaineaiino? aei?ii?ithaaiiy o aeiaaeeo eiai aca?iiae?? c ieae/eie IE aeine?aeaeoaaiiai ?yaeo iia’ycaia c i?io?eaiiyi ?aaeoe?? a oeeo oiiaao ia?aaaaeii ii “oaiiiaiio“ oeyoo. 7. Anoaiiaeaii, ui ia?aiao?e oai?ethi?ianoeaioe?? ethi?iieo o?nii iia’ycai? c oaeaee?noth ?iceeaaeo ia?ieneeeneioe. Ooai?aiiy aei?ii?ithaa/a na?oea a?aeaoaa?oueny i?e aca?iiae?? ?aaeeeaeueii? oi?ie ethi?iieo c noia?ieneae ?ii-?aaeeeaeii wmetafile8? ????? ???????? ?????????????yyy????.??????1????????????? ?`???&??yyyy?????Ayyy®yyy ??.?????&??MathType??P? ???u`y??????8. I?iaeoeoaie ?iceeaaeo aeueo ae?oaoe/ieo iaeiiiniiaieo ia?ieneeeneio o aiaeieo eoaeieo ?ic/eiao ? noia?ieneae ?ii-?aaeeeae wmetafile8? ????? ???????? ?????????????yyy????.??????1????????????? ?`???&??yyyy?????Ayyy®yyy ??.?????&??MathType??P? ???u`y??????9. Anoaiiaeaii, ui aeu? ae?oaoe/i? iiiiia?ieneeeneioe ?yaeo N8-N13 i?iyaeythoue o aiaeieo ?ic/eiao cia/io iiaa?oiaao aeoeai?noue ? i?e aeueo eiioeaio?aoe?yo caeaoi? ooai?thaaoe eiei?aei? ?ic/eie. 10. Iieacaii, ui ci?ia no?oeoo?e ?ic/eio i?e ooai?aii? i?oeae ia?ieneeeneioe i?ecaiaeeoue aei ??cei? ci?ie e?iaoeee i?ioeano ?o ?iceeaaeo oa ia?aiao??a oai?ethi?ianoeaioe?? a ?aaeoe?? c ethi?iieii, ui aeaei ciiao cai?iiiioaaoe oi?aa?naeueio oai?ethi?ianoeaioio iaoiaeeeo aecia/aiiy e?eoe/ii? eiioeaio?aoe?? i?oeaeiooai?aiiy aeueo iiiiia?ieneeeneio o aiaeieo eoaeieo ?ic/eiao. Iaea?aeai? ?acoeueoaoe ni?aiaaeathoue c aeaieie aecia/aiiy EEI iaoaeiiao?e/iei ? ?ao?aeoiiao?e/iei iaoiaeaie. INIIAI? ?ACOEUeOAOE ?IAIOE AEEEAAeAII A IANOOIIEO IOAE?EAOe?ssO: 1. Nei?iaiaaoee ss.I., Ca??/iee ?.I., Caaa?ooa I.I., C?i/oe A.E. Aieea oaiia?aoo?e ia oai?ethi?ianoeaioio ?aaeoe?th ethi?iieo c ia?ieneeao?eiiaith eeneioith // A?ni. Euea?a. oi-oo. Na?. o?i. - 1994. - Aei. 33. - N. 90-93. 2. Ca??/iee ?.I. E?iaoeea ?iceeaaeo ia?ieneeao?eiiai? eeneioe o aiaeii-eoaeiiio ?ic/ei? // A?ni. Euea?a. oi-oo. Na?. o?i. - 1995. - Aei. 34. - N. 66-68. 3. Ca??/iee ?.I., Aooa I.I., Nei?iaiaaoee ss.I. Oaiia?aoo?ia aeoeaoaaiiy oai?ethi?ianoeaioe?? a ?aaeoe?? ethi?iie - ia?ieneeai?eiiaa eeneioa - Ni(??) ? aeei?enoaiiy eiai aeey aecia/aiiy eiaaeueoo // A?ni. Euea?a. oi - oo. Na?. o?i. - 1996. - Aei. 36. - N. 79-82. 4. Nei?iaiaaoee ss.I., Ca??/iee ?.I., Eaaaaeeiaoeue E.I., Caaa?ooa I.I. I?i iiaeeea?noue aecia/aiiy ia?ieneaeo aiaeith, ooai?aiiai i?e ?iceeaae? ia?ieneeai?eiiai? eeneioe o aiaeii-eoaeiiio ?ic/ei? // A?ni. Euea?a. oi-oo. Na?. o?i. - 1996. - Aei. 36. - N. 84-88. 