Aea?aeaaiee oi?aa?neoao “Euea?anueea iie?oaoi?ea”
Iaeueiee ?ai? ?aaiiae/
OAeE 621.383
?ic?iaea iiaeo iaoiae?a i?aeaeuaiiy
aoaeoeaiino? e?aii??aeo oioiaeaeo?e/ieo
ia?aoai?thaa/?a niiy/ii? aia?a??
05.27.01 – oaa?aeio?eueia aeaeo?ii?ea
AAOI?AOA?AO
aeena?oaoe?? ia caeiaoooy iaoeiaiai nooiaiy
eaiaeeaeaoa oaoi?/ieo iaoe
Euea?a – 1999
Aeena?oaoe??th ? ?oeiien.
?iaioa aeeiiaia ia eaoaae?? iai?ai?ia?aeieeiai? aeaeo?ii?ee Aea?aeaaiiai
oi?aa?neoaoo “Euea?anueea iie?oaoi?ea”, I?i?noa?noai ina?oe Oe?a?ie.
Iaoeiaee ea??aiee – aeieoi? o?ceei-iaoaiaoe/ieo iaoe, i?ioani?
Aoaeaeae ss?ineaa Noaiaiiae/,
Aea?aeaaiee oi?aa?neoao “Euea?anueea iie?oaoi?ea”,
i?ioani?.
Io?oe?ei? iiiiaioe: aeieoi? oaoi?/ieo iaoe, i?ioani?
Aio?a Caiii TH??eiae/,
Aea?aeaaiee oi?aa?neoao “Euea?anueea iie?oaoi?ea”,
caa?aeoaa/ eaoaae?e;
aeieoi? o?ceei-iaoaiaoe/ieo iaoe, i?ioani?
Aeieo?oe Ieeiea Eaiio?eiae/,
?inoeooo o?ceee iai?ai?ia?aeiee?a IAI Oe?a?ie,
caa?aeoaa/ a?aeae?eo.
I?ia?aeia onoaiiaa – Iaoeiai-ae?iaie/a ia’?aeiaiiy “Ea?ao”,
a?aeae?e iiaeo i?ia?aneaieo oaoiieia?e,
I?i?noa?noai i?iieneiai? iie?oeee (i. Euea?a).
Caoeno a?aeaoaeaoueny 18 /a?aiy 1999 ?. i 14 aiae. ia can?aeaii?
niaoe?ae?ciaaii? a/aii? ?aaee Ae 35.052.14 i?e Aea?aeaaiiio oi?aa?neoao?
“Euea?anueea iie?oaoi?ea” (290646, Euea?a-13, aoe. N. Aaiaea?e, 12).
C aeena?oaoe??th iiaeia iciaeiieoenue o iaoeia?e a?ae?ioaoe?
Aea?aeaaiiai oi?aa?neoaoo “Euea?anueea iie?oaoi?ea” (aoe. I?ioani?nueea,
1).
Aaoi?aoa?ao ?ic?neaiee “ 15 ” o?aaiy 1999 ?.
A/aiee nae?aoa?
niaoe?ae?ciaaii? a/aii? ?aaee Aaeoea? ?.?.
CAAAEUeIA OA?AEOA?ENOEEA ?IAIOE
Aeooaeuei?noue oaie. ?acoeueoaoii ?ioaineaiiai ?icaeoeo oioiaeaeo?e/ieo
ia?aoai?thaa/?a (OAI) niiy/ii? aia?a?? ca aeaa inoaii? aeanyoee?ooy
noaei oe?iea ai?iaaaeaeaiiy niiy/ieo aeaiaio?a (NA) aeey aeeaeaiiy
??ciiiai?oieo iaeiiiooaeieo aeaeo?iiieo i?eno?i?a. Iaeiae o ca’yceo ?c
aeniaaeaiiyi caian?a aia?aaoe/ii? ne?iaeie ia Caie? oa aacia?a?aiei
c?inoaiiyi iio?aa ethaenoaa o aeaoaa?e aeieia?/ii /eno?e aeaeo?iaia?a??
iinoa? ieoaiiy i?i ?icaeoie aenieiiiooaeii? niiy/ii? aia?aaoeee, yea
ciiaea a eiieo?oaaoe c o?aaeeoe?eieie iaoiaeaie ?aia?aoe??
aeaeo?iaia?a??. Aeiiaaie aei NA aenieiiiooaeii? aia?aaoeee ? ianooii?
e?eoa???: aeniea aoaeoeai?noue ?iaioe; oaoiieia?/ia i?inoioa ? iecueea
aa?o?noue iaea?aeaiiy; aeinoaoiy aea(?aaeaoe?eia no?ee?noue. Ia oeae /an
OAI a?aeiia?aeathoue iaaaaeaiei aeiiaai ia a iiai?e i??? e iaaeae?
caeeoathoueny iecueei?aioaaaeueieie o oe?ieiianooaaiiio aeei?enoaii?.
Aeey i?aeaeuaiiy ?aioaaaeueiino? aenieiiiooaeieo aae?inenoai, ye
i?aaeei, aeei?enoiaothoue aeaa i?aeoiaee. Aeey ia?oiai c ieo oa?aeoa?i?
caoiaee c i?aeaeuaiiy eiao?oe??ioa ei?enii? ae?? (EEAe) NA. Ca?aeii ?c
ae?oaei iaeneiaeueio oaaao i?eae?eythoue ni?iuaiith oa caeaoaaeaiith
oaoiieia?? ae?iaieoeoaa OAI. O a?aeiia?aeiino? c ia?oei i?aeoiaeii
iniiaith aenieiiiooaeii? niiy/ii? aia?aaoeee noaee e?aii??a? NA c
aeeooc?eiei p-n- ia?aoiaeii, aeey yeeo aeinyaiooi iaeaeu? cia/aiiy EEAe.
Iaeiae, iacaaaeath/e ia aenieo aoaeoeai?noue, ?aioaaaeuei?noue oeeo NA ?
iaaeinoaoiuei aenieith aiane?aeie cia/ii? oaoiieia?/ii? neeaaeiino? ?o
aeaioiaeaiiy. O oie aea /an EEAe io?eiaieo i?inoith oaoiieia??th OAI c?
no?oeoo?ith iaoae/ae?aeaeo?ee/iai?ai?ia?aeiee c ?iaeoeiaaiei ?iaa?niei
oa?ii (MIS/IL) caeeoa?oueny iecueeei /a?ac cia/i? ii?/i? ao?aoe ia
iine?aeiaiiio iii?? no?oeoo?e. ?ic?iaeai? ia oeae /an iaoiaee
i?aeaeuaiiy aoaeoeaiino? MIS/IL NA iaieio/a i?ecaiaeyoue aei
oneeaaeiaiiy oaoiieia?? ?o ae?iaieoeoaa.
sse aeey OAI c aeeooc?eiei p-n- ia?aoiaeii, oae ? aeey MIS/IL NA ?
iaaeae? caeeoa?oueny aeooaeueiith i?iaeaia i?i?i?caoe?? iioe/ieo ao?ao,
a oaeiae ao?ao, ui coiiaeai? iaaaoeaiei aieeaii iiaa?oiaai? oa ia’?iii?
?aeiia?iaoe?e. No/ani? aenieiaoaeoeai? aioea?aeaeai? oa ianeaoth/?
iie?eooy oa?aeoa?ecothoueny aenieith neeaaei?noth oaoiieia?/ii?
?aae?caoe??, a i?e oi?ioaaii? ?o ca ni?iuaiith oaoiieia??th ia
aieiae?thoue iaiao?aeieie i?ina?oethth/eie oa ianeaoth/eie
aeanoeainoyie. Ana oea niia?eueith? ?icaeoie aenieiiiooaeii?
aae?iaia?aaoeee oa ?iaeoue aeooaeueieie aeine?aeaeaiiy o aaeoc? ?ic?iaee
?aioaaaeueieo o i?aeoe/iiio canoinoaaii? iaoiae?a i?aeaeuaiiy
aoaeoeaiino? NA c aeeooc?eiei oa ?iaeoeiaaiei p-n- ia?aoiaeaie.
Ca’ycie ?iaioe c iaoeiaeie i?ia?aiaie, ieaiaie, oaiaie. Aeena?oaoe?ei?
aeine?aeaeaiiy aeeiioaaeenue ca ieaiii iaoeiai-aeine?aeii? ?iaioe AeO
“Euea?anueea iie?oaoi?ea” o ?aieao aea?aeathaeaeaoii? oaie “?ic?iaea
o?ceei – oaoiieia?/ieo iniia na??eii i?eaeaoieo ia?aoai?thaa/?a niiy/ii?
aia?a?? ia iniia? iiiie?enoae?/iiai oa aii?oiiai e?aii?th” (oeo?
AeEN/65.1, 1996-1997 ??.); o ?aieao aea?aeaaiiai eiio?aeoo “?aioaaaeuei?
aioea?aeaeai? iie?eooy aeey e?aii??aeo niiy/ieo aeaiaio?a (oeo? AeE
2I/73-98, 1997-1998 ??.) oa a ?aieao i?aeia?iaeiiai iaoeiaiai i?iaeoo
“K(steng(nstige Antireflexionsbeschichtung f(r Silicium-Solarzellen”
ni?eueii c ?inoeoooii aeine?aeaeaiiy niiy/ii? aia?a?? (i. Aia?ooaeue,
I?ia//eia), oeo? UKR-017-97, 1997-1999 ??.
Iaoa ? caaea/? aeine?aeaeaiiy. Iaoa aeena?oaoe?eii? ?iaioe iieyaaea o
?ic?iaoe? iiaeo iaoiae?a i?aeaeuaiiy aoaeoeaiino? e?aii??aeo
oioiaeaeo?e/ieo ia?aoai?thaa/?a niiy/ii? aia?a?? c aeeooc?eiei oa
?iaeoeiaaiei p-n- ia?aoiaeaie, ye? ni?iuothoue oaoiieia?th ?o
iaea?aeaiiy oa caaacia/othoue o?eaaeo aenieoaoaoe?th o neeaae?
aenieiiiooaeieo (aia?aoe?eieo nenoai.