5. Nei?iaiaaoee ss.I., Ca??/iee ?.I., C?i/oe A.E. Aieea oaiia?aoo?e ia oai?ethi?ianoeaioe?th a ?aaeoe?? ethi?iieo c aeayeeie ia?ieneeeneioaie // Oe?. o?i. aeo?i. - 1996. - O. 62, N 5. - N. 26-29. 6. Ca??/iee ?.I., Nei?iaiaaoee ss.I., Caaa?ooa I.I. Oa?i?/iee ?iceeaae ae?oaoe/ieo iaeiiiniiaieo ia?ieneeeneio ?yaeo N9 - N13 o aiaeieo eoaeieo ?ic/eiao // Oe?. o?i. aeo?i. - 1996. - O. 62, N 11. - N. 18-22. 7. Eiaaeue/oe ?.I., ?aoaoiye I.A., Iaieaae/ ?.A., Ca??/iee ?.I., Eiaaeeoei ss.N. Oai?ethi?ianoeaioe?y aiaeieo ?ic/ei?a ia?ieneaeenoeueoaoo iao??th ia iaai?? a i?enooiino? ae?oaoe/ieo nie?o?a oa aeeiaoeenoeueoieneaeo // Oe?. o?i. aeo?i. - 1998. - O. 64, N 7. - N. 20-23. 8. Nei?iaiaaoee ss., Caaa?ooa I., Ca??/iee ?. Oai?ethi?ianoeaioe?y ethi?iieo c ae?oaoe/ieie iiiiia?ieneeeneioaie a i?enooiino? noeueoaoo eiaaeueoo (??) // ? neiiic?oi o?i?/ii? eii?n?? IOO, i?enay/aiee iai’yo? aeaaeai?ea ?iiaia Eo/a?a. - Euea?a: IOO.- 1993. - N. 20. 9. Ca??/iee ?., Caaa?ooa I., C?i/oe A. Oaiia?aoo?ia caeaaei?noue oai?ethi?ianoeaioe?? ethi?iieo c ia?ieneeao?eiiaith eeneioith // ? neiiic?oi o?i?/ii? eii?n?? IOO, i?enay/aiee iai’yo? aeaaeai?ea ?iiaia Eo/a?a. - Euea?a: IOO. - 1993. - N. 35. 10. Ca??/iee ?.I., Caaa?ooa I.I., Nei?iaiaaoee ss.I. Oa?i?/iee ?iceeaae ia?ieneeao?eiiai? eeneioe o aiaeii-eoaeiiio na?aaeiaeu? // Oace aeiiia?aeae ia iaoe. eiio. ca i?aenoieaie IAe? o 1992-1993 ?.?. – Euea?a: EEA. – 1993. – N. 177. 11. Ca??/iee ?.I. Aieea ia?ieneaeo aiaeith ia oai?ethi?ianoeaioe?th a ?aaeoe?? ethi?iieo c ae?oaoe/ieie ia?ieneeeneioaie, eaoae?ciaai?e ?iiaie Ni (??) // Iaoe.-i?aeo. eiio. “Euea?anuee? o?i?/i? /eoaiiy”. - Euea?a: O?i?/ia eii?n?y IOO. - 1994. - N. 106. 12. Ca??/iee ?., Nei?iaiaaoee ss. I?i iniaeeaino? aieeao oaiia?aoo?e ia oai?ethi?ianoeaioio ?aaeoe?th ethi?iieo c ia?ieneeai?eiiaith eeneioith // Eiio. IOO aei 150-e?ooy Euea?anueei? iie?oaoi?ee. - Euea?a: Aea?ae. Oi-o “Euea?anueea iie?oaoi?ea”. - 1995. - N. 106. 13. Ca??/iee ?.I., Nei?iaiaaoee ss.I. Aieea ia?ieneaeo aiaeith ia oai?ethi?ianoeaioio ?aaeoe?th c ia?ieneeao?eiiaith eeneioith // Eiio. i?io.-aeeeaae. neeaaeo ? ani??aio?a EEA. – Euea?a: EEA. – 1995. – N. 214. 14. Ca??/iee ?.I. E?iaoeea ?iceeaaeo ae?oaoe/ieo ia?ieneeeneio ?yaeo N9-N13 o aiaeii-eoaeieo ?ic/eiao a i?enooiino? ethi?iieo // Eiio. i?io.