Aeey aeinyaiaiiy oe??? iaoe iaiao?aeii aoei ae??oeoe ianooii? caaea/?:
ia iniia? aiae?co iaoaiaoe/ii? iiaeae? i?ioeano oioiaieueoa?/iiai
ia?aoai?aiiy o no?oeoo?ao e?aii??aeo NA c aeeooc?eiei oa ?iaeoeiaaiei
p-n- ia?aoiaeaie oa ?ic?aooieo aa?oiuei? iaae? ?o oai?aoe/iiai EEAe
anoaiiaeoe iniiai? iaoai?cie ao?ao c(aia?iaaii? iiooaeiino? oa iai?oeoe
oeyoe ?o i?i?i?caoe??;
c aeei?enoaiiyi iao?aaeeoe?eiiai aeey e?aii??ai? oioiaieueoa?ee aoaeoo
?ic?iaeoe i?eioeeiiai iiaee iaoiae ciaioaiiy iine?aeiaiiai iii?o
no?oeoo? NA c ?iaeoeiaaiei p-n- ia?aoiaeii, aeey yeeo aeii?ioth/eie ?
?acenoeaii-?aeiia?iaoe?ei? ao?aoe; ia(?oiooaaoe aeioe?euei?noue oa
iai?yiee eiai i?aeoe/iiai aeei?enoaiiy;
ia iniia? iaoaiaoe/ii? oai??? ieaioaaiiy aenia?eiaioo ?ic?iaeoe
iaoiaeeeo iioei?caoe?? oaoiieia?? noai?aiiy ?aioaaaeueiiai
aioea?aeaeaiiai iie?eooy aeey e?aii??aeo NA c p-n- ia?aoiaeii.
Iaoeiaa iiaecia iaea?aeaieo ?acoeueoao?a:
Oia?oa aeey ciaioaiiy ii?/ieo ao?ao o NA c ?iaeoeiaaiei p-n- ia?aoiaeii
cai?iiiiiaaii aeei?enoiaoaaoe ciai?oi? aeaeo?e/ia ci?uaiiy,
aeine?aeaeaii iaoai?ci eiai aieeao ia no?oeoo?i? ia?aiao?e, aeo?aei?
aeaeo?e/i? oa?aeoa?enoeee oa EEAe OAI.
Cai?iiiiiaaii iiaa oaoi?/ia ??oaiiy aoaeiae niiy/ieo iiaeoe?a, yea
ia?aaeaa/a? i?aeoe/ia aeei?enoaiiy ciai?oiueiai ci?uaiiy aeey
i?aeaeuaiiy aoaeoeaiino? MIS/IL NA i?e ?o ?iaio? o neeaae?
aenieiiiooaeieo (aia?aoe?eieo nenoai.
Oaeineiiaeaii iaoiaeeeo iioei?caoe?? oa cae?eniaii iioei?caoe?th
oaoiieia?/ieo oiia aeaeo?ioai?/iiai oi?ioaaiiy oa??a ii?enoiai e?aii?th
(por-Si) aeey eiai aeei?enoaiiy ye i?ina?oethth/iai oa
na?oeicaoiiethth/iai iie?eooy o no?oeoo?ao e?aii??aeo NA c ieaia?iith oa
oaenoo?iaaiith o?iioaeueiith iiaa?oiath.
Oia?oa aeey iie?auaiiy ianeaoth/eo aeanoeainoae aioea?aeaeaieo oa??a ia
iniia? por-Si cai?iiiiiaaii aeei?enoiaoaaoe aeaeo?ioai?/io
a?ae?iaai?caoe?th, anoaiiaeaii oa aeine?aeaeaii iioeiaeuei? aeey
i?aeoe/iiai aeei?enoaiiy ?aaeeie oeueiai i?ioeano.
Aenia?eiaioaeueii aeine?aeaeaii aieea aioea?aeaeaiiai iie?eooy ia iniia?
a?ae?iaai?ciaaiiai por-Si ia aeo?aei? aeaeo?e/i? oa?aeoa?enoeee oa EEAe
iiii- oa ioeueoee?enoae?/ieo e?aii??aeo NA, cae?eniaii eiai iaoeiaee
aiae?c.
Ia??oioiaai?noue oa a??ia?aei?noue io?eiaieo o aeena?oaoe??
aenia?eiaioaeueieo ?acoeueoao?a caaacia/o?oueny aeei?enoaiiyi eeane/ieo
aenia?eiaioaeueieo iaoiaeee, a ?o oi/i?noue i?aeoaa?aeaeaii a ?inoeooo?
aeine?aeaeaiiy niiy/ii? aia?a?? (i. Aia?ooaeue, I?ia//eia) eiio?ieueieie
aei??thaaiiyie c aeei?enoaiiyi oanoiaaieo aenia?eiaioaeueieo onoaiiaie.
A??ia?aei?noue oa oi/i?noue ?ic?aooie?a i?aeoaa?aeaeo?oueny iacia/ieie
?ica?aeiinoyie ?acoeueoao?a oai?aoe/iiai aiae?co oa aenia?eiaioo.
I?aeoe/ia cia/aiiy iaea?aeaieo ?acoeueoao?a:
?ic?iaeaii i?inoee aeey oaoi?/ii? ?aae?caoe?? iaoiae i?aeaeuaiiy EEAe NA
c MIS/IL no?oeoo?ith i?e ?o ?iaio? o neeaae? aenieiiiooaeieo
(aia?aoe?eieo nenoai.
?ic?iaeaii iaoiaeeeo iioei?caoe?? oaoiieia?/ieo oiia i?ioeano
aeaeo?ioai?/iiai aiiaeoaaiiy, yea aea? ciiao oi?ioaaoe aenieiaoaeoeai?
i?ina?oethth/? oa na?oeicaoiiethth/? iie?eooy ia iniia? por-Si aeey
e?aii??aeo NA c ??ciith no?oeoo?ith iiaa?oi?.
Anoaiiaeaii oa aeine?aeaeaii ?aaeeie aeaeo?ioai?/ii? a?ae?iaai?caoe??
por-Si, ye? nooo?ai iie?auothoue ianeaoth/? aeanoeaino? ii?enoeo oa??a.
Ia iniia? aiae?co ?acoeueoao?a aenia?eiaioaeueiiai aeine?aeaeaiiy aieeao
a?ae?iaai?ciaaiiai por-Si ia aeo?aei? ia?aiao?e iiii- oa
ioeueoee?enoae?/ieo e?aii??aeo NA ?ic?iaeaii i?aeoe/i? ?aeiiaiaeaoe??
uiaei iiaeaeueoiai i?aeaeuaiiy aoaeoeaiino? OAI c oa?ii por-Si.
?ic?iaeai? o aeena?oaoe?ei?e ?iaio? no?oeoo?e oa aioea?aeaeai? iie?eooy
e?aii??aeo NA c p-n- ia?aoiaeii ai?iaaaeaeai? ia caaiae? “Eia?ea” AAO
“?iaeii” (i. ?aaii-O?aie?anuee) aeey noai?aiiy aeie?a aeeaeaiiy
aeine?aeieo c?ace?a i?e?ieaeueeoeyoi??a IE-05 oa ieaiothoueny aeey
ai?iaaaeaeaiiy o na??eia ae?iaieoeoai aeey noai?aiiy aeie?a aeeaeaiiy
i?e?ieaeueeoeyoi??a ? oaeia??a.
Iniaenoee aianie caeiaoaa/a. O ioae?eaoe?yo, iaienaieo o ni?aaaoi?noa?,
caeiaoaa/aa? iaeaaeaoue: iiaeaeue MIS/IL NA o ?aaeei? ciai?oiueiai
aeaeo?e/iiai ci?uaiiy oa ?acoeueoaoe ?? ?ic?aooieo [1-2, 4-5, 7];
iaoiaeeea oa ?acoeueoaoe iioei?caoe?? oaoiieia?/ieo oiia i?ioeano
aeaeo?ioai?/iiai oi?ioaaiiy aioea?aeaeaiiai iie?eooy ia iniia? por-Si
[3, 6, 10-12]; ?acoeueoaoe aeine?aeaeaiiy ?aaeei?a eiai aeaeo?ioai?/ii?
a?ae?iaai?caoe?? [8-9].
Ai?iaaoe?y ?acoeueoao?a aeena?oaoe??. Iniiai? iieiaeaiiy oa ?acoeueoaoe
aeena?oaoe?? aeiiia?aeaeenue oa iaaiai?thaaeenue ia: First International
Conference on Material Science of Chalcogenide and Diamond-Structure
Semiconductors (Chernivtsi, Ukraine, 1994); V-?e I?aeia?iaei?e
eiioa?aioe?? c o?ceee ? oaoiieia?? oiieeo ie?aie (?aaii-O?aie?anuee,
1995); International School-Conference on Physical Problems in Material
Science of Semiconductors (Chernivtsi, Ukraine, 1995, 1997); 10th
International Conference of Thin Films (Salamanca, Spain, 1996);
School-workshop “Solar Cells: A New Challenge For the Mediterranean Area
(Physics of Materials for Solar Energy Conversion)” (Portici, Italy,
1997); International Conference of SPIE “Photoconversion: Science and
Technologies” (Warsaw, Poland, 1997); International Conference on Porous
Semiconductors: Science and Technology (Malorca, Spain, 1998); 2nd World
Conference on Photovoltaic Solar Energy Conversion (Vienna, Austria,
1998).
Ioae?eaoe??. ?acoeueoaoe aeena?oaoe?eii? ?iaioe iioae?eiaai? o 22
i?aoeyo, c ieo 2 – o iaoeiaeo aeo?iaeao, 1 – o ca??ieeo iaoeiaeo
i?aoeue, 1 – o iaoaio? Oe?a?ie ia aeiao?ae, 14 – o iaoa??aeao ? oacao
eiioa?aioe?e, 3 – o cayaeao ia aeaea/o iaoaio?a Oe?a?ie oa ?in?enueei?
Oaaea?aoe??, 1 – aeaiiiiaaia o AeIOA Oe?a?ie.
No?oeoo?a oa ianya aeena?oaoe??. Aeena?oaoe?eia ?iaioa neeaaea?oueny c?
anooio, i’yoe ?icae?e?a, caaaeueieo aeniiae?a oa nieneo aeei?enoaieo
aeaea?ae. Aiia i?noeoue 80 ?enoie?a oa iaeio oaaeeoeth, a ?? iiaiee
ianya noaiiaeoue 179 noi??iie. Nienie aeei?enoaieo e?oa?aoo?ieo aeaea?ae
i?noeoue 130 iaeiaioaaiue.
INIIAIEE CI?NO ?IAIOE
O anooi? ia(?oioiaaii aeooaeuei?noue aeena?oaoe?eieo aeine?aeaeaiue,
noi?ioeueiaaii ?o iaoo oa caaea/?, iienaii iaoeiao iiaecio oa i?aeoe/io
oe?ii?noue ?acoeueoao?a.
O ia?oiio ?icae?e? aeena?oaoe?? ia iniia? iaeyaeo oa aiae?co iaoeiaeo
ioae?eaoe?e iieacaii, ui iaeiioeiaeuei?oeie aeey aeei?enoaiiy o
aenieiiiooaeieo (aia?aoe?eieo nenoaiao ? e?aii??a? OAI, iaeaoaeoeai?oeie
c yeeo ? NA c p-n- ia?aoiaeii oa OAI IAeI oeio c ?iaeoeiaaiei ?iaa?niei
oa?ii. ?icaeyiooi aaiethoe?th no?oeoo? oeeo oei?a OAI oa iai?/aii
iai?yiee ?o iiaeaeueoiai ?icaeoeo. ?ic?iaeaii caaaeueio iaoiaeeeo
aeena?oaoe?eieo aeine?aeaeaiue, ni?yiiaaieo ia i?aeaeuaiiy aoaeoeaiino?
e?aii??aeo NA c aeeooc?eiei oa ?iaeoeiaaiei p-n- ia?aoiaeaie.
Ca?aeii ?c aecia/aieie iaoith, ia’?eoaie oa iaoiaeeeith aeine?aeaeaiue,
ae?oaee ?icae?e aeena?oaoe?? i?enay/aii ye?niiio oa e?euee?niiio
aecia/aiith oaeoi??a, ye? iaiaaeothoue aeinyaiaiiy iaeneiaeueii?
aoaeoeaiino? oioiaieueoa?/iiai ia?aoai?aiiy o no?oeoo?ao e?aii??aeo NA c
p-n- ia?aoiaeii. Aeey oeueiai cai?iiiiiaaii aeei?enoaoe ?ic?aooiie
aa?oiuei? iaae? oai?aoe/iiai EEAe caaaeaiiai oeio OAI. Iieacaii, ui aeey
ni?iuaiiy aeai?eoio ?ic?aooieo oa aeinyaiaiiy iaiao?aeii? oi/iino?
?acoeueoao?a aeioe?eueii ia’?aeiaoe i?e iiaeaethaaii? oa?iiaeeiai?/i?
ia/eneaiiy aaeaino aia?a?? oa aio?ii?? ? eaaioiai-iaoai?/iee ?ic?aooiie
(aia?aoe?? oa ?aeiia?iaoe?? iin??a ca?yaeo a NA.
Ia iniia? ?ic?aooieo aa?oiuei? iaae? oai?aoe/iiai EEAe NA c p-n-
ia?aoiaeii ia/eneaii aaee/eio iniiaieo ao?ao oioi(aia?iaaii? iiooaeiino?
a i?ioean? oioiaieueoa?/iiai ia?aoai?aiiy (?en. 1). Anoaiiaeaii, ui aeey
e?aii??aeo NA c aeeooc?eiei oa ?iaeoeiaaiei p-n- ia?aoiaeaie
iaenooo?a?oeie ? ?acenoeaii-?aeiia?iaoe?ei? ao?aoe (~3(6 %), ye?
ni?e/eiai? iaaaoeaiei aieeaii ii?/iiai iii?o no?oeoo?e NA, iiaa?oiaai?
oa ia’?iii? ?aeiia?iaoe?e, a oaeiae iioe/i? ao?aoe (~4(7 %), ye? ?
iane?aeeii iaiiaiiai iiaeeiaiiy iaaeath/iai na?oeiaiai iioieo.
?en. 1. Ia?a?iciiae?e aia?a?? o e?aii??aiio NA c p-n- ia?aoiaeii o
i?ioean? oioiaieueoa?/iiai ia?aoai?aiiy. No??eeaie c i?aeienii “2 %”
iieacaii ao?aoe aia?a??, yeeo i?eioeeiiai iiaeia oieeiooe
Ocaaaeueiaiiy ? aiae?c ?acoeueoao?a oai?aoe/ieo aeine?aeaeaiue aea?
i?aenoaae noaa?aeaeoaaoe, ui aoaeoeaii? i?i?i?caoe?? ii?/ieo oa iioe/ieo
ao?ao o NA c p-n- ia?aoiaeii iiaeia aeinyaiooe aai i?e aeei?enoaii?
iiaeo, iao?aaeeoe?eieo aeey e?aii??ai? oioiaieueoa?ee aoaeo?a, aai
oeyoii aaaaeaiiy a ?o no?oeoo?o iiaeo iaoa??ae?a.
O a?aeiia?aeiino? ?c oeei o o?aoueiio ?icae?e? aeena?oaoe?eii? ?iaioe
aeine?aeaeo?oueny aoaeoeai?noue aeei?enoaiiy aeey ciaioaiiy
?acenoeaii-?aeiia?iaoe?eieo ao?ao ciai?oiueiai aeaeo?e/iiai ci?uaiiy.
sse ia’?eo aeine?aeaeaiiy i?e oeueiio ia?aii MIS/IL NA, aeey yeeo
caaaeai? ao?aoe ? aeii?ioth/eie. Oa?aeoa?iith iniaeea?noth MIS/IL
no?oeoo?e ? iayai?noue oiieiai o?ce/iiai p-n- ia?aoiaeo, ui aeieea? o
iai?ai?ia?aeieeia?e i?aeeeaaeoe? p-oeio i?ae aieeaii aaoaeiaaiiai o
ae?aeaeo?e/iiio oa?? iiceoeaiiai ca?yaeo (?en. 2(a)). ?ic?aooiee
iieacothoue, ui iioaioe?eii MIS/IL NA ? aoaeoeai?oeie, i?ae NA c
aeeooc?eiei p-n- ia?aoiaeii. Iaeiae aeinyaiaiiy ia?aaeaa/aii? oai?aoe/ii
aeniei? aoaeoeaiino? MIS/IL NA oneeaaeith?oueny aiane?aeie cia/ieo ao?ao
c(aia?iaaii? iiooaeiino? o aenieiiiiiio ?iaa?niiio oa??.
Aeey oieeiaiiy o?ce/ieo iaiaaeaiue oa iecueei? ?aioaaaeueiino?, ui
aeanoea? o?aaeeoe?eiei iaoiaeai i?aeaeuaiiy EEAe MIS/IL NA, ?ic?iaeaii
iiaee iaoiae i?i?i?caoe?? ?acenoeaii-?aeiia?iaoe?eieo ao?ao o MIS/IL
no?oeoo??. Oeae iaoiae (?oioo?oueny ia aeei?enoaii? ii?yae ?c
aioo??oi?ie oaeoi?aie (aenieith aonoeiith aaoaeiaaiiai ca?yaeo,
iecueeith aonoeiith iiaa?oiaaeo noai?a, aoaeoii ??cieoe? ?ia?o aeoiaeo)
oaeiae oaeoi??a ciai?oiueiai aieeao, a naia – ciai?oiueiai aeaeo?e/iiai
ci?uaiiy. sse aaciao no?oeoo?o aeey ?aae?caoe?? iaoiaeo ciai?oiueiai
ci?uaiiy cai?iiiiiaaii aeei?enoaoe no?oeoo?o MIS/IL NA c ?iaa?n?eiith
a?aa?ieith ia iniia? iaoaeo /e ieneaeo c iecueeith ?iaioith aeoiaeo
(?en. 2(b)). Aeey iiaeaeueoiai ciaioaiiy ieoiiiai iii?o ?iaa?niiai oa?o
oa ni?e/eiaieo iei ?acenoeaieo ao?ao c(aia?iaaii? iiooaeiino?
i?iiiio?oueny i?eeeanoe aei ?iaa?n?eii? a?aa?iee ciai?oith iai?oao o
cai?ioiiio aa?ieiaii?.
?en. 2 Noaiaoe/ia cia?aaeaiiy NA c MIS/IL no?oeoo?ith: a – oeiiaa
eiino?oeoe?y; b – no?oeoo?a c ?iaa?n?eiith a?aa?ieith. 1 – oeeueiee
eiioaeo; 2 – e?aii??aa i?aeeeaaeea p-oeio i?ia?aeiino?; 3 – ca?aeiaiee
oa?; 4 – ?iaa?niee oa? n-oeio; 5 – ie?aea SiO2; 6 – no?oiicae?ath/a
a?aa?iea; 7 – ?iaa?n?eia a?aa?iea
?en. 3. A?ao?ee caeaaeiinoae IL’/IL(V) (1), Voc’/Voc(V) (2), FF’/FF(V)
(3), (’/((V) (4), aea IL, Voc, FF ? ( a?aeiia?aeii aeo?aei? aeaeo?e/i?
oa?aeoa?enoeee oa EEAe MIS/IL NA i?e a?aenooiino? ciai?oiueiai ci?uaiiy;
IL’, Voc’, FF’ ? (’- aeo?aei? ia?aiao?e MIS/IL NA a ?aaeei? ciai?oiueiai
aeaeo?e/iiai ci?uaiiy
Aeey aecia/aiiy aoaeoeaiino? aeei?enoaiiy cai?iiiiiaaiiai iaoiaeo
iiaoaeiaaii iiaeaeue MIS/IL NA i?e ?o ?iaio? a ?aaeei? ciai?oiueiai
aeaeo?e/iiai ci?uaiiy. Iiaeaethaaiiyi anoaiiaeaii iaoai?ci aieeao
ciai?oiuei? iai?oae ia no?oeoo?i? ia?aiao?e, aeo?aei? aeaeo?e/i?
oa?aeoa?enoeee oa EEAe MIS/IL NA.