-aeeeaae. neeaaeo ? ani??aio?a EEA. – Euea?a: EEA. – 1995. – N. 216. 15. Ca??/iee ?.I. I?i iaoai?ci oaiia?aoo?iiai aeoeaoaaiiy ? eaoae?coth/i? ae?? eiaaeueoo a ?aaeoe?? ethi?iieo c ae?oaoe/ieie ia?ieneeeneioaie // Eiio. i?io.-aeeeaae. neeaaeo ? ani??aio?a EEA. – Euea?a: EEA. – 1996. – N. 102. 16. Ca??/iee ?.I., Nei?iaiaaoee ss.I. Aeine?aeaeaiiy eiei?aeiiai noaio ae?oaoe/ieo iiiiia?eneeeneio o aiaeieo ?ic/eiao // Eiio. i?io.-aeeeaae. neeaaeo ? ani??aio?a EEA. – Euea?a: EEA. – 1997. – N. 262. Ca??/iee ?ai? Ie?iiiae/. E?iaoeea ?iceeaaeo aeueo ae?oaoe/ieo iaeiiiniiaieo ia?ieneeeneio o aiaeieo eoaeieo ?ic/eiao oa ?o ?aaeoe?? c ethi?iieii. – ?oeiien. Aeena?oaoe?y ia caeiaoooy iaoeiaiai nooiaiy eaiaeeaeaoa o?i?/ieo iaoe ca niaoe?aeuei?noth 02.00.04 - o?ce/ia o?i?y. - Euea?anueeee aea?aeaaiee oi?aa?neoao ?iai? ?aaia O?aiea, Euea?a, 1999 ?. Anoaiiaeaii, ui ?iceeaae aeueo ae?oaoe/ieo iiiiia?ieneeeneio (IE) o aiaeieo eoaeieo ?ic/eiao - oea aaaaoinoaae?eiee i?ioean, yeee i?io?ea? ca o?ueiia iniiaieie oeyoaie: a?ae?ie?c ia?ieneeeneioe ? a?iieaeoey?ia aca?iiae?y ia?ieneai?iio c iieaeoeaie IE /e ia?ieneaeo aiaeith. Ia/eneaii e?iaoe/i? oa aeoeaaoe?ei? ia?aiao?e i?eaaaeaieo ?aaeoe?e ?iceeaaeo. A oiiaao aenia?eiaioo aeyaeaii eiiiainaoe?eiee aoaeo. Iieacaii, ui ai?oa?ii oai?ethi?ianoeaioe?? ethi?iieo c iiiiia?ieneeeneioaie ? 3-ai?iiooaeao o caoaeaeaiiio noai?, a aeoeaieie i?iaeoeoaie ?iceeaaeo IE ? noia?ieneae ?ii-?aaeeeae ? neiaeaoiee eenaiue. Aecia/aii e?eoe/i? eiioeaio?aoe?? i?oeaeiooai?aiiy IE o aiaeieo ?ic/eiao. Ia iniia? aeine?aeaeaiue aieeao i?oeaey?iiai na?aaeiaeua ia?ieneeeneioe ia e?iaoeeo ?? ?iceeaaeo ? ia?aiao?e oai?ethi?ianoeaioe?? c ethi?iieii cai?iiiiiaaii oai?ethi?ianoeaioiee iaoiae aecia/aiiy EEI aeueo iiiiia?ieneeeneio Eeth/ia? neiaa: aeu? ae?oaoe/i? iiiiia?ieneeeneioe, oai?ethi?ianoeaioe?y, ethi?iie, i?oeaeiooai?aiiy, oai?ethi?ianoeaioiee iaoiae. Ca?e/iue Eai?ue Ie?iiiae/. Eeiaoeea ?aniaaea aunoeo aeeoaoe/aneeo iaeiiiniiaiuo ia?ieneeeneio a aiaeiuo uaei/iuo ?anoai?ao e eo ?aaeoeee n ethieiieii. – ?oeiienue. Aeenna?oaoeey ia nieneaiea iao/iie noaiaie eaiaeeaeaoa oeie/aneeo iaoe ii niaoeeaeueiinoe 02.00.04 - oece/aneay oeiey. - Eueaianueeee ainoaea?noaaiiee oieaa?neoao eiaie Eaaia O?aiei, Eueaia, 1999 a. Aeenna?oaoeeiiiay ?aaioa niaea?aeeo ?acoeueoaou enneaaeiaaiee eeiaoeee ?aniaaea aunoeo