Anoaiiaeaii, ui iaeiaioee aieea ciai?oi? ci?uaiiy cae?enith? ia
aaee/eio no?oio ei?ioeiai caieeaiiy (?en. 3(1)). Eiai i?e??no i?e
iai?oc? ci?uaiiy 0.6 A noaiiaeoue o?eueee 1.5 %. Nooo?a?oei ca oeeo oiia
? i?e??no (~ 7 %) iai?oae oieinoiai oiaeo (?en. 3(2)). Ciaioaiiy i?ae
aieeaii ciai?oiueiai ci?uaiiy ?acenoeaii-?aeiia?iaoe?eieo ao?ao aaaea
aei c?inoaiiy a?eueo i?ae ia 22 % eiao?oe??ioa caiiaiaiiy AAO (?en.
3(3)). Noia?iee aoaeo a?ae aieeao ciai?oiueiai ci?uaiiy i?iyaey?oueny o
c?inoaii? ia 30 % EEAe MIS/IL NA (?en. 3(4)).
?en. 4. Oaoi?/ia ??oaiiy aoaeiae NI, ui ia?aaeaa/a? aeei?enoaiiy
ciai?oiueiai ci?uaiiy aeey i?aeaeuaiiy EEAe MIS/IL NA i?e ?o ?iaio? o
neeaae? aenieiiiooaeieo (aia?aoe?eieo nenoai
?en. 5. A?aeiinia ca?eueoaiiy EEAe NI i?e aeei?enoaii? aoaeoo
ciai?oiueiai ci?uaiiy a caeaaeiino? a?ae e?eueeino? NA o eiai neeaae?.
?acoeueoaoe ii?iiaaii aei aaee/eie EEAe NI o?aaeeoe?eii? eiino?oeoe??
Iiaeaethaaiiyi ?iaioe NA c MIS/IL no?oeoo?ith a ?aaeei? ciai?oiueiai
ci?uaiiy anoaiiaeaii, ui iaenooo?a?oei ? aieea i?eeeaaeaii? iai?oae o
ae?aiacii? a?ae 0 aei 0.6A (aeea. ?en. 3). Aeoiaey/e c oiai, ui aa?oiy
iaaea aeacaiiai ?ioa?aaeo aeecueea aei aaee/eie iai?oae oieinoiai oiaeo
MIS/IL NA, ye aeaea?aei ciai?oiueiai ci?uaiiy cai?iiiiiaaii
aeei?enoiaoaaoe aeiiii?aeiee MIS/IL NA. Y?oiooth/enue ia oeueiio,
cai?iiiiiaaii iiaa oaoi?/ia ??oaiiy aoaeiae niiy/iiai iiaeoey (NI), a
yeiio aeo?aeia iai?oaa c aeiiii?aeiiai NA iiaea?oueny o cai?ioiiio
aa?ieiaii? ia ?iaa?n?ei? a?aa?iee e?eueeio iniiaieo MIS/IL NA (?en. 4).
Iiaeaethaaiiyi anoaiiaeaii, ui aaea i?e o?ueio iniiaieo NA
aoaeoeai?noue oaeiai NI ia?aaeuoaaoeia EEAe NI o?aaeeoe?eii?
eiino?oeoe?? c aiaeia?/iith e?euee?noth NA (?en. 5). I?e iiaeaeueoiio
ca?eueoaii? e?eueeino? NA EEAe cai?iiiiiaaiiai NI c?inoaoeia ? i?e
aeei?enoaii? o iiaeoe? 20 NA ia?aaeuoaaoeia EEAe NI o?aaeeoe?eii?
eiino?oeoe?? ia 25 %. Iaea?aeai? ?acoeueoaoe iai/ii ?ethno?othoue aenieo
aoaeoeai?noue aeei?enoaiiy iaoiaeo ciai?oiueiai ci?uaiiy aeey
i?aeaeuaiiy EEAe MIS/IL NA i?e ?o ?iaio? o neeaae? aenieiiiooaeieo
(aia?aoe?eieo nenoai.
?icaeoeia? cai?iiiiiaaii? o ae?oaiio ?icae?e? eiioeaioe?? ciaioaiiy
iioe/ieo ao?ao o e?aii??aeo NA oeyoii aaaaeaiiy a ?o no?oeoo?o iiaeo
iai?ai?ia?aeieeiaeo iaoa??ae?a i?enay/aii /aoaa?oee ?icae?e
aeena?oaoe??. sse ia?niaeoeaiee aeey aeei?enoaiiy c oe??th iaoith
iaoa??ae aeine?aeaeo?oueny ii?enoee e?aii?e (por-Si).
Ocaaaeueiaiiy oa aiae?c aeina?aeo oioiaieueoa?/iiai aeei?enoaiiy por-Si
i?aeoaa?aeaeo? iiaeeea?noue ni?iuaiiy oaoiieia?? noai?aiiy oa nooo?aiai
i?aeaeuaiiy aoaeoeaiino? e?aii??aeo NA i?e aaaaeaii? a ?o no?oeoo?o
oa??a oeueiai iaoa??aeo ye aioea?aeaeaiiai iie?eooy. Iaeiae,
iacaaaeath/e ia nooo?aa ciaioaiiy iioe/ieo ao?ao i?e aeei?enoaii? por-Si
o no?oeoo?ao NA, ne?ae a?aecia/eoe oaeiae ? iaaio iaiaaeai?noue eiai
i?aeoe/iiai canoinoaaiiy. Oey iaiaaeai?noue coiiaeaia a iniiaiiio oei,
ui iaea?eueoi? i?i?i?caoe?? ao?ao ia a?aeaeaaiiy aeinyaiooi aeey
ii?enoeo oa??a caaoiaoee ~ 10 iei, a i?ina?oethth/a iie?eooy c oaeith
oiaueiith ia iiaea aooe aoaeoeaii aeei?enoaia o no?oeoo?ao NA c i?eeei
p-n- ia?aoiaeii. O oie aea /an no/aniee ??aaiue aioea?aeaeaieo
aeanoeainoae oiieeo (aei 100 ii) oa??a por-Si ? iaaeinoaoi?i aeey
aoaeoeaii? i?i?i?caoe?? iioe/ieo ao?ao o NA.
Ia iniia? aea/aiiy oa aiae?co i?e?ino?oeoo?e por-Si aenoiooi a?iioaco
i?i iiaeeea?noue iiaeaeueoiai iie?auaiiy eiai aioea?aeaeaieo
aeanoeainoae oeyoii iioei?caoe?? oaoiieia?/ieo oiia i?ioeano
aeaeo?ioai?/iiai oi?ioaaiiy oeueiai iaoa??aeo. Aenia?eiaioaeueia
ia?aa??ea oe??? a?iioace i?iaiaeeoueny o i’yoiio ?icae?e?
aeena?oaoe?eii? ?iaioe. Aeey ?ic?iaee iaoiaeeee iioei?caoe?? oaoiieia??
oi?ioaaiiy por-Si aeei?enoaii iaoaiaoe/io oai??th ieaioaaiiy
aenia?eiaioo. Ca?aeii c ?ic?iaeaiith iaoiaeeeith ia ia?oiio aoai?
iioei?caoe?? iiaoaeiaaii iiaeaeue aioea?aeaeaiiai iie?eooy ia iniia?
por-Si c o?aooaaiiyi iniaeeainoae aea?aiiai iaoa??aeo. Iiaeaethaaiiy
i?aeoaa?aeeei a?iioaco i?i iiaeeea?noue nooo?aiai ciaioaiiy iioe/ieo
ao?ao ia a?aeaeaaiiy a?ae iiaa?oi? ii?enoiai oa?o oa iaaeaei ciiao
anoaiiaeoe iioeiaeueiee ae?aiacii eiai iioe/ieo ia?aiao??a – oiaueie oa
iieacieea caeiieaiiy (?en. 6).
I?e aenia?eiaioaeueiiio aecia/aii? oiaueie oa iieacieea caeiieaiiy
oa??a por-Si ca aeiiiiiaith ae?iniiao?e/ii? niaeo?ineii?? anoaiiaeaii,
ui o?aaeeoe?ei? iaoiaee iioe/iiai ae?aaiinooaaiiy ia iiaeooue aooe
aoaeoeaii aeei?enoai? aeey aecia/aiiy iioe/ieo ia?aiao??a por-Si. Oea
iiyniaii ia iniia? ?acoeueoao?a no?oeoo?iiai aeine?aeaeaiiy por-Si, yea
aeyaeei cia/io iaiaeii??aei?noue ii?enoiai oa?o ca oiaueiith ii an?e
ieiu? c?acea.
Aeey aoaeoeaiiai iioe/iiai ae?aaiinooaaiiy oa??a por-Si ?ic?iaeaii
iiaee iaoiae aecia/aiiy eiai iioe/ieo ia?aiao??a, ui (?oioo?oueny ia
aeei?enoaii? caeaaeiino? niaeo?aeueiiai iieiaeaiiy oa aaee/eie i?i?ioio
niaeo?a a?aeaeaaiiy ii?enoiai oa?o a?ae eiai oiaueie oa iieacieea
caeiieaiiy. Ii?yae ?c i?inoioith oa oi?aa?naeuei?noth oeae iaoiae
caaacia/o? oaeiae aenieo oi/i?noue, ui i?aeoaa?aeaeaii c?noaaeaiiyi
?acoeueoao?a iiaeaethaaiiy oa aenia?eiaioo.
?en. 6. ?ic?aooieiaa caeaaei?noue eiao?oe??ioa a?aeaeaaiiy oa?o por-Si
a?ae eiai oiaueie oa iieacieea caeiieaiiy aeey aeiaaeeie oaee? 600 ii
?c aeei?enoaiiyi ?ic?iaeaii? iaoiaeeee iioe/iiai ae?aaiinooaaiiy
ii?enoeo oa??a aeine?aeaeaii aieea ia iioe/i? ia?aiao?e por-Si
oaoiieia?/ieo oiia eiai aeaeo?ioai?/iiai oi?ioaaiiy. Anoaiiaeaii, ui a
iaea?eueo?e i??? ia aaee/eio iieacieea caeiieaiiy por-Si aieeaa? aonoeia
aiiaeiiai no?oio, a oie /an ye oiaueia ii?enoiai oa?o a iniiaiiio
aecia/a?oueny /anii aiiaeii? ia?iaee. Aeine?aeaeaiiyi aieeao
oaoiieia?/ieo oiia ?inoo ia aioea?aeaeai? aeanoeaino? por-Si anoaiiaeaii
/?oei ae?aaeai? i?i?ioie a?aeaeaaiiy aeey iaaieo cia/aiue aonoeie
aiiaeiiai no?oio oa /ano aeaeo?ioai?/ii? ia?iaee. Oea aea? ciiao
aeinyaiooe ciaioaiiy iioe/iiai a?aeaeaaiiy a?ae iiaa?oi? por-Si, i?ioa
oaeee o?ae iioei?caoe?? ? neeaaeiei aeey i?aeoe/ii? ?aae?caoe??
aiane?aeie aaaaoioaeoi?iino? aenia?eiaioo. Aeey oieeiaiiy
aaaaoioaeoi?iino? iioei?caoe?eieo aeine?aeaeaiue cai?iiiiiaaii ye
iniiaiee e?eoa??e iioei?caoe?? aeei?enoiaoaaoe aaee/eio aiiaeiiai
ca?yaeo. Oaeee aenia?eiaioaeueiee i?aeo?ae iaaeaa iiaeeea?noue oaeaeei
anoaiiaeoe ae?aiacii iioeiaeueieo iioe/ieo ia?aiao??a i?ina?oethth/iai
iie?eooy ia iniia? por-Si oa iioei?coaaoe oaoiieia?th eiai oi?ioaaiiy.
Aenia?eiaioaeueii anoaiiaeaii, ui i?i?i?caoe?y ao?ao ia a?aeaeaaiiy
aeinyaa?oueny i?e oi?ioaaii? oa?o por-Si a aeaeo?ie?o? ia iniia?
C2H5OH:HF = 1:1 c aonoeiith aiiaeiiai ca?yaeo a ae?aiacii? a?ae 0.2 aei
0.25 Ee/ni2. Aioea?aeaeai? iie?eooy, noi?iiaai? ca oaeeo oaoiieia?/ieo
oiia, oa?aeoa?ecothoueny ?aei?aeii iecueeeie eiao?oe??ioaie iioe/iiai
a?aeaeaaiiy (?en. 7(a)) ? ca aoaeoeai?noth i?ina?oeaiiy ? noi??ieie c
iaee?aueie aioea?aeaeaieie iioe/ieie nenoaiaie, ui aeei?enoiaothoueny o
oaoiieia?? no/anieo e?aii??aeo NA.
?en. 7. Niaeo?e a?aeaeaaiiy iioei?ciaaieo oa??a por-Si, ae?iuaieo ia
ieaia?i?e (a) ? oaenoo?iaai?e (b) e?aii??a?e iiaa?oi?
Ii?yae ?c aenia?eiaioaie c i?ina?oeaiiy ieaia?ii? e?aii??ai? iiaa?oi? o
aeena?oaoe?ei?e ?iaio? aia?oa eiiieaenii aeine?aeaeaii aieea
aeaeo?ioai?/iiai aiiaeoaaiiy ia aioea?aeaeai? aeanoeaino? e?aii??ai?
iiaa?oi?, oaenoo?iaaii? ai?cio?iiiei oai?/iei o?aaeaiiyi. Iaoiaeaie
aeaeo?iiii? i?e?ineii?? anoaiiaeaii, ui o i?ioean? aiiaeoaaiiy
no?aaeththoueny aa?oeie oa a?ai? i??ai?ae iiaa?oiaai? oaenoo?e. Oea, o
naith /a?ao, iaaaoeaii aieeaa? ia aioea?aeaeai? aeanoeaino?
oaenoo?iaaii? iiaa?oi?. Aeey oiai, uia oieeiooe iioeiaeaeaiiy
iiaa?oiaai? oaenoo?e i?iaaaeaii aeiaeaoeiao iioei?caoe?th oaoiieia??
?inoo oa??a por-Si oa anoaiiaeaii oiiae aeaeo?ioai?/iiai aiiaeoaaiiy,
ye? aeathoue ciiao oi?ioaaoe ii?eno? oa?e ia oaenoo?iaai?e iiaa?oi? aac
iii?oiiai iioeiaeaeaiiy aaiiao??? iiaa?oiaai? oaenoo?e.
Iioei?caoe?eieie aenia?eiaioaie anoaiiaeaii, ui iaee?au? ?acoeueoaoe c
i?ina?oeaiiy oaenoo?iaaii? e?aii??ai? iiaa?oi? aeinyaathoueny i?e
aeei?enoaii? aeaeo?ie?oo ia iniia? ?ic/eio C2H5OH:H2O:HF = 1:1:1 oa
aaee/eie aiiaeiiai ca?yaeo aeecueei 0.46 Ee/ni2. Noi?iiaai? ca oaeeo
oaoiieia?/ieo oiia aioea?aeaeai? iie?eooy ia iniia? por-Si
oa?aeoa?ecothoueny ?aei?aeii iecueeeie eiao?oe??ioaie a?aeaeaaiiy (?en.
7(b)) ? ? aoaeoeai?oeie aeey i?ina?oeaiiy oaenoo?iaaii? iiaa?oi?, i?ae
aiaeia?/i? iie?eooy ia iniia? ae?ieneaeo /e i?o?eaeo e?aii?th.
C ?en. 7 aeaeii, ui i?e aeei?enoaii? o no?oeoo?? e?aii??aeo NA oeiiaeo
aioea?aeaeaieo iie?eoue o niaeo?aeueiiio ae?aiacii? a?ae 950 aei 1100 ii
caaaeaee ia? i?noea nooo?aa c?inoaiiy iioe/ieo ao?ao. I?e/eiith oeueiai
? iecueeee eiao?oe??io iioe/iiai iiaeeiaiiy e?aii?th o aeeaeiueiio
?*-ae?aiacii?. Aeey ciaioaiiy oaeeo ao?ao o no/anieo aenieiaoaeoeaieo NA
aeei?enoiaothoue iioe/i? nenoaie caoiieaiiy na?oea. Iaeiae oaoiieia?/ia
?aae?caoe?y nenoai ?c na?oeicaoiiethth/eie aeanoeainoyie ? iaaeoi
neeaaeiith, ui, o naith /a?ao, oneeaaeith? oaoiieia?th noai?aiiy
e?aii??aeo NA.
Aeey nooo?aiai ciaioaiiy iioe/ieo ao?ao o aeeaeiueiio ?*-ae?aiacii? oa
ni?iuaiiy oaoiieia?? noai?aiiy e?aii??aeo NA cai?iiiiiaaii ye iioe/io
nenoaio caoiieaiiy na?oea aeei?enoiaoaaoe oiano? oa?e por-Si. Oeae
i?aeo?ae (?oioo?oueny ia aiae?c? ?acoeueoao?a no?oeoo?ieo aeine?aeaeaiue
oianoeo ii?enoeo oa??a. Iaoiaeaie aeaeo?iiii? i?e?ineii?? anoaiiaeaii,
ui i?e oi?ioaaii? por-Si c aonoeiith aiiaeiiai ca?yaeo a?eueoa 2 Ee/ni2
no?oeoo?a oa?o por-Si yaey? niaith noeoii?noue oiieiai (~ 100 ii)
i?eiiaa?oiaaiai iacaii?enoiai oa?o oa oianoiai ia’?iiiai iae?iii?enoiai
i?aeoa??a. Oea aea? i?aenoaae aaaaeaoe, ui iacaii?enoee oa? iiaea
aoaeoeaii ciaiooaaoe iioe/i? ao?aoe ia a?aeaeaaiiy, o oie /an ye
iae?iii?enoee oa?, ?ici?? iaiaeii??aeiinoae yeiai noi??iee ?c
aeiaaeeiith na?oeiai? oaee?, iiaea caaacia/eoe ?icn?thaaiiy iaaeath/iai
na?oeiaiai iioieo oa ni?eyoeia caoiieaiith na?oea o no?oeoo?? NA.
?en. 8. Niaeo? a?aeaeaaiiy na?oeicaoiiethth/iai iie?eooy ia iniia? oa?o
por-Si caaoiaoee 10 iei (nooe?eueia e?i?y). Aeey ii??aiyiiy i?eaaaeaii
niaeo? a?aeaeaaiiy ii?enoiai oa?o caaoiaoee 100 ii
Iioei?caoe?y oaoiieia?? ?inoo oianoeo oa??a por-Si iaaeaea iiaeeea?noue
noi?ioaaoe ia ?o iniia? na?oeicaoiiethth/? iie?eooy, ye? ciaioothoue
iioe/i? ao?aoe ia a?aeaeaaiiy o ae?aiacii? 300(1150 ii c 45.8 % aei 3.32
% ? caaaeyee nai?i aioea?aeaeaiei aeanoeainoyi (?en. 8) ia iathoue
aiaeia?a o na?o?.
Ine?eueee aioea?aeaeaia iie?eooy ia iniia? por-Si oi?io?oueny
aaciina?aaeiuei ia e?aii??a?e iiaa?oi?, oi i/aaeaeii, ui aeey
i?i?i?caoe?? iaaaoeaiiai aieeao ia aeo?aei? oa?aeoa?enoeee NA
iiaa?oiaai? ?aeiia?iaoe?? ii?enoee oa? iiaeiai caaacia/eoe oaeiae
ianeaaoe?th iiaa?oi? iai?ai?ia?aeieea. Iaeiae i?aeoeea na?oiaeo
aeine?aeaeaiue o oe?e aaeoc? na?ae/eoue i?i oa, ui por-Si ia aieiae??
iaiao?aeiei ??aiai ianeaoth/eo aeanoeainoae ? aei oeueiai /ano oae ? ia
?ic?iaeaii aoaeoeaiiai iaoiaeo ?o iie?auaiiy.