aeeoaoe/aneeo iiiiia?ieneeeneio a aiaeiuo ?anoai?ao e eeiaoeee oaieethieianoeaioeee ethieiiea i?e ieeneaiee aai iiiiia?ieneeeneioaie. Onoaiiaeaii, /oi ?aniaae aunoeo aeeoaoe/aneeo iiiiia?ieneeeneio a aiaeiuo uaei/iuo ?anoai?ao – iiiainoaaeeeiue i?ioean, eioi?ue i?ioaeaao ii o??i iai?aaeaieyi iaeiia?aiaiii: aeae?ieec ia?ieneeeneiou e aeiieaeoey?iia acaeiiaeaenoaea ia?ieneaieiia eee n iieaeoeie IE, eee n iieaeoeie ia?aeene aiaei?iaea, eioi?ue ia?acoaony a ia?aie ?aaeoeee. Iaeaeaii eeiaoe/aneea e aeoeaaoeeiiiua ia?aiao?u i?eaaaeaiuo ?aaeoeee. Iieacaii, /oi noaaeeueiinoue ia?ieneeeneio a ?yaeo N8-N13 oiaiueoaaony, a niiniaiinoue e uaei/iiio aeae?ieeco aic?anoaao. Niioiioaiey aeeaaeia auaeaeaiiuo ?aaeoeee a noia?ioth nei?inoue ?aniaaea caaeneo io ?I n?aaeu. Eeiaoe/anee ii?aaeaeythuae ?aaeoeeae yaeyaony aeiieaeoey?iia acaeiiaeaenoaea ?acee/iuo oi?i ia?ieneeeneiou, ii-yoiio iaeneiaeueiay nei?inoue i?ioeanna ?aniaaea iaaethaeaaony i?e cia/aieyo ?I aeeceeo e ?Ea ia?ieneeeneiou. Aeey ?aaeoeee ?aniaaea onoaiiaeai eiiiainaoeeiiiue yoaeo. I?aaeiieaaaaony, /oi aeoeaaoeey i?ioeannia ?aniaaea ia?ieneeeneiou inouanoaeyaony ca n/ao oeie/aneiai acaeiiaeaenoaey a ?anoai?a. Ia?aciaaiea ianoieeeo ia?aoiaeiuo eiiieaenia ia?ieneaieii-aiaea, ia?ieneaieii-iieaeoea IE, ia?ieneaieii-ia?ieneae aiaei?iaea nii?iaiaeaeaaony ?ac?uaii iaaieueoiai eiee/anoaa aiaei?iaeiuo naycae iaaeaeo iieaeoeaie ?anoai?eoaey. ?aniaae oaeiai eiiieaena ia ea?aiiiaoth eeneioo e eenei?iae – eeieoe?othuee a i?ioeana ?aniaaea ia?ieneeeneiou. I?e enneaaeiaaiee oaieethieianoeaioiuo ?aaeoeee ethieiiea n iiiiia?ieneeeneioaie onoaiiaeaii oanioth naycue iaaeaeo ia?aiao?aie OE e nei?inoueth ?aniaaea IE. Aia?aua eco/ai niaeo? eceo/aiey. Iieacaii, /oi yiieoa?ii oaieethieianoeaioeee anoue 3-aieiiooaeao a aicaoaeaeaiiii ninoiyiee, a iniiaiuie i?iaeoeoaie ?aniaaea ia?ieneeeneio – noia?ieneae eii-?aaeeeae wmetafile8? ????? ???????? ?????????????yyy????.??????1????????????? ?`???&??yyyy?????Ayyy®yyy ??.?????&??MathType??P? ???u`y??????Onoaiiaeaii, /oi ieeneaiea ethieiiea iiiiia?ieneeeneioaie i?ioaeaao ii aeaoo iooyo iaeiia?aiaiii – n eceo/aieai naaoa, e aac eceo/aiey. A iineaaeiai neo/aa a ?anoai?a iaeaieeaaaony i?iaeoeo “oaiiiaiai” i?aa?auaiey ethieiiea, eioi?ue oooeo aicaoaeaeaiiua ninoiyiey eceo/aoaey naaoa e aeacaeoeae?oao iaiaoiaeeiue aeey oaieethieianoeaioeee noia?ieneae wmetafile8? ????? ???????? ?????????????yyy????.??????1????????????? ?