?en. 9. Niaeo?e oioiethi?ianoeaioe?? oa??a por-Si: 1- i?ney
a?ae?iaai?caoe?? i?ioyaii 2-o aiae. c aonoeiith no?oio 1 iA/ci2; 2 –
i?ney 3-o aiaeeiiiai ia?iaiai o?aaeaiiy a HF; 3 – i?ney 3-o aiaeeiiiai
aieiaiai o?aaeaiiy a HF; 4 – i?ney 40 oa. a?ae?iaai?caoe?? c aonoeiith
no?oio 0.6 iA/ci2. 5 – niaeo? oioiethi?ianoeaioe?? na?aeiae?iuaiiai oa?o
por-Si
Oia?oa aeey aoaeoeaiiai iie?auaiiy ianeaoth/eo aeanoeainoae por-Si
cai?iiiiiaaii aeei?enoiaoaaoe eiai aeaeo?ioai?/io a?ae?iaai?caoe?th o
caaaa/aieo aoiia?iei aiaeiai aeaeo?ie?oao. Anoaiiaeaii oa aeine?aeaeaii
iioeiaeuei? aeey i?aeoe/iiai aeei?enoaiiy ?aaeeie oeueiai i?ioeano.
Iiceoeaiee aieea aeaeo?ioai?/ii? a?ae?iaai?caoe?? ia ianeaoth/?
aeanoeaino? por-Si i?aeoaa?aeaeaii aeine?aeaeaiiyi ca iaoiaeii
oioiethi?ianoeaioe?? oa aeine?aeaeaiiyi e?eaeo aiiaeiiai ca?yaeaeaiiy.
Anoaiiaeaii, ui ?ioaineai?noue oioiethi?ianoeaioe?? por-Si, yea
aaciina?aaeiuei ei?aeth? c eiai ianeaoth/eie aeanoeainoyie, c?inoa?
i?ney a?ae?iaai?caoe?? i?eaeecii o 150 ?ac?a (?en. 9). I?iaaaeaiee
ii??aiyeueiee aiae?c iieacaa, ui ca aoaeoeai?noth iie?auaiiy ianeaoth/eo
aeanoeainoae ii?enoeo oa??a aeaeo?ioai?/ia a?ae?iaai?caoe?y ia?aaa?oo?
iaoiaee oai?/ii? ia?iaee por-Si, ye? aaaaeaeenue aei iaaeaaiueiai /ano
iaeia?niaeoeai?oeie (?en. 9).
Aeey noi?uaiiy i?ioeano aeaeo?ioai?/iiai oi?ioaaiiy aioea?aeaeaiiai
iie?eooy ia iniia? a?ae?iaai?ciaaiiai por-Si c oaoiieia??th aeaioiaeaiiy
e?aii??aeo NA cai?iiiiiaaii oi?ioaaoe ii?enoee oa? ia caaa?oaeueiiio
aoai? noai?aiiy no?oeoo?e NA i?ney iaianaiiy o?iioaeueii? eiioaeoii?
nenoaie. Oaeee i?aeo?ae aea? ciiao oieeiooe aeiaeaoeiaiai i?ioeano
oioie?oia?ao??, caaaeyee /iio ni?iuo? oaoiieia?th aeaioiaeaiiy
e?aii??aeo NA. Uia caiia?aoe iioeiaeaeaiiy eiioaeoii? a?aa?iee i?ae /an
aiiaeoaaiiy o ?ic/ei? HF o?eaae?noue aeaeo?ioai?/ii? ia?iaee aoei
ciaioaii aei 3-6 naeoiae. Aeey oiai, uia aaee/eia aiiaeiiai ca?yaeo
caeeoaeanue o ae?aiacii? iioeiaeueieo cia/aiue, ciaioaiiy /ano o?aaeaiiy
aoei eiiiainiaaia ca ?aooiie ca?eueoaiiy aonoeie aiiaeiiai no?oio.
I?iaaaeai? iioei?caoe?ei? caoiaee iaaeaee iiaeeea?noue noi?ioaaoe
aioea?aeaeai? iie?eooy ia iniia? a?ae?iaai?ciaaiiai por-Si ia iiaa?oi?
no?oeoo? e?aii??aeo NA aac aoaeue-yeiai iioeiaeaeaiiy o?iioaeueii?
eiioaeoii? a?aa?iee.
Aieea aioea?aeaeaiiai iie?eooy ia iniia? a?ae?iaai?ciaaiiai por-Si ia
aeo?aei? aeaeo?e/i? oa?aeoa?enoeee oa EEAe iiii- ? ioeueoee?enoae?/ieo
e?aii??aeo NA aeine?aeaeoaaany c aeei?enoaiiyi ?i?oaoi?a niiy/iiai
niaeo?a AM 1.5G a ?inoeooo? aeine?aeaeaiiy niiy/ii? aia?a?? (i.
Aia?ooaeue, I?ia//eia). Ia iniia? ocaaaeueiaiiy aenia?eiaioaeueieo
?acoeueoao?a anoaiiaeaii iaoai?ci oa nooi?iue aieeao o?iioaeueiiai
ii?enoiai oa?o ia aeo?aei? ia?aiao?e aeine?aeaeoaaieo NA (?en. 10).
?en. 10. Aieea aioea?aeaeaiiai iie?eooy ia iniia? a?ae?iaai?ciaaiiai
por-Si ia aeo?aei? aeaeo?e/i? oa?aeoa?enoeee oa EEAe iiii- oa
ioeueoee?enoae?/ieo e?aii??aeo NA. An? ia?aiao?e i?aaenoaaeai? o
aeaeyae? ni?aa?aeiioaiiy ?o aaee/ei aei oa i?ney oi?ioaaiiy ii?enoiai
oa?o
Anoaiiaeaii, ui aeei?enoaiiy a?ae?iaai?ciaaiiai por-Si ye
aioea?aeaeaiiai iie?eooy o no?oeoo?ao iiii- oa ioeueoee?enoae?/ieo NA
ni?ey? ca?eueoaiith ?o no?oio ei?ioeiai caieeaiiy a?eueoa i?ae ia 50 %.
Iaeiae ii?yae c? ciaioaiiyi iioe/ieo ao?ao i?e aeei?enoaii? por-Si o
no?oeoo?? NA niinoa??aa?oueny oaeiae c?inoaiiy
?acenoeaii-?aeiia?iaoe?eieo ao?ao, ui i?iyaey?oueny o ciaioaii? iai?oae
oieinoiai oiaeo (Voc) oa eiao?oe??ioa caiiaiaiiy AAO (FF). Caaaeyee
oeueiio i?e??no EEAe NA c aioea?aeaeaiei iie?eooyi ia iniia? por-Si
iaiaaeaiee ??aiai 30 % (?en. 10).
Ia iniia? aea/aiiy iaoai?cio ?acenoeaii-?aeiia?iaoe?eieo ao?ao o
no?oeoo?ao NA c por-Si anoaiiaeaii, ui i?e/eiith ciaioaiiy eiao?oe??ioa
caiiaiaiiy ? c?inoaiiy ieoiiiai iii?o ai?oa?a i?e oi?ioaaii? ii?enoiai
oa?o, a aea(?aaeaoe?y iai?oae oieinoiai oiaeo ? iane?aeeii aieeao
iiaa?oiaai? ?aeiia?iaoe??. Aeey iiaeaeueoiai i?aeaeuaiiy EEAe NA c
aioea?aeaeaiei iie?eooyi ia iniia? a?ae?iaai?ciaaiiai por-Si
cai?iiiiiaaii iioei?coaaoe oaoiieia?/i? oiiae aeeooc?eiiai i?ioeano oa
noaa?e?coaaoe ianeaoth/? aeanoeaino? por-Si oeyoii eiai eainoeyoe??.
INIIAI? ?ACOEUeOAOE ? AENIIAEE
Eaaioiai-iaoai?/iei ? oa?iiaeeiai?/iei iiaeaethaaiiyi i?ioeano
oioiaieueoa?/iiai ia?aoai?aiiy oa ia iniia? ?ic?aooieo aa?oiuei? iaae?
oai?aoe/iiai EEAe e?aii??aeo NA ia/eneaii aaee/eio
?acenoeaii-?aeiia?iaoe?eieo oa iioe/ieo ao?ao oioi(aia?iaaii?
iiooaeiino? o NA c aeeooc?eiei oa ?iaeoeiaaiei p-n- ia?aoiaeaie.
?ic?iaeaii i?eioeeiiai iiaee iaoiae i?i?i?caoe??
?acenoeaii-?aeiia?iaoe?eieo ao?ao o NA c ?iaeoeiaaiei p-n- ia?aoiaeii,
ui (?oioo?oueny ia canoinoaaii? ciai?oiueiai aeaeo?e/iiai ci?uaiiy.
Anoaiiaeaii oa aeine?aeaeaii iaoai?ci aieeao ciai?oiueiai ci?uaiiy ia
no?oeoo?i? ia?aiao?e, aeo?aei? aeaeo?e/i? oa?aeoa?enoeee oa EEAe oeueiai
oeio NA.
Cai?iiiiiaaii iiaa oaoi?/ia ??oaiiy aoaeiae niiy/iiai iiaeoey, yea
ia?aaeaa/a? i?aeoe/ia aeei?enoaiiy ciai?oiueiai aeaeo?e/iiai ci?uaiiy ?
aea? ciiao i?aeaeueoe a?eueoa i?ae ia 25% EEAe NA c ?iaeoeiaaiei p-n-
ia?aoiaeii i?e ?iaio? o neeaae? aenieiiiooaeieo (aia?aoe?eieo nenoai.
Oaeineiiaeaii iaoiaeeeo iioei?caoe?? oa cae?eniaii iioei?caoe?th
oaoiieia?/ieo oiia aeaeo?ioai?/iiai oi?ioaaiiy oa??a ii?enoiai e?aii?th
(por-Si). Caaaeyee oeueiio ia iniia? por-Si noai?aii i?ina?oethth/?
iie?eooy aeey e?aii??aeo NA c aeeooc?eiei p-n- ia?aoiaeii, ye? ca
aoaeoeai?noth ciaioaiiy iioe/ieo ao?ao noi??i? c iaee?aueie
aioea?aeaeaieie iioe/ieie nenoaiaie.