`???&??yyyy?????Ayyy®yyy ??.?????&??MathType??P? ???u`y??????Iaia?oaeaii, /oi aunoea aeeoaoe/aneea ia?ieneeeneiou a aiaeiuo ?anoai?ao niiniaiu ia?aciauaaoue eieeieaeu. Ii?aaeaeaiu eo e?eoe/aneea eiioeaio?aoeee ieoeaeeiia?aciaaiey. Aeey ia?ieneo?eaeaeaiiaie eeneiou iaeaeai ieoeaey?iue aan e /enea aa?aaaoeee i?e ?aciuo cia/aieyo ?I. Eciaiaiea no?oeoo?u ?anoai?a i?e ia?aciaaiee ieoeaee IE aaaeao e ?aceiio eciaiaieth eeiaoeee eo ?aniaaea e ia?aiao?ia oaieethieianoeaioeee a ?aaeoeee n ethieiieii, /oi eniieueciaaii iaie i?e ?ac?aaioea oieaa?naeueiie oaieethieianoeaioiie iaoiaeeee ii?aaeaeaiey EEI aunoeo iiiiia?ieneeeneio a aiaeiuo uaei/iuo ?anoai?ao. Eeth/aaua neiaa: aunoea aeeoaoe/aneea iiiiia?ieneeeneiou, oaieethieian-oeaioeey, ethieiie, ieoeaeeiia?aciaaiea, oaieethieianoeaio-iue iaoiae. Zarichniy Igor Mironovich. The kinetic of high aliphatic monobasic peroxyacids decomposition in aqueous basic solutions and their reactions with luminol. - Manuscript. Thesis for obtaining the scientific degree of Candidate of Chemical Sciences by speciality 02.00.04 - Physical Chemistry, I. Franko L’viv state university, L’viv, 1999. It is determined that decomposition of high aliphatic monobasic peroxyacids in aqueous basic solutions is multistage process, which carries out by three main ways: hydrolyseys of peroxyacids and bimolecular interaction of peroxyanion with peroxyacids molecules or with hydrogen peroxydes molecules. The kinetic activate parameters of these reactions are calculated. Compensative effect in conditions of experiment is discovered. It is showed that the emitter of chemiluminescence of luminol with monoperoxyacids is excited form 3-aminophtalate, but the active products of peroxyacids decompositions are superoxyde ion-radical and singlet oxygen. The critical concentrations of peroxyacids micelloformation in aqueous solutions are determined. On the base of investigates of peroxyacids micellar mediums influence on the kinetic of its decomposition and parameters of its chemiluminescence with luminol the chemiluminescent method of the determination of high monoperoxyacids CCM is proposed. Keywords: high aliphatic monoperoxyacids, chemiluminescence, luminol, micelloformation, chemiluminescent method.

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