Anoaiiaeaii, ui o ?acoeueoao? oi?ioaaiiy por-Si i?e aonoei? aiiaeiiai
ca?yaeo a?ae 2 aei 10 Ee/ni2 no?oeoo?a ii?enoiai oa?o yaey? niaith
noeoii?noue oiieiai i?eiiaa?oiaaiai iacaii?enoiai oa oianoiai ia’?iiiai
iae?iii?enoiai i?aeoa??a. ?ic?iaeaii oaoiieia?th oi?ioaaiiy ia iniia?
oaeeo oa??a por-Si iioe/ieo nenoai caoiieaiiy na?oea, ye? ciaioothoue
iioe/i? ao?aoe ia a?aeaeaaiiy o ae?aiacii? 300(1150 ii c 45.8 % aei 3.32
% ? caaaeyee nai?i aioea?aeaeaiei aeanoeainoyi ia iathoue aiaeia?a o
na?o?.
Iieacaii, ui aoaeoeaiiai iie?auaiiy ianeaoth/eo aeanoeainoae por-Si
iiaeia aeinyaiooe aeaeo?ioai?/iith a?ae?iaai?caoe??th o caaaa/aieo
aoiia?iei aiaeiai aeaeo?ie?oao. Anoaiiaeaii oa aeine?aeaeaii iioeiaeuei?
aeey i?aeoe/iiai aeei?enoaiiy ?aaeeie oeueiai i?ioeano.
Aenia?eiaioaeueii anoaiiaeaii, ui aeei?enoaiiy iioei?ciaaiiai
aioea?aeaeaiiai iie?eooy ia iniia? a?ae?iaai?ciaaiiai por-Si o
no?oeoo?ao iiii- oa ioeueoee?enoae?/ieo e?aii??aeo NA caaacia/o?
ca?eueoaiiy no?oio ei?ioeiai caieeaiiy a?eueoa i?ae ia 50 %. Aeey
iiaeaeueoiai i?aeaeuaiiy EEAe NA c i?ina?oethth/ei iie?eooyi ia iniia?
por-Si cai?iiiiiaaii iioei?coaaoe ia?aiao?e aeeooc?eiiai i?ioeano oa
noaa?e?coaaoe ianeaoth/? aeanoeaino? ii?enoiai oa?o oeyoii eiai
eainoeyoe??.
NIENIE IIOAE?EIAAIEO I?AOeUe
Yerokhov V.Yu., Melnyk I.I. Influence of external bias to photoelectric
properties of silicon MIS/IL structures // Solid-State Electronics. –
1998. – 42. – P. 883-889.
Aoaeaeae ss.N., A?ioia A.TH., Iaeueiee E.E. Aeeyiea aiaoiaai
yeaeo?e/aneiai niauaiey ia oioiyeaeo?e/aneea naienoaa e?aiieaauo MIS/IL
no?oeoo? // Oeceea e oaoieea iieoi?iaiaeieeia. – 1997. – ? 10. – N.
1273-1277.
??ioia A.TH., Iaeueiee ?.?. Oioiaeaeo?e/i? ia?aoai?thaa/? niiy/ii?
aia?a?? ia aii?oiiio e?aii?th // A?niee Aea?aeaaiiai oi?aa?neoaoo
“Euea?anueea iie?oaoi?ea”.- 1995. – ? 297. – N. 83-90.
Iao. 23063 A. Oe?a?ia, IEA H 01 L 31/05. Niiy/iee iiaeoeue
aenieiiiooaeii? aia?aaoeee / ??ioia A.TH., Iaeueiee ?.?., ?a?aiei ?.I.
(Oe?a?ia); AeO “Euea?anueea iie?oaoi?ea”. – ? 94086785; Cayae. 29.08.94;
Iioae. 30.06.98, Athe. ? 3.
A?ioia A.TH., Iaeueiee E.E. Iooe iiauoaiey EIAe oioiyeaeo?e/aneeo
i?aia?aciaaoaeae nieia/iie yia?aee // Ain. oi-o “Euea?anueea
iie?oaoi?ea”. – Eueaia, 1994. – 21 n. – ?on. – Aeai. a AIOA Oe?aeiu
03.06.94, ? 1094 – Oe. 94.
Yerokhov V.Yu., Melnyk I.I., Iznin O.I. Photoconversion in solar cells
structures with porous silicon // Proc. of SPIE “Photoconversion:
Science and Technologies”. – 1998. – 3580. – P. 168-177.
Yerokhov V.Yu., Melnyk I.I., Konopaltseva L.I. Increase of
photoconversion efficiency in MIS/IL solar cells // Proc. of SPIE
“Photoconversion: Science and Technologies”. – 1998. – 3580. – P.
178-184.
Yerokhov V.Yu., Melnyk I.I., Gasko L.Z., Iznin O.I. Porous silicon
hydrogenizing for solar cells // Abstracts Book Int. Conf. on Porous
Semiconductors: Science and Technology. – Malorca (Spain). – 1998. – P.
247.
Yerokhov V.Yu., Melnyk I.I., Bogdanovsky Yu.N., Iznin O.I. Hydrogenated
porous silicon in solar cells structures // Proc. 2nd World Conference
on Photovoltaic Solar Energy Conversion. – Vienna (Austria). – 1998. –
P. 1256-1259.
Yerokhov V.Yu., Melnyk I.I. Porous silicon in structures of solar cells
// Proc. School-workshop “Solar Cells: A New Challenge For the
Mediterranean Area (Physics of Materials for Solar Energy Conversion)”.
– Portici (Italy).- 1997.- P. 67-75.
Yerokhov V.Yu., Melnyk I.I., Iznin O.I. Solar cells structures with
porous silicon // Abstract Booklet Second Int. School-Conference on
Physical Problems in Material Science of Semiconductors.- Chernivtsi
(Ukraine). – 1997. – P. 270.
Yerokhov V.Yu., Melnyk I.I. Thin Films of Porous Silicon in
Photoelectric Transmitters // Abstracts Book 10th International
Conference of Thin Films.- Salamanca (Spain).- 1996. – P. 179.
Iaeueiee ?.?. ?ic?iaea iiaeo iaoiae?a i?aeaeuaiiy aoaeoeaiino?
e?aii??aeo oioiaeaeo?e/ieo ia?aoai?thaa/?a niiy/ii? aia?a??. – ?oeiien.
Aeena?oaoe?y ia caeiaoooy iaoeiaiai nooiaiy eaiaeeaeaoa oaoi?/ieo iaoe
ca niaoe?aeuei?noth 05.27.01 – oaa?aeio?eueia aeaeo?ii?ea. – Aea?aeaaiee
oi?aa?neoao “Euea?anueea iie?oaoi?ea”. Euea?a, 1999.
Aeena?oaoe?th i?enay/aii ?ic?iaoe? oa aeine?aeaeaiith iiaeo iaoiae?a
i?i?i?caoe?? ?acenoeaii-?aeiia?iaoe?eieo oa iioe/ieo ao?ao o e?aii??aeo
niiy/ieo aeaiaioao (NA) c aeeooc?eiei oa ?iaeoeiaaiei p-n- ia?aoiaeaie.
Aeey ciaioaiiy ?acenoeaii-?aeiia?iaoe?eieo ao?ao o NA c ?iaeoeiaaiei
p-n- ia?aoiaeii cai?iiiiiaaii aeei?enoiaoaaoe ciai?oi? aeaeo?e/ia
ci?uaiiy. Ia(?oiooaai? aoaeoeai?noue oa iai?yiee i?aeoe/iiai
aeei?enoaiiy oeueiai iaoiaeo. Iioe/i? ao?aoe cai?iiiiiaaii i?i?i?coaaoe
aaaaeaiiyi o no?oeoo?o e?aii??aeo NA oa??a ii?enoiai e?aii?th (por-Si).
Aeey iie?auaiiy aioea?aeaeaieo aeanoeainoae por-Si iioei?ciaaii
oaoiieia?th eiai aeaeo?ioai?/iiai oi?ioaaiiy. Nooo?aiai iie?auaiiy
ianeaoth/eo aeanoeainoae oeueiai iaoa??aeo aeinyaiooi caaaeyee
?ic?iaeaiiio iaoiaeo aeaeo?ioai?/ii? a?ae?iaai?caoe??. Aenia?eiaioaeueii
i?aeoaa?aeaeaii aoaeoeai?noue aeei?enoaiiy a?ae?iaai?ciaaiiai por-Si
aeey i?i?i?caoe?? iioe/ieo ao?ao o no?oeoo?ao iiii- oa
ioeueoee?enoae?/ieo e?aii??aeo NA.
Eeth/ia? neiaa: oioiaeaeo?e/iee ia?aoai?thaa/, e?aii?e, niiy/iee
aeaiaio, ii?enoee e?aii?e, aioea?aeaeaia iie?eooy, a?ae?iaai?caoe?y.
Melnyk I.I. Development of new methods for efficiency increase of
silicon photoelectric converters of a solar energy. – Manuscript.
Thesis for a doctor’s degree by speciality 05.27.01 – solid-state
electronics. – State university “Lviv polytechnic”. Lviv, 1999.
The dissertation is devoted to development and research of new methods
of minimization of resistive-recombination and optical losses in silicon
solar cells (SC) with diffused and induced p-n junctions. For reduction
of resistive-recombination losses in SC with induced p-n junction its
offered to use external bias. The substantiation of efficiency and
directions of practical use of the given method is carried out. The
minimization of optical losses are offered to by reaching by
introduction in silicon SC structure of porous silicon (por-Si) layers.
For improvement of antireflecting properties of por-Si the optimization
of technology of its electrochemical formation is carried out. Essential
improvement of passivation properties of this material is achieved due
to the developed method of an electrochemical hydrogenation. Efficiency
of use of hydrogenated por-Si for minimization of optical losses in
structures of mono- and multicrystalline silicon SC is experimentally
confirmed.
Key words: photoelectric converter, silicon, solar cell, porous
silicon, antireflection coating, hydrogenation.
Iaeueiee E.E. ?ac?aaioea iiauo iaoiaeia iiauoaiey yooaeoeaiinoe
e?aiieaauo oioiyeaeo?e/aneeo i?aia?aciaaoaeae nieia/iie yia?aee. –
?oeiienue.
Aeenna?oaoeey ia nieneaiea o/aiie noaiaie eaiaeeaeaoa oaoie/aneeo iaoe
ii niaoeeaeueiinoe 05.27.01 – oaa?aeioaeueiay yeaeo?iieea. –
Ainoaea?noaaiiue oieaa?neoao “Eueaianeay iieeoaoieea”. Eueaia, 1999.
Aeenna?oaoeeiiiay ?aaioa iinayuaia ?ac?aaioea iiauo ?aioaaaeueiuo
iaoiaeia iiauoaiey yooaeoeaiinoe e?aiieaauo nieia/iuo yeaiaioia (NY) n
p-n- ia?aoiaeii e ninoieo ec aaaaeaiey, iyoe ?acaeaeia, iaueo auaiaeia e
nienea eniieueciaaiiuo eeoa?aoo?iuo enoi/ieeia.
Ai aaaaeaiee iainiiaaia aeooaeueiinoue aeenna?oaoeeiiiuo enneaaeiaaiee,
noi?ioee?iaaia eo oeaeue e caaea/e, iienaia iao/iay iiaecia e
i?aeoe/aneay oeaiiinoue iieo/aiiuo ?acoeueoaoia.
Ia iniiaa iaci?a e aiaeeca iao/iuo ioaeeeaoeee iieacaii, /oi iaeaieaa
iioeiaeueiuie aeey eniieueciaaiey a aunieiiiuiuo aaia?aoeeiiiuo nenoaiao
yaeythony e?aiieaaua oioiyeaeo?e/aneea i?aia?aciaaoaee (OYI), n?aaee
eioi?uo iaeaieaa yooaeoeaiuie yaeythony OYI n p-n- ia?aoiaeii e NY ni
no?oeoo?ie iaoaee/aeeyeaeo?ee/iieoi?iaiaeiee n eiaeooee?iaaiiui
eiaa?niui neiai (MIS/IL). ?anniio?aia yaiethoeey no?oeoo? yoeo oeiia OYI
e iaia/aiu iai?aaeaiey eo aeaeueiaeoaai ?acaeoey. ?ac?aaioaia iauay
iaoiaeeea aeenna?oaoeeiiiuo enneaaeiaaiee, iai?aaeaiiuo ia iiauoaiea
yooaeoeaiinoe e?aiieaauo NY n aeeoooceiiiui e eiaeooee?iaaiiui p-n-
ia?aoiaeaie.
A niioaaonoaee n ii?aaeaeaiiuie oeaeueth, iauaeoaie e iaoiaeeeie
enneaaeiaaiee, inouanoaeaii ea/anoaaiiia e eiee/anoaaiiia ii?aaeaeaiea
oaeoi?ia, eioi?ua ia?aie/eaatho aeinoeaeaiea iaeneiaeueiie yooaeoeaiinoe
oioiaieueoae/aneiai i?aia?aciaaiey a no?oeoo?ao e?aiieaauo NY n p-n-
ia?aoiaeii. Aeey yoiai i?iaaaeaii iiaeaee?iaaiea oioiaieueoae/aneiai
i?aia?aciaaiey a no?oeoo?a e?aiieaauo NY n p-n- ia?aoiaeii e ?an/ao
aa?oiae a?aieoeu eo oai?aoe/aneiai EIAe.
Onoaiiaeaii, /oi iniiaiuie oeiaie iioa?ue oioiaaia?e?iaaiiie iiuiinoe a
NY n aeeoooceiiiui e eiaeooee?iaaiiui p-n- ia?aoiaeaie yaeythony
?acenoeaii-?aeiiaeiaoeeiiiua e iioe/aneea iioa?e. Iaiauaiea e aiaeec
oai?aoe/aneeo enneaaeiaaiee aeaao iniiaaiey iieaaaoue, /oi yooaeoeaiie
ieieiecaoeee iie/aneeo e iioe/aneeo iioa?ue a NY n p-n- ia?aoiaeii
aiciiaeii aeinoe/ue eee i?e eniieueciaaiee iiauo, iao?aaeeoeeiiiuo aeey
e?aiieaaie oioiaieueoaeee yooaeoia, eee iooai aaaaeaiey a eo no?oeoo?o
iiauo iieoi?iaiaeieeiauo iaoa?eaeia.
A niioaaonoaee n yoei aeey yooaeoeaiiai oiaiueoaiey
?acenoeaii-?aeiiaeiaoeeiiiuo iioa?ue a NY n eiaeooee?iaaiiui p-n-
ia?aoiaeii ?ac?aaioai i?inoie aeey oaoie/aneie ?aaeecaoeee iaoiae,
iniiaaiiue ia eniieueciaaiee aiaoiaai yeaeo?e/aneiai niauaiey.
Enneaaeiaai iaoaieci aeeyiey aiaoiaai niauaiey ia no?oeoo?iua ia?aiao?u,
auoiaeiua yeaeo?e/aneea oa?aeoa?enoeee e EIAe MIS/IL NY. Iainiiaaiu
oeaeaniia?aciinoue e iai?aaeaiey i?aeoe/aneiai eniieueciaaiey aeaiiiai
iaoiaea, a oaeaea i?aaeeiaeaii iiaia oaoie/aneia ?aoaiea eiino?oeoeee
nieia/iiai iiaeoey, eioi?ia iicaieyao iiauneoue aieaa /ai ia 25 % EIAe
NY n eiaeooee?iaaiiui p-n- ia?aoiaeii i?e eo ?aaioa a ninoaaa
aunieiiiuiuo aaia?aoeeiiiuo nenoai.
A ea/anoaa ia?niaeoeaiiai iaoa?eaea aeey oiaiueoaiey iioe/aneeo iioa?ue
a e?aiieaauo NY enneaaeoaony ii?enoue e?aiiee (por-Si). Iaiauaiea e
aiaeec iiuoa oioiaieueoae/aneiai eniieueciaaiey por-Si iiaeoaa?aeaeaao
aiciiaeiinoue oi?iuaiey oaoiieiaee iieo/aiey e nouanoaaiiiai iiauoaiey
yooaeoeaiinoe e?aiieaauo NY i?e aaaaeaiee a eo no?oeoo?o neiaa yoiai
iaoa?eaea a ea/anoaa aioeio?aaeathuaai iie?uoey. Ia iniiaa eco/aiey e
aiaeeca iee?ino?oeoo?u por-Si auaeaeiooa aeiioaca i aiciiaeiinoe
aeaeueiaeoaai oeo/oaiey aai aioeio?aaeaoaeueiuo naienoa iooai
iioeiecaoeee oaoiieiae/aneeo oneiaee i?ioeanna yeaeo?ioeie/aneiai
oi?ie?iaaiey yoiai iaoa?eaea. N yoie oeaeueth ?ac?aaioaia e iainiiaaia
iaoiaeeea iioeiecaoeee oaoiieiaee ?inoa ii?enouo neiaa. N
eniieueciaaieai aeaiiie iaoiaeeee ia iniiaa por-Si nicaeaiu
i?inaaoeythuea e naaoicaoaaouaathuea iioe/aneea iie?uoey aeey e?aiieaauo
NY n ieaia?iie e oaenoo?e?iaaiiie iiaa?oiinoueth, eioi?ua ii
yooaeoeaiinoe oiaiueoaiey iioe/aneeo iioa?ue niiinoaaeiu n iaeeo/oeie
aioeio?aaeathueie iioe/aneeie nenoaiaie.
Aia?aua aeey yooaeoeaiiai oeo/oaiey ianneae?othueo naienoa por-Si
i?aaeeiaeaii eniieueciaaoue yeaeo?ioeie/aneoth aeae?iaaiecaoeeth.
Yenia?eiaioaeueii enneaaeiaaiu iioeiaeueiua aeey i?aeoe/aneiai
eniieueciaaiey ?aaeeiu aeaiiiai i?ioeanna. Iieiaeeoaeueiia aeeyiea
yeaeo?ioeie/aneie aeae?iaaiecaoeee ia ianneae?othuea naienoaa por-Si
iiaeoaa?aeaeaii enneaaeiaaieyie n eniieueciaaieai ?yaea
yenia?eiaioaeueiuo iaoiaeee.
Iioeiecaoeeiiiuie enneaaeiaaieyie onoaiiaeaiu oaoiieiae/aneea oneiaey,
eioi?ua iicaieytho oi?ie?iaaoue neie aeae?iaaiece?iaaiiiai por-Si ia
caaa?oathuai yoaia nicaeaiey no?oeoo?u NY aac iia?aaeaeaiey o?iioaeueiie
eiioaeoiie nenoaiu. Yenia?eiaioaeueii iiaeoaa?aeaeaia yooaeoeaiinoue
eniieueciaaiey oaeiai iioeiece?iaaiiiai aioeio?aaeathuaai iie?uoey aeey
ieieiecaoeee iioe/aneeo iioa?ue a no?oeoo?ao iiii- e
ioeueoee?enoaeee/aneeo e?aiieaauo NY. I?iaaaeai aiaeec ?acoeueoaoia e
?ac?aaioaiu i?aeoe/aneea ?aeiiaiaeaoeee ioiineoaeueii aeaeueiaeoaai
iiauoaiey EIAe NY n i?inaaoeythuei iie?uoeai ia iniiaa por-Si.
Eeth/aaua neiaa: oioiyeaeo?e/aneee i?aia?aciaaoaeue, e?aiiee, nieia/iue
yeaiaio, ii?enoue e?aiiee, aioeio?aaeathuaa iie?uoea, aeae?iaaiecaoeey.
PAGE 18
PAGE 13
Нашли опечатку? Выделите и нажмите CTRL+Enter
